Physical Sciences and Mathematics Commons^™

Using Chromium Stable Isotopes To Monitor Chromium Reactive Transport: Oxidation Experiments And Field Studies, Alejandro Villalobos Aragon

Open Access Theses & Dissertations

Chromium (Cr) is a common contaminant found at a number of sites globally. Cr sources can be either anthropogenic or natural. Cr occurs in nature in two valences, with Cr(VI) being carcinogenic, more toxic and mobile than Cr(III). Reduction of Cr(VI) to Cr(III) is a common remediation strategy, but monitoring Cr reduction using only concentration and speciation analyses is a difficult endeavor because concentrations can be affected by dilution and advection in addition to reduction. Cr isotopes are fractionated during reduction processes, so monitoring isotopic changes in Cr may be a faster and more effective way to monitor reduction. This …