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Full-Text Articles in Physical Sciences and Mathematics

Post Monitoring Of A Cyclodextrin Remediated Chlorinated Solvent Contaminated Aquifer, Rebecca Mary Hinrichs Jan 2004

Post Monitoring Of A Cyclodextrin Remediated Chlorinated Solvent Contaminated Aquifer, Rebecca Mary Hinrichs

LSU Master's Theses

Hydroxypropyl-β-cyclodextrin (HPβCD) has been tested successfully in the laboratory and in the field for enhanced flushing of low-polarity contaminants from aquifers. The cyclodextrin molecule forms a toroidal structure, which has a hydrophobic cavity. Within this cavity, organic compounds of appropriate shape and size can form inclusion complexes, which is the basis for the use of cyclodextrin in groundwater remediation. The hydrophilic exterior of the molecule makes cyclodextrin highly water-soluble. The solubility of cyclodextrins can be further enhanced by adding functional groups, such as hydroxypropyl groups, to the cyclodextrin core. The aqueous solubility of HPβCD exceeds 950 g/L. These high solubilities …


Nature And Dynamics Of Late Miocene/Early Pliocene Ice-Sheet Grounding Events On The Pacific Margin Of The Antarctic Pennisula Outer Continental Shelf, David C. Egan Jan 2004

Nature And Dynamics Of Late Miocene/Early Pliocene Ice-Sheet Grounding Events On The Pacific Margin Of The Antarctic Pennisula Outer Continental Shelf, David C. Egan

LSU Master's Theses

Package-3 unconformities identified by Bart and Anderson (1995) were mapped to evaluate their glacial unconformity interpretation using a regional grid of single channel seismic data from the Antarctic Peninsula outer continental shelf. Detailed correlations show many crosscutting relationships within Package 3 such that the unconformities and units they bound are not regionally continuous across the margin. Comparison of Package-3 unconformities with the modern bathymetry reveals that cross-shelf trough and bank morphology is absent, which indicates that ice streams probably did not exist on the shelf during Package-3 time. On the continental shelf, only the middle part of Package 3 is …


Overlap Zones, Growth Faults, And Sedimentation: Using High Resolution Gravity Data, Livingston Parish, La, Carrie Alison Cazes Jan 2004

Overlap Zones, Growth Faults, And Sedimentation: Using High Resolution Gravity Data, Livingston Parish, La, Carrie Alison Cazes

LSU Master's Theses

In south Louisiana, parallel to the coast of the Gulf of Mexico, are belts of east-to-west trending, listric-normal faults with associated contemporaneous sedimentation and fault movement. The Tepetate-Baton Rouge Fault system in south-central Louisiana contains individual fault segments which are arcuate and overlap each other in map view, as seen on LiDAR data. Gravity survey data, with a sample spacing of 20 to 50 m, was collected across normal fault scarps. Structural ramps may form in the area between overlapping normal fault segments creating an east-to-west gradient. This gradient change may divert streams and provide areas for coarse-grained sediments to …


Enhanced Flushing With Cyclodextrin For The Remediation Of Creosote Contaminated Soil, Monalisa Dutta Jan 2004

Enhanced Flushing With Cyclodextrin For The Remediation Of Creosote Contaminated Soil, Monalisa Dutta

LSU Master's Theses

Past practices of applying creosote and coal tar preservatives to wood, such as unlined pits and trenches, have resulted in contamination of the surface and ground water at thousand of sites. The low aqueous solubility, volatility and bioavailability of many these constituents limit their degradation by natural attenuation and standard remediation techniques such as ground water flushing, soil vapor extraction, and bioremediation. While research has shown that cyclodextrin solutions have the ability to enhance the solubility of some of the components of creosote, additional work is needed to evaluate its potential as a remedial agent for these sites. Equilibrium batch …


Seismic Stratigraphic Investigation Of The Ukpokiti Field Channel Complex, Oml 108, Offshore Nigeria, Northwestern Niger Delta, Toby Latwan Stewart Jan 2004

Seismic Stratigraphic Investigation Of The Ukpokiti Field Channel Complex, Oml 108, Offshore Nigeria, Northwestern Niger Delta, Toby Latwan Stewart

LSU Master's Theses

Detailed seismic stratigraphic analyses and mapping show that a well defined Ukpokiti Field Channel complex (late Miocene) found on the up-thrown side of a major back-to-back fault system in the West Niger delta inner-continental shelf probably formed during a single eustatic fall. The channel (>500 msec, 10 km wide) shows several tributaries entering the trunk axis from what was probably a surface of subaerial exposure. Slumping is prominent on the north flank of the trunk channel. No channel unconformity is evident in the down-thrown block. This investigation seeks to resolve the lack of down-dip correlative seismic expression across the …


A Comparison Of A High-Resolution Survey And A Three-Dimensional Seismic Survey In A Feature-Rich Region Of The Green Canyon Area, Gulf Of Mexico, Bruce Miles Samuel Jan 2004

A Comparison Of A High-Resolution Survey And A Three-Dimensional Seismic Survey In A Feature-Rich Region Of The Green Canyon Area, Gulf Of Mexico, Bruce Miles Samuel

LSU Master's Theses

Recent advances in Autonomous Underwater Vehicle (AUV) technology have revolutionized the positioning and accuracy of high-resolution deep sea mapping tools. Geologic hazard and engineering surveys by AUV’s are producing high-resolution data sets of a quality that has never before been seen. Three-dimensional (3D) seismic data, though traditionally used for only deep subsurface mapping of large areas, is now being reprocessed at a higher resolution and utilized in well site investigations and geologic hazard assessments. This study makes a comparison between a 3D seismic survey and an AUV high-resolution survey in order to determine the strengths and weaknesses of both of …


Migmatization Of Archean Aluminous Metasediments From The Eastern Beartooth Mountains, Montana, U.S.A., Andrew T. Maas Jan 2004

Migmatization Of Archean Aluminous Metasediments From The Eastern Beartooth Mountains, Montana, U.S.A., Andrew T. Maas

LSU Master's Theses

Geothermobarometry, mineral compositions and textures, and thermodynamic models suggest biotite dehydration melting occurred in the peraluminous rocks of the eastern Beartooth Mountains. These Archean metapelitic migmatites are metatexites and diatexites, and have typical metamorphic assemblages of Qtz + Pl + Kfs + Bt + Sil +/- Grt +/- Crd. The subsequent in situ crystallization of the magma derived from the biotite dehydration created migmatitic leucosomes in the rocks. These leucosomes are primarily composed of quartz, plagioclase and potassium feldspar. Water derived from the dehydration of biotite was dissolved in the melted phase. Crystallization of the magma reintroduced this water to …