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Degradation Of Select Chlorinated Hydrocarbons By (I) Sulfide-Treated Hydrous Ferric Oxide (Hfo) And (Ii) Hydroxyl Radicals Produced In The Dark By Oxygenation Of Sodium Dithionite-Reduced Hfo, Dhurba Raj Pandey

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A previous work demonstrated that sulfide-treated iron oxides (goethite, hematite, and magnetite) may not show reductive pathways with carbon tetrachloride (CT) as observed with lab-precipitated iron sulfide. We examined the kinetics and products of reaction of sulfide-treated hydrous ferric oxide (HFO) towards select chlorinated hydrocarbons in batch reactors with HFO: HS- molar ratio of 1:1.5 at pH 7. CT, 1,1,2-trichlroethane (1,1,2-TeCA), 1,1,1,2-tetrachloroethane (1,1,1,2-TeCA) and 1,1,2,2-tetrachloroethane (1,1,2,2-TeCA) showed faster kinetics whereas chloroform (CF) showed slower kinetics. Trichloroethene (TCE) degradation was observed at three pHs: 7, 8 and 10; the loss in the reactors were not much different from controls at pH …