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Physical Sciences and Mathematics Commons

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Earth Sciences

William & Mary

Dissertations, Theses, and Masters Projects

2003

Articles 1 - 6 of 6

Full-Text Articles in Physical Sciences and Mathematics

Laboratory Oxide Coatings: Physical Form And Surface Chemistry, Kea U. Duckenfield Jan 2003

Laboratory Oxide Coatings: Physical Form And Surface Chemistry, Kea U. Duckenfield

Dissertations, Theses, and Masters Projects

The impact of dissolved trace metals on aquatic ecosystems and human health is controlled by sorption, i.e., binding to the surfaces of environmental particles. Since many environmental particles are coated with highly reactive substances, and since discrepancies in trace metal sorption behavior persist between oxides developed in the laboratory and environmental oxide phases, it was hypothesized that the physical form of oxide coatings may influence the chemical properties of the coated particle. Therefore, relationships between the physical forms of several different Fe(III) oxide coatings and the Cu(II) sorption behavior of the coated solids were investigated in comparison with the component …


Controls On The Delivery Of Fluvial Sediment To The Coastal Ocean: The Salinas River, California, Katherine L. Farnsworth Jan 2003

Controls On The Delivery Of Fluvial Sediment To The Coastal Ocean: The Salinas River, California, Katherine L. Farnsworth

Dissertations, Theses, and Masters Projects

To estimate delivery to the coastal ocean, a global river database was assembled. An estimated 35,000 km3 of freshwater, 4 * 10 6 tonnes of dissolved solids and 18.6 * 106 tonnes of suspended sediment are delivered annually. The global delivery of fluvial water and sediment, both suspended and dissolved, is dominated by Southeast Asia, due to the unique climatic, geologic and geomorphic character of the rivers in this region. Over 30% of the global freshwater and dissolved solid discharge, and an astounding 70% of the suspended sediment originate in this region. The Salinas River, central California, was the focus …


Polycyclic Aromatic Hydrocarbon Sources And Distribution In An Urban Estuary, Shelby E. Walker Jan 2003

Polycyclic Aromatic Hydrocarbon Sources And Distribution In An Urban Estuary, Shelby E. Walker

Dissertations, Theses, and Masters Projects

As part of the assessment of the potential risk posed by contaminated sediments to the environment and human health, the United States Environmental Protection Agency (USEPA) is developing a set of sediment quality criteria (SQC) that are based on equilibrium partitioning (EqP). While EqP theory has often been used to predict contaminant concentrations within a factor of two for a range of sediment types, substantial deviations from predicted values have also been documented. The objective of this research was to evaluate the influence of PAH source on PAH sediment-pore water partitioning and distribution in sediments. The Elizabeth River is one …


Relationships Between Watershed Characteristics And Base Flow Nutrient Discharges To Eastern Shore Coastal Lagoons, Virginia, Jennifer Wu Stanhope Jan 2003

Relationships Between Watershed Characteristics And Base Flow Nutrient Discharges To Eastern Shore Coastal Lagoons, Virginia, Jennifer Wu Stanhope

Dissertations, Theses, and Masters Projects

No abstract provided.


Microbial Dynamics And Biogeochemistry In The North Pacific Subtropical Gyre, Matthew J. Church Jan 2003

Microbial Dynamics And Biogeochemistry In The North Pacific Subtropical Gyre, Matthew J. Church

Dissertations, Theses, and Masters Projects

The research presented in this dissertation describes the influence of planktonic bacterial growth on upper ocean organic matter dynamics in the North Pacific Subtropical Gyre (NPSG). Examination of the temporal dynamics in dissolved organic matter (DOM) was coupled with investigations that targeted the influence of heterotrophic bacterial production (HBP) on organic matter fluxes in the NPSG. Nine cruises to the Hawaii Ocean Time-series field site Station ALOHA revealed that HBP accounted for a large flux of organic carbon in the upper ocean of the NPSG. HBP was significantly enhanced by sunlight, with photoenhancement of HBP accounting for 3.2 mol C …


Availability Of Humic Nitrogen To Phytoplankton, Jason Holt See Jan 2003

Availability Of Humic Nitrogen To Phytoplankton, Jason Holt See

Dissertations, Theses, and Masters Projects

The chemical, physical, and biological factors affecting the bioavailability of humic nitrogen (N) to coastal phytoplankton were examined. Historically, humic substances have largely been considered biologically refractory, and humic-N is though to be unavailable biologically without prior oxidation via photochemical cleavage or remineralization by bacteria. This is due in part to the high aromaticity and low N content of humic substances. This dissertation investigates whether these assumptions are valid, and whether humic substances may be a more important source of N to the coastal phytoplankton community than previously believed. The research consisted of four main parts. First, changes in the …