Physical Sciences and Mathematics Commons^™

Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines

Masters Theses & Specialist Projects

An increase in atmospheric CO2 since the Industrial Revolution has altered rates of global climate change and has motivated a need to better quantify the flux of carbon between Earth’s reservoirs. Attempts to quantify the exchange of atmospheric carbon between sources and sinks have led to an increasing interest in the terrestrial landscape, including the continental carbon sink associated with carbonate-mineral dissolution. This research sought to better inform an understanding of karst landscapes and their relationship with global climate change through carbon cycling. The study utilized high-resolution data collection of pH, temperature, and specific conductance of waters in the Cascade …

Hydrological Dynamics Of Surface-Groundwater Interactions Between Major Springs Of Mammoth Cave And The Green River, Kentucky, Usa, Matthew Cecil

Masters Theses & Specialist Projects

Mammoth Cave is an iconic example of the cave and karst systems that underlie over 50% of the United States and provide around 13% of the world’s population with water resources. These environmental features are vulnerable to drought, pollution, and human impacts. The complex hydrological regime of the Mammoth Cave system has been studied in the past, but there are improvements and updates that can be made to the past research. The dynamics of the surface-groundwater system, particularly reversals of the Green River and how it backfloods into the cave, are some examples. Echo River and River Styx Springs provide …

A Predictive Flood Model For Urban Karst Groundwater Systems, Trayson Lawler

Masters Theses & Specialist Projects

Urban karst environments are often plagued by groundwater flooding, which occurs when water rises from the subsurface to the surface through the underlying caves and other karst features. The heterogeneity and interconnectedness of karst systems often makes them very unpredictable, especially during intense storm events; urbanization exacerbates the problem with the addition of many impervious surfaces. Residents in such areas are frequently disturbed and financially burdened by the effects of karst groundwater flooding. The Federal Emergency Management Agency (FEMA) offers limited protection to citizens living near flood-prone areas as they primarily focus on the areas near surface bodies of water. …

Comparison Of Groundwater Chemistry And Associated Biodiversity Of Sulfidic Karst Habitats In Southcentral Kentucky, Kendall Wheeler

Mahurin Honors College Capstone Experience/Thesis Projects

In most ecosystems, primary production is conducted by plants or photosynthetic microbes; however, extremophilic sulfur-oxidizing bacteria can use hydrogen sulfide gas (H2S) as an electron donor to produce metabolic energy in a type of metabolism called chemoautotrophy. These ecosystems are a prominent feature of some karst landscapes, and two have been observed in the Mammoth Cave system, Sulphur River in Parker Cave and Marianne’s Pass in Mammoth Cave National Park respectively.

Sulfidic water is ubiquitous in southcentral Kentucky and is strongly associated with hydrocarbon deposits. This oil boom of the 1880s in this region predates most environmental regulation and records …

Carbon Cycling And Critical Zone Dynamics In An Urbanized Karst Groundwater System, Amy Hourigan

Masters Theses & Specialist Projects

Increasing atmospheric CO₂ concentrations are correlated to rising global temperatures. Investigating the cumulative global carbon cycling processes is important to understand and quantify the global carbon cycle. By investigating basic geochemical parameters, EpCO₂, DIC, and δ¹³C_DIC, at four sites along Lost River Cave (LRC), in Bowling Green, Kentucky, concentrations, fluxes and sources of C dissolved in groundwater were determined. Urban karst groundwater systems, compared to more natural karst landscapes, typically exhibit widespread impervious, heat-absorbing surfaces, urban heat island effects, and increased anthropogenic groundwater inputs and localized CO₂ emissions. Carbonate hydrogeochemical …

Atmosphere/Landscape Co2 Interactions In Mammoth Cave National Park: Hydrochemistry Of Cascade River, Great Onyx Cave, Jessica Williams

Mahurin Honors College Capstone Experience/Thesis Projects

High-resolution analysis of water/CO₂/carbonate rock geochemistry was conducted at the Great Onyx Groundwater Basin in Mammoth Cave National Park. The purpose of this work has been to undertake hydrochemical characterization of the karst groundwater in Cascade River, the largest cave stream in the upper level of Great Onyx Cave, which is below a relatively pristine karst landscape.

Hydrochemical monitoring of Cascade River at Biz Falls using field, laboratory, and high-resolution electronic data-sonde measurements has provided a detailed picture of the stream’s behavior with respect to the transport and influence of carbon dioxide in the surface and groundwater system …

Application Of Excitation-Emission Matrices To Fluorescent Dye Tracing Of Groundwater Flow, Cayla M. Baughn

Masters Theses & Specialist Projects

Fluorescent dye tracing of groundwater is a technique employed particularly in carbonate rock karst regions to examine karst hydrology by mapping underground flow paths. It is important to understand the hydrology of karst environments because solutionally-enlarged conduits may allow the rapid influx of contaminants into the groundwater system. Fluorescent dye tracing involves the injection of a fluorescent dye into an appropriate injection site (sinking streams, sinkholes, or even through soil flushed with water) and is followed by sampling at sites where the dye may be recovered (typically springs). Various methods exist by which sampling may occur, but all methods ultimately …

Impacts Of Forest Management And Timber Harvest Practices On Karst Critical Zone Processes In Tongass National Forest, Alaska, Anna Gwendolyn Harris

Masters Theses & Specialist Projects

This study characterizes the throughfall, hydrogeochemistry, dissolution rates, and carbon sources of two proximate temperate rainforest cave systems within the Tongass National Forest in Southeast Alaska (Tongass). Study sites include: an old-growth forest, characterized by having never been logged (containing Walkabout Cave system); and a previously logged – within thirty years, second-growth forest (containing Zina Cave system). Precipitation data were recorded over a five-month period at 10-minute intervals, to understand the effects of throughfall between the altering old and second-growth canopies. At each major spring for the two cave systems, high-resolution data were collected from June 29 through November 21, …

Hydrogeochemical Characterization And Speleogenesis Of Sistema Huautla In Oaxaca, Mexico, Fernando Hernandez

Masters Theses & Specialist Projects

Sierra Mazateca, Mexico is home to Sistema Huautla, the deepest cave in the Western hemisphere with 1,560 meters of depth and 90 kilometers of passage, including 26 entrances distributed in a high-relief, karstified terrain, within the Sistema Huautla Karst Groundwater Basin. Exploration of the cave has generated research questions about its evolution and geomorphology given the different vadose and phreatic zones impacted by tectonic and incision processes. Dye traces during this study of Cueva de La Peña Colorada confirmed it is a fossil resurgence of the cave system. An additional cave, Cueva Elysium, was connected hydrologically in 2019, expanding the …

Controls On Speleogenesis In The Upper-Mississippian Pennington Formation On The Western Cumberland Plateau Escarpment, Hali Steinmann

Masters Theses & Specialist Projects

Much of the pioneering work on caves of the Cumberland Plateau (province spanning Tennessee, Kentucky, Alabama, and Georgia) has been stratigraphically located within the Mississippian Bangor and Monteagle Limestones, wherein some of the region’s largest and most spectacular caves occur. Of interest to the understanding of this karst landscape, but severely underrepresented in the literature thereof, are caves and karst features in a heterogeneous sequence of clastics and carbonates known collectively as the Pennington Formation (Upper Mississippian). This work consisted of a regional study of Pennington caves on the western Cumberland Plateau escarpment (Alabama and Tennessee), and a case study …

Evaluating The Influences Of Karst Hydrogeology On Freshwater Harmful Algal Blooms In Kentucky Lakes, Robert T. Schaefer

Masters Theses & Specialist Projects

A problem exists in Nolin River Lake and Rough River Lake in Kentucky, due to the increasing prevalence of cyanobacterial-based harmful algal blooms (CyanoHABs) and the threats they pose to local communities. These lakes were developed as artificial reservoirs from embankment. Further complicating the issue, the lakes are located within a heavily karstified region and there exists no plan or method currently for monitoring or managing CyanoHABs in a karst region with regard to groundwater inputs to the lake systems or their tributaries. A mixture of techniques and analysis methods was used to determine the best way to monitor and …

Trophic Dynamic Interactions In A Temperate Karst River, Elizabeth Malloy

Masters Theses & Specialist Projects

Surface streams in karst landscapes are often characterized by high nutrient levels due to incomplete filtration through series of innumerable, below-ground conduits. Seasonal growth of the filamentous alga, Cladophora, is typically associated with nutrient-rich waters. This research compared macroinvertebrate food web structure between riverine reaches with contrasting underlying karst topography, nutrient levels, and Cladophora cover during summer 2012 and autumn 2013. Recent work in these reaches found a high correlation between Cladophora cover and nutrient content, particularly nitrate. Four questions were addressed during this study: 1. Do longitudinal trends in algal and consumer δ13C values relate to decreased DIC availability …

Public School Science Education And Geographically-Specific Environmental Sustainability Issues: Implications For Social Work Education, Amanda Gallion

Mahurin Honors College Capstone Experience/Thesis Projects

The focus of this project was to examine the educational practices of Kentucky-based public school teachers (grades 4th-8th) related to their efforts to incorporate sustainability into the science classroom and specifically related to the teachers’ focus or lack of focus on karst landscape. The major themes that were analyzed were how educators include this content into their classroom material and how this impacts their students in the area of environmental sustainability. The themes analyzed were: environmental sustainability as a lifestyle choice; education about environmental sustainability, the nexus of family, school, and community; the importance of geographical context in regards to …

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …

Evaluating The Effectiveness Of Regulatory Stormwater Monitoring Protocols On Groundwater Quality In Urbanized Karst Regions, Daniel C. Nedvidek

Masters Theses & Specialist Projects

Non-point pollution from stormwater runoff is one of the greatest threats to water quality in the United States today, particularly in urban karst settings. In these settings, the use of karst features and injection wells for stormwater management results in virtually untreated water being directed into the karst aquifer. Currently, no policies exist specifically to provide water quality protections to karst environments. This study utilized a combination of karst stormwater quality data, along with survey data collected from MS4 Phase II communities, and an analysis of current federal, local, and state water quality regulations, to assess the need for karst-specific …

Big Red, Small Planet, Christian Ryan-Downing , Editor, Leslie North , Editor

Sustainability Publications and Resources

At WKU, “The Spirit Makes the Master”. Our commitment to continuous improvement is clearly reflected in our sustainability efforts. WKU’s commitment to sustainability, whether demonstrated in campus operations or in educational programs, helps to ensure that our graduates are prepared to address the complicated environmental, social and economic issues we face today. They will be able to think critically, solve problems creatively and be engaged citizens. If that’s all we accomplish then we will have achieved great success. But our sustainability commitment pays dividends, as it also leads us to reduce our environmental footprint, practice social responsibility, and conserve natural …

From Sink To Resurgence: The Buffering Capacity Of A Cave System In The Tongass National Forest, Usa, Chris Groves, Melissa Hendrikson

Earth, Environmental, and Atmospheric Sciences Faculty Publications

The Tongass National Forest of Southeast Alaska, USA, provides a unique environment for monitoring the impact of the cave system on water quality and biological productivity. The accretionary terrane setting of the area has developed into a complex and heterogeneous geologic landscape which includes numerous blocks of limestone with intense karstification. During the Wisconsian glaciation, there were areas of compacted glacial sediments and silts deposited over the bedrock. Muskeg peatlands developed over these poorly drained areas. The dominant plants of the muskeg ecosystem are Sphagnum mosses, whose decomposition leads to highly acidic waters with pH as low as 2.4. These …

Water Quality Impacts From Agricultural Land Use In Karst Drainage Basins Of Sw Kentucky And Sw China, Chris Groves, Ted Baker

Earth, Environmental, and Atmospheric Sciences Faculty Publications

Karst regions are composed of soluble rock, often limestone, which leads to the formation of fissures, sinkholes, and water flow conduits such as caves. Pollutants in karst waters tend to be quickly directed and concentrated into these subsurface conduits. As a result of this and other factors, water resources are especially sensitive to contamination and pollution in karst areas. Pollutant concentrations going into karst subsurface fluvial systems are often very similar to the concentrations surfacing at outlets such as springs. Areas connected by karst conduit flows must be distinctly determined and special attention should be given to water quality impacts …

Water Quality Impacts From Agricultural Land Use In Karst Drainage Basins Of Sw Kentucky And Sw China, Chris Groves, Ted Baker

Chris Groves

Karst regions are composed of soluble rock, often limestone, which leads to the formation of fissures, sinkholes, and water flow conduits such as caves. Pollutants in karst waters tend to be quickly directed and concentrated into these subsurface conduits. As a result of this and other factors, water resources are especially sensitive to contamination and pollution in karst areas. Pollutant concentrations going into karst subsurface fluvial systems are often very similar to the concentrations surfacing at outlets such as springs. Areas connected by karst conduit flows must be distinctly determined and special attention should be given to water quality impacts …

An Analysis Of Base-Level Conduit Sedimentation In South Central Kentucky, Ben Tobin

Masters Theses & Specialist Projects

In karst basins, significant amounts of surface-derived sediment can enter into cave systems. The transport and deposition of these sediments in underground streams is a function of flow velocity, sediment supply and passage morphology. Changes in the surface environment can affect the water and sediment supplies to subsurface drainage systems and thus may be reflected in the sedimentary structure, texture and rates of deposition of cave sediments. Cave sediments in two south central Kentucky caves were studied to evaluate a possible, relationship between variations in deposit characteristics and variations in surface changes, including land-use. Samples were collected using coring tubes …

Storm Response And Water Balance Of Temperate Rainforest Karst Watersheds: Tongass National Forest, Alaska, Johanna Kovarik

Masters Theses & Specialist Projects

The Tongass National Forest in southeast Alaska contains 2,176 square kilometers of karst. As part of the evolving Tongass Land Management Plan, research into the function of karst systems is crucial in understanding how forest management affects not only karst areas but also surrounding ecosystems. Dye trace and water balance results in two watersheds on the north end of Prince of Wales Island demonstrate the difficulty in containing the effects of management, as water can enter karst catchments from unknown sources at different flow regimes. A dye trace was conducted in Windgate and Canyon Block watersheds. Two sinking streams were …

Hydrochemistry In An Alpine Karst System, Sequoia And Kings Canyon National Parks, California, Joel Despain

Masters Theses & Specialist Projects

This study uses high-resolution, long-term conductivity, temperature, discharge, pH, and laboratory data from 2001 through 2003 from an alpine karst spring located at 2,500 m amsl in Sequoia National Park, California to reveal detailed chemical parameters of this karst system. The data show a system with a pronounced spring run-off, extended periods of base flow quiescence, storm responses tied to precipitation as rain or as snowfall, and clear diurnal and seasonal patterns of discharge. pH and spC values show an inverse relationship to discharge and temperature, which are generally in phase. Total inorganic carbon (TIC) and the fraction of mineral-derived …

Hydrolgeologic Groundwater Sensitivity And Vulnerability Mapping In South Central Kentucky, Andrea Croskrey

Masters Theses & Specialist Projects

Groundwater sensitivity (Ray and O'dell 1993 a) refers to the inherent ease with which groundwater can be contaminated based on hydrogeologic characteristics. We have developed digital methods for identifying areas of varying groundwater sensitivity for a ten county area of south-central Kentucky relevant to a scale of 1: 24,000. The study area includes extensive limestone karst sinkhole plains, with groundwater that is generally extremely sensitive to contamination. Digitally Vectorized Geologic Quadrangles (DVGQs) were combined with elevation data to both identify hydrogeologic groundwater sensitivity regions and to identify zones of "high risk runoff where contaminants could be transported in runoff from …

Evaluating Uranium Depth Versus Socio-Economic Statistics For Residential Radon Vulnerability In Warren County, Kentucky, Anthony Iovanna

Masters Theses & Specialist Projects

Residences in Warren County, Kentucky, are characterized by high levels of residential radon, which is one of the radioactive daughter products of uranium. According to the United States Environmental Protection Agency (US EPA), radon exposure causes approximately 22,000 lung cancer deaths in the United States per year. The City of Bowling Green, in Warren County, is underlain by karst, an easily soluble limestone subsurface, which allows radon gas to travel easily through cracks and fissures. Carbonate rocks under Bowling Green are underlain by the Devonian Chattanooga Shale, a low-grade uranium ore and a potential source of radon gas. A digital …