Physical Sciences and Mathematics Commons^™

Toward A Greater Comprehension Of The Paraná Epicontinental Sea During The Late Paleozoic Ice Age: The Glacial And Postglacial Record In The Western Paraná Basin (Brazil) And The Kaokoveld Fjord Network (Namibia), Eduardo Luiz Menozzo Da Rosa

Theses and Dissertations

The late Paleozoic Ice Age (LPIA; 362 to 255 Ma) was an icehouse interval that drove substantial changes in Earth’s surficial systems. Numerous paradigms regarding aspects of the LPIA were established throughout ~150 years of research based primarily on the evolving state of knowledge in sedimentology. The near-field lithological evidence for widespread glaciation across sedimentary basins of Gondwana are the building blocks for comprehensive paleoclimatic, biologic, paleogeographic, and ice volume models. Nevertheless, the embodied glacial record from several late Paleozoic Gondwanan depocenters still rely on insufficient and/or outdated sedimentologic and stratigraphic studies, which can lead to misinterpretations in models built …

Nutrient Dynamics Of Freshwater Estuarine Sediments Disturbed By Dredging, Ryan Allan John Roekle

Theses and Dissertations

This study examined the nutrient environment of sediments in the Milwaukee River estuary and the dynamics of those nutrients during simulated disturbance experiments within the context of large-scale dredging remediation. Surface sediments were collected from throughout the Milwaukee estuary (including river, harbor, and nearshore stations) by PONAR, centrifuged to separate porewater (interstitial water) from solid material, and filtered to further isolate and stabilize dissolved material. Porewaters were analyzed for dissolved nutrients including ammoniacal nitrogen (AN), nitrate, nitrite, and soluble reactive phosphorus (SRP). Surface sediment porewaters within the estuary were often highly enriched in AN and SRP, which were often 10-2000x …

Testing The Use Of Anisotropy Of Magnetic Susceptibility (Ams) In Determining Genetic Origins Of Paleoproterozoic Diamictites, Miles A. Harbury

Theses and Dissertations

The Huronian Supergroup (2.4-2.1 Ga) in Ontario, Canada is widely accepted as an important stratigraphic interval for interpreting Paleoproterozoic climate. This is because it contains some of the oldest glaciogenic rocks on the planet. However, massive and poorly-stratified diamictites in the Gowganda Formation of the Huronian Supergroup have varying depositional interpretations among sedimentologists (subglacial, rainout, sediment gravity flow etc.). Diamictites can occur from a variety of processes and, therefore, proper depositional interpretation is essential for unraveling detailed environmental conditions at the time of deposition. Anisotropy of magnetic susceptibility (AMS) looks at the orientation of magnetic particles within a rock and …

Entangled Conquest: A Study Of Cultural Hybridization And Change In Norman Ireland, Sean Mcconnel

Theses and Dissertations

This thesis employs entanglement theory and new geophysical macro-analytical methods to

examine the spread of Norman culture in late medieval Ireland. The traditional theories of

Anglo-Norman conquest by mass migration, by military conquest, and by political conquest are

reviewed and compared to a more nuanced theory of Normanization, which suggests that

genetically Irish people, who spoke Irish, practiced Irish law, and pursued Irish interests were

primarily responsible for what is considered "Norman" material culture on the Island. This

dissertation presents the idea that adherence to the English king was a necessary and expedient

action on the part of Irish lords …

Using Anisotropy Of Magnetic Susceptibility (Ams) To Identify A Tectonic Lineation In The Pulo Do Lobo Formation In The Southern Iberian Shear Zone Near Aracena, Spain, Devin Levang

Theses and Dissertations

The Southern Iberian Shear Zone (SISZ) is a Variscan-aged suture representing the closure of a small ocean basin during the Carboniferous. The SISZ is bounded on either side by the well-studied, relatively homogeneous Beja-Acebuches Metabasites (BAM) and the complex and heterogeneous accretionary metasedimentary rocks of the Pulo do Lobo (PdL). The SISZ underwent a combination of shortening and lateral shearing known as transpression. Despite a very well-developed tectonic foliation, kinematic interpretation in the PdL is made difficult by a lack of easily identifiable lineations. Anisotropy of magnetic susceptibility (AMS), a geophysical technique measuring the relative anisotropy of magnetic susceptibility axes …

Unraveling Deformation Mechanisms And Kinematics In Metasedimentary Rocks Along The Southern Iberian Shear Zone, Kayla P. Kopinski

Theses and Dissertations

The primary goal of this project is to document deformation mechanisms in quartz-rich rocks across a 100 m wide ductile shear zone to evaluate whether strain localization at the brittle-ductile transition is accompanied by variations in active or dominant deformation mechanisms. A secondary goal of this project is to evaluate whether the kinematic framework varies across a shear zone with a major rheological boundary. The Southern Iberian Shear Zone (SISZ), a major terrane bounding shear zone within the Iberian Massif, is an ideal location to study these questions because it is a regional scale shear zone currently exposed at the …

Strain Development And Partitioning Across A Transpressional Shear Zone Along A Quartzite- Metagabbro Contact In The Black Hills Uplift, South Dakota, Eric L. Schuemann

Theses and Dissertations

The Nemo region of South Dakota’s Black Hills offers an ideal location to study transpressional shear zones because it hosts an exposed Archean lithological boundary between two contrasting rheological units, the Boxelder Creek Quartzite (BCQ), a rift-depositional quartzite, and the Blue Draw Metagabbro (BDM), a metagabbro sill, deformed within a ductile shear zone that represents the beginning of main-phase formation of the North American continent as we know it today. The tectonic setting of the Black Hills is at the eastern edge of the Archean Wyoming province, located near the Trans-Hudson Orogeny suture zone that formed between the Wyoming and …

Stratigraphy, Sedimentology, And Deformational Significance Of Cambrian And Early Ordovician Strata Along The Southeast Wisconsin Arch, Allison Raeann Kusick

Theses and Dissertations

A detailed study of the stratigraphic units in and around the Wisconsin Arch of central and southeast Wisconsin are presented to refine the sedimentologic record and the geologic implications within the Cambrian and early Ordovician strata. The Cambrian and early Ordovician sediments in central and southeast Wisconsin unconformably overlie a topographic high composed of Precambrian basement rocks, called the Wisconsin Arch, and consist of various clastic deposits, dolostones, and several horizons of deformation. Bedrock cores, made available through the Wisconsin Geological and Natural History Survey (WGNHS), were analyzed, to understand sedimentation in the Cambrian and early Ordovician. My analyses focused …

Swimming Ability Of The Enigmatic Carboniferous Fish: Tullimonstrum Gregarium, Jacob James Potter

Theses and Dissertations

Tullimonstrum gregarium, more commonly known as the Tully Monster, is one of the strangest creatures in the fossil record. While it was traditionally considered a problematic fossil, recent studies have firmly placed the Tully Monster with the vertebrates as a relative of lamprey and hagfish. This may offer insight into the Tully Monster’s ecology, but the Tully Monster’s Swimming ability remains uncertain due to its strange body plan. This study aims to investigate the hydrodynamics of these features to gain insight into the Tully Monster’s swimming ability using computational fluid dynamics (CFD). 3D and 2D simulations of the Tully Monster …

Terrestrial Perspective On The Formation, Evolution, And Detection Of Zeolites In Lacustrine Environments On Early Mars, Gayantha Roshana Loku Kodikara

Theses and Dissertations

This study evaluates the possible formation and evolution mechanisms of zeolites on early Mars with possible explanations for their limited detections using Earth analogs. This study focuses on the formation of zeolites in the closed basin lakes where the largest relatively pure concentrations of natural zeolites are found on Earth. Five working hypotheses were formulated to explore the limited detection of zeolites in closed basin lakes on Mars and different styles of scientific reasoning with suitable examples were used to test the independent, converging lines of inquiry. Zeolites may not be identifiable in certain locations on Mars using orbital data …

The Effects Of Hybridization On Skeletal Morphology In Two Closely Related Populations Of Rhesus Macaques (Macaca Mulatta): A Geometric Morphometric Approach, Cody Zachery Schumacher

Theses and Dissertations

Precise identification and classification techniques are vital for the field of paleoanthropology to ensure that hominin fossilized remains are labeled accurately. The morphology of extinct hominin specimens will typically be compared to extant nonhuman primate species because of how closely related they are phylogenetically. Observable similarities in their morphological variation can be examined to infer which traits may be a result of evolution and this can update our understanding of their evolutionary relationships. The genus Macaca displays a level of morphological variation that is similar to that seen in the genus Homo, therefore macaques can be used as an analogous …

Alkalinity Enhanced Mass Reduction Of Uranium Contaminated Sediment, Cullen Edward Meurer

Theses and Dissertations

Uranium is a toxic and radioactive metal that is naturally occurring in the Earth’s crust. The uranium mining boom of the 1950’s produced many contaminated aquifers throughout the United States. Monitoring of groundwater data suggests that uranium concentrations may take 100’s of years to naturally attenuate to below the maximum contamination limit. This project examines a potential and novel remediation technique of groundwater contaminated with uranium through alkalinity enhanced desorption from the solid phase. Alkalinity enhances the desorption of uranium by complexing uranyl (UO22+) with Ca and CO3 which allows for further desorption. Since remediation is time consuming and expensive, …

Mass Transport Of Uranium During Recharge Of Surface Water To Contaminated Groundwater, Kendyl Nicole Hoss

Theses and Dissertations

This study characterized the predominant mass transport mechanisms of uranium during river water recharge to contaminated groundwater to better characterize its mobility. It was hypothesized that the mass transfer of uranium from the solid phase to the aqueous phase was occurring during periods of river water to groundwater recharge via concentration-driven desorption. Sediment data confirmed the presence of uranium on the solid phase via nitric acid extraction. The recharge of river water to the saturated zone of a uranium-contaminated aquifer was simulated in a multi-well tracer test. The injection fluid was Little Wind River water and was traced with added …

Baseflow Variability Due To Changes In Climate, Basin Characteristics, And Groundwater Withdrawals In The State Of Wisconsin, Usa, Susan Borchardt

Theses and Dissertations

ABSTRACT

BASEFLOW VARIABILITY DUE TO CHANGES IN CLIMATE,BASIN CHARACTERISTICS, AND GROUNDWATER WITHDRAWALS IN THE STATE OF WISCONSIN, USA

bySusan Borchardt The University of Wisconsin-Milwaukee, 2022 Under the Supervision of Professor Woonsup Choi

In Wisconsin, the number of high-capacity wells has increased substantially, and concerns have been raised about their impact on both groundwater levels and streamflow. At the same time Wisconsin’s climate has been changing, and both the annual precipitation (5%) and temperature (1.5oC) have been trending upward over the last 68 years and both are predicted to increase into the future. This study attempted to demonstrate the simultaneous effects …

Sorption Of 2-Naphthalene Sulfonate To Organic Carbon In Natural Saturated Porous Media, Jiyan Hatami

Theses and Dissertations

Organic carbon (OC) in aquifer sediments serves as a key geochemical control on contaminant fate and transport, potentially immobilizing or delaying mass transport downgradient. Quantifying the abundance of OC in aquifer sediments is therefore imperative in developing a conceptual understanding of local contaminant transport. Traditional methods involve time-intensive coring and lab analyses for total OC (TOC) at distinct intervals with depth. These methods fail to account for the heterogeneity between discrete points and do not interrogate TOC along groundwater flow pathways. 2-naphthalene sulfonate (2-NS), a novel groundwater tracer, was investigated here as a possible sorptive tracer for estimating the relative …

Analyzing Weathering Patterns In Modern And Paleolake Deposits Of Tecopa, California: Implications For The Detection Of Paleolakes On Mars, Jason Benjamin Carman

Theses and Dissertations

This study focuses on two stratigraphic sections from the Tecopa paleolake and samples from the modern Tecopa and Amargosa River basins as a terrestrial analogue to Martian paleolakes. Previous work shows that the later stages of Pleistocene Lake Tecopa were highly alkaline and saline due to evaporation, which led to the formation of authigenic lacustrine minerals such as zeolites, clays, and precipitates that are potentially similar to Martian paleolakes. Paleolakes can provide information on past aqueous processes, such as the changes in the hydrologic cycle that a particular area experienced over the lifespan of a lake on Earth or Mars. …

A South Polar View Of Late Paleozoic Glaciation: Physical Sedimentology And Provenance Of Glacial Successions In The Tasmanian And Transantarctic Basins, Elizabeth Rosa Woodford Ives

Theses and Dissertations

The Late Paleozoic Ice Age (LPIA; ~ 374 – 256 Ma) is the longest Phanerozoic icehouse interval. this interval in Earth’s history was largely defined by extensive glaciation of the southern hemisphere at both polar and temperate latitudes. Glaciers are powerful climatic and geologic actors, especially during icehouse periods, and widespread glaciation can have a significant influence on both regional and global climate and geology. Therefore, constraining the characteristics of LPIA glaciers is essential to developing a global-scale understanding of this key climatic event in Earth’s history. The manuscripts in this dissertation examine the sedimentology, transport directions, stratigraphy, and detrital …

Fluid Flow And Deformation: Exploring The Relationships Between Fluid Flow, Deformation Mechanisms, Quartz Crystallographic Preferred Orientation Fabric Development, And Kinematics In The Willard Thrust Fault, Utah, Falyn Strey

Theses and Dissertations

Thirty-four quartz-rich samples were collected across the Willard thrust fault in Utah to explore the effects that fluid has on faulting. In particular, the relationships between fluid, deformation mechanisms, crystallographic preferred orientation (CPO) fabric development, and kinematic vorticity were investigated. A petrographic analysis of all 34 samples determined the relative contributions of brittle fracturing, crystal plasticity, and diffusional processes along with their possible relation to fluid interaction. Crystal plasticity dominates throughout most of the field area except where significant contributions from diffusive deformation occurs in rocks with significant mica concentrations and fine grain sizes, especially those located near the fault. …

Fluvial And Sequence Stratigraphy Analysis Of The Hell Creek And Fort Union Formations To Test Models For Sedimentation Across The Cretaceous-Paleogene Boundary In Makoshika State Park, Glendive, Montana, Quintin Bendixen

Theses and Dissertations

The Cretaceous-Paleogene Boundary outcrops extensively throughout Makoshika State Park in Glendive, Montana. A distinct change in sedimentation style occurs across the Cretaceous- Paleogene in the Williston Basin deposits found in eastern Montana and western North Dakota. The well documented Hell Creek Formation of the Upper Cretaceous period consists of fresh and brackish water influenced deposits on the western low-lying coast of the Western Interior Seaway. The overlying Fort Union Formation consists of coals and fluvial sandstone deposits. Geologic explanations for the depositional shift include tectonic forces of the Sevier/Laramide Orogeny to the west, The Cretaceous-Paleogene Extinction Event, and the advancement …

Analyzing Strain Localization, Kinematic Partitioning And Fluid Flow In The Pulo Do Lobo Metasedimentary Rocks Along The Southern Iberian Shear Zone, Andalucia, Spain, Nancy Alejandra Carman

Theses and Dissertations

The Southern Iberian Shear Zone is a regional scale ductile shear zone that placed Beja-Acebuches metabasites over metapelite and quartzite rocks of the Pulo do Lobo Formation in a transpressional deformation with components of thrust and left-lateral movement. This project evaluates factors that contributed to strain localization at a variety of scales within the Pulo do Lobo formation, including lithologic variations, microstructures, and fluid flow. Additionally, microstructural data are used to test whether kinematic partitioning accompanied strain localization. Grain scale asymmetric indicators of sigma-type clasts, S-C fabrics, and asymmetric folds indicate dominant thrust motion. Strain intensity and metamorphic grade increase …

Surface Alteration In The Ölkelduháls, Nesjavellir, And Geysir Hydrothermal Systems, Iceland: Implications For Mars, Jordan Ludyan

Theses and Dissertations

Silica- and sulfate-rich deposits observed by Mars Exploration Rover (MER) Spirit near Home Plate, Gusev crater, Mars, indicate alteration of Mars basalt by a diverse array of hydrothermal fluids and processes. Constraining the precise fluid conditions present at the time of deposition for these deposits on Mars relies on investigations of terrestrial hydrothermal systems that produce similar mineral assemblages. Alteration products and fluids collected from the Ölkelduháls, Nesjavellir, and Geysir hydrothermal areas in southern Iceland cover a wide range of end-member and intermediate fluid and alteration environments, and provide a means to compare the secondary minerals produced from different hydrothermal …

Evaluating Hydration And Artificial Aging Effects On The Paleointensity In Natural Glass, Sebastian Fearn

Theses and Dissertations

Young natural volcanic glasses have been successfully used to recover Earth’s geomagnetic field intensity (paleointensity). However, the magnetic stability and reliability of volcanic glass as a paleomagnetic recorder over geologic time is unclear. Paleointensity estimates may be influenced by natural processes that alter magnetic mineralogy. Previous results from paleointensity and rock magnetic experiments suggest that post-emplacement hydrothermal alteration can alter the magnetic remanence and can possibly cause paleointensity experiments to fail. Low-temperature hydration and natural relaxation of the glass structure over time may also adversely impact paleointensity results. In this study, rhyolitic and basaltic glass specimens underwent artificial aging and …

Sedimentology, Sequence Stratigraphy, And High-Precision U-Pb Age Constraints On The Late Paleozoic Ansilta Formation, Calingasta-Uspallata Basin, Nw Argentina, John Ethan Malone

Theses and Dissertations

The Ansilta Formation, located several kilometers east of the Astronomical Observatory El Leoncito near Barreal, San Juan Province, Argentina was deposited during the late Mississippian to early Pennsylvanian. This succession includes glacimarine, nearshore, and fluvial systems deposited at the mid-Carboniferous portion of the late Paleozoic ice age within the Calingasta—Uspallata Basin on the western margin of the Protoprecordillera. The lower member of the Ansilta Formation is equivalent to the nearby Leoncito, Majaditas, and Hoyada Verde formations, and is composed of diamictite, conglomerates, sandstones, pebbly mudstones, and laminated mudstone. Glacial environments are unique in that facies changes occur as a result …

Late Paleozoic Climatic Reconstruction Of Western Argentina: Glacial Extent And Deglaciation Of Southwestern Gondwana, Kathryn N. Pauls

Theses and Dissertations

Throughout its history Earth has experienced both icehouse and greenhouse conditions. Shifts and transitions from one end member to the other are driven by numerous driving mechanisms on global, orbital and more local scales. In particular, the late Paleozoic ice age (LPIA) is thought to have been driven by global drivers such as the drift of the Gondwanan continent across the South Pole, fluctuations in atmospheric CO2 concentrations, and Milankovitch cycles. It was also affected by more local and regional drivers such as active tectonism along accretionary margins and changes in atmospheric and oceanic circulation patterns. South American Gondwana provides …

Water Chemistry And Lake Dynamics Of Laguna Bacalar, Quintana Roo, Mexico, Ryan Matzuk

Theses and Dissertations

Laguna Bacalar in the Quintana Roo region is the second largest lake in Mexico and contains freshwater derived solely from groundwater. Local geology on the Yucatan Peninsula is karstic and the southern shoreline of Laguna Bacalar is spotted with a handful of cenotes that contribute substantial amounts of inflowing groundwater to the lake. This is shown by sonde profile data taken in one of the largest cenotes in the area. Outflow is dominated by a surface water outlet in the southern portion of the lake and an unknown amount of outflowing groundwater. During January of 2017 through 2019, UWM researchers …

Characterization Of Water Pathways And Hydrolytic Weakening Within Naturally Deformed Quartz Grains Along The Willard Thrust Fault, Utah, Charles Alexander Martin

Theses and Dissertations

Evidence of water infiltration was examined in naturally deformed quartzite clasts from diamictite of the Mineral Fork Formation sampled from Antelope Island in the Great Salt Lake, Utah. The diamictite deformed via subsimple shear in the footwall of the Willard thrust fault and displays spatial variations in strain intensity. Evidence of water infiltration was investigated utilizing three complimentary techniques: standard petrographic microscopy to identify microstructures and interpret deformation mechanisms; scanning electron microscopy cathodoluminescence (SEM-CL) to create maps of healed microfractures and subgrain boundaries related to pathways of fluid infiltration; and synchrotron-source Fourier-transform infrared spectroscopy (FTIR) to create micron-scale water absorbance …

Simulating The Effects Of Urbanization And Climate Change On Ground Water Recharging Using The Usgs Precipitation And Runoff Modelling System (Prms), Kenneth Oanes

Theses and Dissertations

The Root River watershed, located in southeastern Wisconsin, was selected to be the subject of a study modeling the impacts of urbanization and climate change on groundwater recharge. Historical and projected (2035) land use data for the study area was sourced from the Southeast Wisconsin Regional Planning Committee (SEWRPC). The USGS Precipitation and Runoff Modelling System (PRMS) was selected to estimate recharge from a 35-year period of historical climate data (1980-2014). PRMS was run for the full 35-year time period under each land-use scenario and model outputs for evapotranspiration (ET), runoff, and recharge were calculated on a daily time-step.

Model …

A Feasibility Study Of Microbialites As Paleomagnetic Recorders, Ji-In Jung

Theses and Dissertations

Microbialites are carbonate organosedimentary deposits formed by benthic microbial communities that trap and bind detrital sediments, and/or inorganic and biologically influenced calcification. Any ferromagnetic particles incorporated into the microbialite structure have the potential to preserve variations in Earth’s magnetic field. A paleomagnetic record in microbialites would be useful for reconstructing the geomagnetic field because it may record at a high temporal resolution based on estimated growth rates, thus preserving relatively short-period variations of the Earth’s magnetic field. In addition, microbialites can be found in the geologic record going back ~3.5 Ga, hence potentially providing information on very ancient variations in …

Development Of A Hydrodynamic And Sediment Transport Model For Green Bay, Lake Michigan, Bahram Khazaei

Theses and Dissertations

Sediment dynamics are strongly linked with biogeochemical and physical changes in estuarine systems. Understanding the links between sediment processes and ecosystem responses is necessary for the restoration of degraded systems. Located in Northern US, and one of the largest freshwater estuaries on earth, Green Bay is a distinct example of these degraded systems. Rapid development and anthropogenic activities increased nutrient loading rates into the bay and led to a major disruption of the pre-existing biogeochemical regimes in the ecosystem. Contaminated and nutrient-rich sediments were discharged to the bay by the Fox River for almost half a century. Green Bay’s seasonal-, …

Pesticides In Urban/Suburban Water Wells In Milwaukee, Ozaukee, Washington, And Waukesha Counties In Wisconsin, Leslie Bychinski

Theses and Dissertations

The professional lawn care business has developed into a multibillion-dollar industry over the last few decades with a rise in home and garden market sector for urban/suburban use. Some homeowners purchase and apply the pesticides themselves while others hire professional lawn care companies. The US EPA states that “all pesticides are toxic to some degree” and the prevalent, widespread use of pesticides is both a major environmental problem and a public health issue. There have been many studies tracing agricultural pesticides application and contamination of public drinking water, and less on (sub)urban, residential pesticide application. This study targets active, private …