Physical Sciences and Mathematics Commons^™

Spatial And Seasonal Variability Of Dissolved Organic Matter In The Cariaco Basin, Laura Lorenzoni, Gordon T. Taylor, Claudia R. Benitez-Nelson, Dennis A. Hansell, Enrique Montes, Robert Masserini, Kent Fanning, Ramón Varela, Yrene Astor, Laurencia Guzmán, Frank E. Muller-Karger

Faculty Publications

[1] Dissolved organic carbon (DOC), nitrogen (DON), and phosphorus (DOP) were measured monthly at the CARIACO Time Series station (10°30′N, 64°40′W) in the southeastern Caribbean Sea between 2005 and 2012. Marked seasonal variability in DOC concentrations was observed, with lower values (~66 µM) in the upper water column (<75 >m) during the upwelling season (December–April) due to the injection of cool, DOC‐impoverished Subtropical Underwater from the Caribbean Sea. During the rainy season (May–November) waters were stratified and upper layer DOC concentrations increased to ~71 µM. Interannual variability in surface (1 m) concentrations of DOC was also observed in response to …

Biogenic Nitrogen Gas Production At The Oxic–Anoxic Interface In The Cariaco Basin, Venezuela, E. Montes, M. A. Altabet, F. E. Muller-Karger, M. I. Scranton, R. C. Thunell, Claudia R. Benitez-Nelson, L. Lorenzoni, Y. M. Astor

Faculty Publications

Excess nitrogen gas (N2xs) was measured in samples collected at six locations in the eastern and western sub-basins of the Cariaco Basin, Venezuela, in September 2008 (non-upwelling conditions) and March 2009 (upwelling conditions). During both sampling periods, N2xs concentrations were below detection in surface waters, increasing to ~ 22 μmol N kg−1 at the oxic–anoxic interface ([O2] < ~ 4 μmol kg−1, ~ 250 m). Below the oxic–anoxic interface (300–400 m), the average concentration of N2xs was 24.7 ± 1.9 μmol N kg−1 in September 2008 and 27.5 ± 2.0 μmol N kg−1 in March 2009, i.e., N2xs concentrations within this depth interval were ~ 3 μmol N kg−1 higher (p < 0.001) during the upwelling season compared to the non-upwelling period. These results suggest that N-loss in the Cariaco Basin may vary seasonally in response to changes in the flux of sinking particulate organic matter. We attribute the increase in N2xs concentrations, or N-loss, observed during upwelling to: (1) higher availability of fixed nitrogen derived from suspended and sinking particles at the oxic–anoxic interface and/or (2) enhanced ventilation at the oxic–anoxic interface during upwelling.

Tectonics Of The South Georgia Rift, David Michael Heffner

Theses and Dissertations

Triassic rifting of the supercontinent Pangea left behind numerous basins on what is now the eastern North American margin. The South Georgia Rift (SGR) was thought to be the best preserved of these basins having been capped by thick basalt flows of the Central Atlantic Magmatic Province (CAMP) and later buried beneath the Cretaceous and younger Coastal Plain. Because it is buried beneath the Coastal Plain, the SGR is only known through sparse drilling and geophysical methods. Despite this limited dataset, the SGR is the only one of the eastern North American Triassic basins known to overlie the ancient Alleghanian …

Benthic Boundary Layer Processes: Bedform Evolution And Bottom Turbulence, Timothy Robert Nelson

Theses and Dissertations

Bedform roughness, caused by ripples on the seabed, plays an important role in controlling sediment dynamics in the nearshore region. In this dissertation, the temporal and spatial evolution of ripples from two field sites located in the South Atlantic Bight, offshore Long Bay, SC and Georgia are used to relate wave-induced ripple geometry (wavelength and orientation) to near bed directional wave velocities. 2-D spectral analysis techniques were developed to automate detection of ripple wavelength, direction, and irregularity. This analysis showed that magnitude, direction, and duration of wave forcing controls ripple geometry and irregularity. During highly energetic events, ripple geometry changes …

Climate Change Effects On Vibrio Bacteria In The Winyah Bay Estuary And The Projected Spread Of Vibrio Under Future Climatic Scenarios., Reem Deeb

Theses and Dissertations

While there are several studies on the distribution ofVibrio vulnificusandVibrio parahaemolyticusin estuarine waters around the world, there is little information on the distribution of both organisms in South Carolina waters. Monthly sampling of surface and bottom water from 9 sites in Winyah Bay was conducted over the period April-October 2012. Both organisms were enumerated on CHROMagarVibriomedia. TheVibriocounts obtained were mainly less than 20 Colony Forming Units (CFU)/ml which is typical for what was found elsewhere along the coast of the Carolinas. TheVibrio vulnificuscounts were the highest when salinity ranged between 5 ppt and 20 ppt.Vibrio parahaemolyticusdid not show a clear …

Energy Metrics For State Government Buildings, Trevor Michael

Theses and Dissertations

Measuring true progress towards energy conservation goals requires the accurate reporting and accounting of energy consumption. An accurate energy metrics framework is also a critical element for verifiable Greenhouse Gas Inventories. Energy conservation in government can reduce expenditures on energy costs leaving more funds available for public services. In addition to monetary savings, conserving energy can help to promote energy security, air quality, and a reduction of carbon footprint. With energy consumption/GHG inventories recently produced at the Federal level, state and local governments are beginning to also produce their own energy metrics systems.

In recent years, many states have passed …

Identifying Values And Benefits Of Congaree National Park, Maka Bitsadze

Theses and Dissertations

Protected areas are important tools for the conservation of biological diversity. They also support a wide range of ecosystem services and provide economic, cultural and social values and benefits. Many values and benefits of protected areas are poorly understood and greatly under-valued by decision-makers, the business sector, and the general public. Accordingly, identification and assessment of values and benefits of protected areas has been increasingly promoted during recent years.

This research investigates values and benefits of Congaree National Park and provides guidance for the further economic valuation of identified values and benefits. While the ecological significance of Congaree National Park …

Volcanic And Tectonic Processes Along Anomalous Mid-Ocean Ridges, Julia Kathryn Howell

Theses and Dissertations

The morphological and structural characteristics of the global spreading ridge system are systematically related to spreading rate and magma supply (e.g. Macdonald, 1982). Because intermediate spreading-rate ridges (ISRs) spreading between 60 and 80 mm/yr have characteristics of both fast and slow spreading ridges, they are ideal environments to study the differences controlling upper crustal accretion. We examine the distribution of seamounts along spreading ridges to understand the relationship between seamount volcanism and axial morphology along four ISRs: the Juan de Fuca Ridge (JdFR), the Galápagos Spreading Centers (GSC), the Southeast Indian Ridge (SEIR), and the Eastern Lau Spreading Centers (ELSC). …

Thermal History Of Nearly Metamict Zircon Of The Taza-Guercif Basin (Morocco) Revealed Using Scanning Electron Microscope High-Density Fission-Track Dating, Tyler Michael Izykowski

Theses and Dissertations

Northwest Africa provides unique insight into a wide range of geologic processes throughout a vast portion of Earth's history. Moroccan geology in particular can provide valuable insight, from the formations of West Africa through the Eburnian orogeny (~2000 Ma), Gondwana during the Pan-African orogeny (~900-500 Ma), and Pangaea by means of the Hercynian (Variscan) orogeny (~400-300 Ma), to more recent crustal and climatic events, such as the Messinian salinity crisis (5.96-5.33 Ma). However, the current lack of western literature regarding this region presents a significant obstacle in understanding the aforementioned processes. Herein, I employ a new technique in zircon fission-track …

Geochemical Source Components In Seafloor Lavas In The Aleutian Back-Arc, Max Thomas Siegrist

Theses and Dissertations

Whole-rock compositions of seafloor lavas are used to constrain the processes and source characteristics contributing to the formation of geochemically distinctive, primitive magma types located in the Aleutian back-arc. Samples were dredged primarily from small volcanic cones on the seafloor, located between the emergent volcanoes and in the back-arc up to 60 km from the volcanic front. Compositions vary from basalt to dacite, with 48-70 % SiO₂ and 4-13 % MgO. Nearly 30% of the samples are primitive, with Mg/Mg+Fe >0.60. Most primitive samples are basalts, which fall into two groups, based on minor and trace element abundances. Low/med-K …

Drought Indices In Decision-Making Process Of Drought Management, Ekaterina Negodyaeva Altman

Theses and Dissertations

Drought indices are one of the most important elements of an effective drought monitoring and early warning system. They help to characterize drought and guide appropriate responses to reduce drought impacts. Drought indicators are more useful than raw data in decision-making process, even though each index has specific use and limited by its strengths and weaknesses. The literature review showed the evaluation of drought conditions by decision-makers as an important issue, but so far no research has been done to understand how decision-makers use diverse and often conflicting values of drought indices to make drought declarations. This research studies how …

The Effects Of Mean Sea Level And Tidal Amplitude On Ground Water Discharge And Pore-Water Salinity Distribution Along A Forest/Marsh Boundary, North Inlet, Sc, John Bradley Peurifoy

Theses and Dissertations

Advective groundwater flow in salt marshes is an important mechanism through which nutrients are exported to adjacent coastal waters. Groundwater flow also influences the distribution of pore-water salinity in the subsurface marsh, which affects botanical zonation, nutrient transport, and primary productivity. Recent idealized marsh island simulations have suggested that increases in tidal amplitude result in increased groundwater discharge, and that the elevation of MWL relative to the marsh platform is inversely related to groundwater discharge. These simulations were only representative of marsh islands (as opposed to forest-marsh boundaries) and relied on simulated tides and MWL position. The results were not …

Amplitude Vs. Offset Effects On Gas Hydrates At Woolsey Mound, Gulf Of Mexico, Walter R. Anderson

Theses and Dissertations

Due to the estimated massive quantities of natural methane hydrates, they represent one of the largest sources of future alternative energy on Earth. Methane hydrates have been found in the shallow sub-seafloor of the Northern Gulf of Mexico where the water depth is in excess of ~900 m. Mississippi Canyon Block 118 has been chosen by the Gulf of Mexico Hydrates Research Consortium to be the site of a multi-sensor, multi-discipline sea-floor observatory for gas hydrate research. First evidence for gas hydrates at MC 118 was observed at Woolsey Mound. Subsurface evidence for gas hydrates has subsequently been substantiated by …

Tidal Flux Of Trace Metals And Rare Earth Elements In A Barrier Island Salt Marsh, Ryan Antle

Theses and Dissertations

Barrier island salt marshes are known as sources of nutrients to the coastal ocean but it is unclear whether they are also sources or sinks of trace metals in regards to coastal waters. Salt marshes are characterized by steep redox and biogeochemical gradients, which constantly fluctuate as a result of tidal pumping. While several studies have examined metal budgets between terrestrial fresh water, estuarine subterranean fluids, and coastal saline waters, there is little data regarding fluid chemistry for metals in salt water estuaries in the absence of fresh water input. This study investigated a back barrier salt marsh on Cabretta …

Subsurface Imaging And Petrophysical Analysis Of The South Georgia Rift Basin, South Carolina, Olusoga Martins Akintunde

Theses and Dissertations

The Triassic-Jurassic South Georgia Rift (SGR) basin, buried beneath Coastal Plain sediments of southern South Carolina, southeastern Georgia, western Florida, and southern Alabama, consists of an assemblage of continental rift deposits (popularly called red beds), and mafic igneous rocks (basalt flows and diabase sills). The red beds are capped by basalts and/or diabase sills, and constitute the target for supercritical CO2 storage as part of a Department of Energy funded project to study feasibility for safe and long-term sequestration. This study addresses key stratigraphic, structural and petrophysical issues critical to determine subsurface suitability for CO2 storage as well as improved …