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Full-Text Articles in Physical Sciences and Mathematics
A New Method Of Synthesizing Black Birnessite Nanoparticles: From Brown To Black Birnessite With Nanostructures, Shizhi Qian, Marcos A. Cheney, Pradip K. Bhowmik, Sang W. Joo, Wensheng Hou, Joseph M. Okoh
A New Method Of Synthesizing Black Birnessite Nanoparticles: From Brown To Black Birnessite With Nanostructures, Shizhi Qian, Marcos A. Cheney, Pradip K. Bhowmik, Sang W. Joo, Wensheng Hou, Joseph M. Okoh
Mechanical Engineering Faculty Research
A new method for preparing black birnessite nanoparticles is introduced. The initial synthesis process resembles the classical McKenzie method of preparing brown birnessite except for slower cooling and closing the system from the ambient air. Subsequent process, including wet-aging at 7◦C for 48 hours, overnight freezing, and lyophilization, is shown to convert the brown birnessite into black birnessite with complex nanomorphology with folded sheets and spirals. Characterization of the product is performed by X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), thermogravimetric analysis (TGA), and N2 adsorption (BET) techniques. Wet-aging and lyophilization times are shown to …
Ascent And Decompression Of Viscous Vesicular Magma In A Volcanic Conduit, Helene Massol, Claude Jaupart, Darrell Pepper
Ascent And Decompression Of Viscous Vesicular Magma In A Volcanic Conduit, Helene Massol, Claude Jaupart, Darrell Pepper
Mechanical Engineering Faculty Research
During eruption, lava domes and flows may become unstable and generate dangerous explosions. Fossil lava-filled eruption conduits and ancient lava flows are often characterized by complex internal variations of gas content. These observations indicate a need for accurate predictions of the distribution of gas content and bubble pressure in an eruption conduit. Bubbly magma behaves as a compressible viscous liquid involving three different pressures: those of the gas and magma phases, and that of the exterior. To solve for these three different pressures, one must account for expansion in all directions and hence for both horizontal and vertical velocity components. …