Physical Sciences and Mathematics Commons^™

Catechol Effected Dissolution Of Silicate Minerals, James Maurice Kelley

Dissertations and Theses

The chemical properties of guanidinium tris(catecholato)siliconate, [(H₂N)₂C=NH₂]₂[Si(C₆H₄O₂)₃]·XH₂O (0 < X < 1), precipitated from an ammoniacal solution of silica and catechol by adding guanidinium hydrochloride, (H₂N)₂C=NH·HC1, were studied, and infrared, nmr, x-ray powder diffraction, and analytical data were gathered.

This same compound was, upon addition of' (H₂N)₂C=NH·HC1, isolated from 0.25, M aqueous catechol solutions buffered at pH 10 and containing the silicate minerals albite, andradite, muscovite, pyrophyllite, talc, and wollastonite, and also from unbuffered catechol solutions containing wollastonite and andradite.

It is concluded from this work that the formation of an anionic catechol-silicon complex, Si(C₆H₄O₂)₃²⁻, is largely responsible for the dissolution of the minerals mentioned above. From this conclusion, it is proposed that naturally occurring members of the class of organic compounds to which catechol belongs, the aromatic v̲i̲̲c̲-diols, may play …

The Geology Of The Southeast Quarter Of The Bone Mountain Quadrangle, Oregon, Richard Cortland Kent

Dissertations and Theses

This thesis is a study of the geology of the southeast quarter of the Bone Mountain Quadrangle. The bedrock geology mapped includes about 56 square miles.The Klamath Mountain and Coast Range Provinces of southwestern Oregon are represented in the area. Rocks in the area include the Rogue, Dothan Riddle, Days Creek, upper member of the Umpqua and Tyee Formations. The ages of these rocks range from Late Jurassic to middle Eocene. Late Jurassic ultramafic and mafic intrusive rocks associated with the Rogue Formation occur in the Klamath Province. The metavolcanics of the Rogue Format ion and an associated linear belt …