Physical Sciences and Mathematics Commons^™

Re-Evaluating Missouri’S Strategic Element Potential: A Geochemical Study Of The Mesoproterozoic Fe-Cu-Co-Ree Deposits In Southeast Missouri, Usa, Brandon James Sullivan

Doctoral Dissertations

"Iron-oxide-copper-gold (IOCG) deposits are poorly understood mineral systems. For example, we do not know why Cu- and Co-rich IOCG deposits typically occur proximal to Fe ore deposits that are notably Cu and Co-poor, such as Iron Oxide Apatite (IOA) deposits. To better understand the formation of IOA and IOCG deposits in Missouri, USA, this PhD thesis examines the genesis of the Kratz Spring IOA and the Boss Central Dome IOCG deposits. This study presents the first constraints on formation conditions and fluid sources in the studied deposits using integrated petrographic, mineral composition, and Fe isotope analyses of oxide minerals. Observations …

Experimental Investigation Of High-Temperature Brine-Shale Interactions, Anna Atasha Hoffmann

Doctoral Dissertations

"Hydrofracturing (fracking), a common practice in the Petroleum Industry to induce or improve fluid flow in tight formations, creates chemical disequilibrium that further alters the porosity and permeability of host rocks and results in the production of saline and contaminated produced waters (PW). The PW of the Tuscaloosa Marine Shale (TMS) are Na-Ca-Mg-K-Cl brines with mean concentrations of approximately 16% Total Dissolved Solids (TDS) and circumneutral pH. Analysis of composition suggests the PW result from a 20 to 80% dilution of formation waters (relict brines of the Louann Salt) by fracking fluid. Trace element concentrations generally show moderate to strong …

Applied Geochemistry, Geochronology And Biostratigraphy: Case Studies From The 38th Parallel Structures In Missouri And Orange Basin, Offshore Western South Africa, Marissa Kay Spencer

Doctoral Dissertations

"The unique alignment of the Decaturville, Crooked Creek, and Weaubleau geological structures in central Missouri, three of nine known such structures along the 38th parallel in Illinois, Missouri, and Kansas, has puzzled geoscientists for decades. Research using palynology (palynomorphs and particulate organic matter) and radiometric dating of impact spherules were used to constrain age and a relationship between these enigmatic structures and infer their paleoenvironmental conditions. Novel melting damages, unique to impact, were documented in the palynomorphs in all the three structures. Early Ordovician acritarchs with melted processes correlate with ⁴⁰Ar-³⁹Ar stepwise heating age of impact spherules …

Hydroclimate Variability In Central America During The Holocene Inferred From Lacustrine Sediments In Lake Izabal, Eastern Guatemala, Edward Fernando Duarte

Doctoral Dissertations

"Holocene hydroclimate reconstructions have contributed to our understanding of the mechanisms controlling precipitation in Central America. Recent hydroclimate proxy records from the region, however, have revealed considerable spatiotemporal complexity in precipitation variability. This complexity is hypothesized to result from the interaction between multiple oceanic-atmospheric processes that converge in the region. This project analyzed three sediment cores from Lake Izabal, eastern lowland Guatemala, with the goal of understanding changes in precipitation, lake productivity, and lake water chemistry during the Holocene. Our proxy results indicate that precipitation in the region increased from the early to the middle Holocene, when Lake Izabal became …

Mantle Flow And Transition Zone Discontinuities Beneath The Carribean Plate: Constraints From Shear Wave Splitting And Receiver Function Analyses, Tu Xue

Doctoral Dissertations

"Azimuthal anisotropy quantified by teleseismic SKS, SKKS, PKS (“XKS”) and local S wave splitting parameters is used to investigate lithospheric deformation and asthenospheric flow beneath the boundary zone of the North American and Caribbean plates and adjacent areas. A total of 4915 XKS and 1202 pairs of local S wave splitting parameters were obtained at 24 broad band seismic stations. The XKS observations can be divided into two groups based on the spatial distribution of the resulting fast polarization orientations. Those observed on the Caribbean Plate are mostly WNW-ESE which are roughly trench-parallel. In contrast, the fast orientations observed on …

The Kanarra Fold-Thrust System -- The Leading Edge Of The Sevier Fold-Thrust Belt, Southwest Utah, William Joseph Michael Chandonia

Doctoral Dissertations

“The Jurassic to Eocene Sevier fold-thrust belt is the subject of continued scientific curiosity in tectonics, stratigraphy, and industry. Understanding its development in southwest Utah is hindered in part due to the multiple origins proposed for the Kanarra anticline, a major leading edge structure -- a drag fold along the Hurricane fault, Laramide monocline, Sevier fault propagation fold, or a combination of these -- which have confused its tectonic significance and regional context. This confusion results from the structural complexity of its exposed eastern limb, as well as displacement and burial of its crest and western limb beneath Neogene sediments …

Application Of Machine Learning In Geophysics: Ranking Teleseismic Shear Wave Splitting Measurements And Classifying Different Types Of Earthquakes, Yanwei Zhang

Doctoral Dissertations

"During the past decades, applications of Machine Learning have been explosively developed to solve various academic and industrial problems, and over-human performance has been shown in diverse areas. In geophysical research, Machine Learning, especially Convolutional Neural Network (CNN), has been applied in numerous studies and demonstrated considerable potential. In this study, we applied CNN to solve two geophysical problems, ranking teleseismic shear splitting (SWS) measurements and classifying different types of earthquakes.

For ranking teleseismic SWS measurements, we utilized a CNN-based method to automatically select reliable SWS measurements. The CNN was trained by human-verified teleseismic SWS measurements and tested using synthetic …

Depositional Conditions, Stratigraphic Evolution, And Allo- And Autogenic Controls Of Lower Permian Non-Marine Carbonate Rocks, Lucaogou Low-Order Cycle, Bogda Mountains, Nw China, Yiran Lu

Doctoral Dissertations

"The overall objective of this study is to interpret the depositional conditions of lacustrine carbonate deposits of the lower Permian Lucaogou low-order cycle in the greater Turpan-Junggar continental rift basin, NW China. The depositional environments of ten carbonate lithofacies in the Tarlong-Taodonggou half graben and the Zhaobishan section were interpreted. Allo- and autogenic factors were identified. They controlled characteristics and distribution pattern of carbonate deposits in regional and local scale, respectively. Allogenic factors include the amount and direction of regional siliciclastic input, basin geometry, cyclic humidity/aridity oscillation, temperature, and regional tectonics. Autogenic factors include local siliciclastic input, local topography, local …

Pressure Relief Wells: Analysis Of Subsurface Heterogeneity To Evaluate Relief Well Locations For Mississippi River Levees, Emma Marie Young

Masters Theses

“When designing pressure relief well systems, it is imperative to understand what major geomorphology and heterogenies features are present, such as buried oxbow lakes, especially when the feature is parallel to the source, such as the Mississippi River. When present, there is a notable greater increase in head pressures, especially on the landward tow of the levee. This can cause erosional features that originally thought of to have been protected from by installing pressure relief wells. When comparing the effective hydraulic conductivities of horizontal clay layers and vertical clay layers spanning the length of the model, little to no noticeable …

Using Lake Sediment Chemistry In The Exploration For Nickel Laterite Deposits In Tropical Regions, Gabriela Yvonne Ramirez

Masters Theses

"Developing reliable geochemical indicators to guide the search for ore deposits is a long-standing goal. This particularly applies to tropical regions that are often heavily vegetated which hampers boots-on-the ground exploration efforts. Here we present the preliminary results of a study that investigates the usefulness of lake sediment chemistry in the exploration for nickel laterite ore deposits in tropical regions using Lake Izabal, Guatemala, as a case study. Lake Izabal’s catchment area contains Ni laterite deposits along its northern shore, whereas no Ni-laterite discoveries have been made in the south except for a Ni mine in the southern region that …

Laterally Heterogeneous Seismic Anisotropy Investigated By Shear Wave Splitting Analyses, Yan Jia

Doctoral Dissertations

"Numerous geophysical studies suggest that seismic anisotropy is a nearly ubiquitous property of the Earth’s crust and upper mantle. In this study, we utilize the shear wave splitting technique to investigate the piercing-point-dependent azimuthal anisotropy beneath the northeastern edge of the Sichuan Basin in central China, and the spatial and temporal variations of anisotropy near the 2019 M7.1 Ridgecrest earthquake in California, respectively. A clear back azimuthal dependence of the splitting parameters and the lack of a 90° or 180° periodicity of azimuthal variation in the observed fast orientations provide strong evidence for the existence of piercing-point-dependent anisotropy beneath the …

Lithofacies Characterization Of Marine Shelf Shale And Implicaitons On Depositional Conditions And Processes On The Continental Shelf — A Case Study Of The Upper-Cretaceous Tuscaloosa Marine Shale In Louisiana And Mississippi, U.S.A., Efren Mendez Jr

Masters Theses

"The Upper Cretaceous Tuscaloosa Marine Shale (TMS) is an unconventional shale reservoir deposited on the continental shelf of the northern Gulf of Mexico Basin. Previous studies have focused on sequence stratigraphy, thermal modeling, and well-log correlations. However, a limited understanding of the stratigraphic heterogeneity of the TMS is yet to be studied. This study aims to characterize the stratigraphic heterogeneity of the TMS using core, petrographic, and well-log analyses to better understand the depositional conditions and processes that occur on the continental shelf. The TMS has been classified into four lithofacies of very fine sands – coarse silts (LF1), medium-fine …

Adsorption Of Arsenic Onto River Sediments, Leticia Augusta Dos Santos Ferreira

Masters Theses

“Previous studies have noted the relationship between shallow groundwater rich in sodium (Na) and bicarbonate (HCO₃) and elevated levels of dissolved arsenic. However, most experimental work on arsenic adsorption in the presence of HCO₃ and differing Na/Ca ratios has proven difficult to extrapolate to natural systems because of differences in tested mineral compositions and component concentrations. In this study, I performed a series of adsorption experiments using river sediments to evaluate the influence of HCO₃ and monovalent/divalent cations on the extent of arsenic adsorption onto natural sediment in groundwater.

Batch adsorption (kinetics, equilibrium, and metal loading) …

The Pilot Knob Magnetite, Pilot Knob Hematite, And Shepherd Mountain Iron Oxide Deposits In Southeast Missouri -- Local Expressions Of A Magmatic-Hydrothermal Plumbing System?, Bolorchimeg N. Tunnell

Doctoral Dissertations

“The Southeast Missouri Iron Metallogenic Province in the Midwestern USA contains seven major and several minor IOA/IOCG-type deposits, all of which are spatially associated with the early Mesoproterozoic (1.50-1.44 Ga) magmatism in the St. Francois Mountains terrane. This Ph.D. project focuses on the Pilot Knob deposits, i.e., the deeper largely massive Pilot Knob Magnetite (PKM) and the shallower Pilot Knob Hematite (PKH) deposits, and the Shepherd Mountain deposit that are located less than 2.1 km distance from one another. The first precise age for the formation of the PKM ore is constrained at 1438±5.8 Ma using apatite U-Pb method. Petrographic …

Preclassic Cultural Eutrophication Of Lake Petén Itzá, Lowland Guatemala, By The Early Maya Of Nixtun-Ch'ich', Brooke A. Birkett

Masters Theses

"Paleolimnological evidence indicates the ancient Maya transformed lowland terrestrial ecosystems by felling forest vegetation to construct large civic-ceremonial centers and expand agriculture. The effects of prehistoric Maya land alterations on lake trophic status, however, remain poorly understood. We analyzed a 515-cm-long sediment core from Lake Petén Itzá, lowland Guatemala, to infer paleoenvironmental changes resulting from Maya occupation of the riparian archaeological site of Nixtun-Ch'ich'. Substantial increases in charcoal and fecal stanol concentrations indicate Maya occupation of the Candelaria Peninsula by the late Early Preclassic period beginning ca. 1400 cal yr Before the Common Era (hereafter BCE), despite scant archaeological evidence …

Neogene Dinoflagellate Cysts From The Tropical Americas, Damian Cardenas

Doctoral Dissertations

"Marine palynomorphs, mainly dinoflagellate cysts and acritarchs, constitute excellent proxies for biostratigraphic and paleoceanographic studies in neritic sequences. Neogene marine palynological studies have mostly focused on the Northern Hemisphere, resulting in the scarcity of dinoflagellate cysts and acritarchs from tropical latitudes. Forty samples encompassing the late Chattian-late Burgidalian time interval (~24.1- 17.3 Ma) in the Southern Caribbean were analyzed for their marine palynological contents. A biostratigraphic scheme for the region is proposed and includes the upper Chattian-lower Aquitanian Minisphaeridium latirictum Interval Zone (~23.9-22.0 Ma), the upper Aquitanian Achomosphaera alcicornu Interval Zone (~22.0-20.3 Ma), and the Burdigalian Cribroperidinium tenuitabulatum Interval Zone …

Multiple Generations Of Phlogopite In An Alnöite Diatreme: Insights Into The Petrogenesis Of The Avon Alkaline Igneous Province, Missouri, Nathan Gregory Limbaugh

Masters Theses

“Alkaline Ultramafic Carbonatite (AUC) complexes, although rare, are valued for diamonds and REEs, and as windows into subcontinental and mantle processes as recorded by rock fabrics, mineral spatial relationships, and mineral compositions. We report specifically on olivine and phlogopite petrographic relationships and compositions from the Devonian alnoite diatreme-facies of the Avon Alkaline Igneous Province, Missouri. The diatreme alnoite is a mixture of domains of olivine magmaclasts (OM) set in a crystal-rich melilite matrix. OM are highly fractured, serpentinized olivine pseudomorphs with variable amounts of pristine olivine fragments. Larger olivine domains typically exhibit clear crystal faces and irregular “channels” indicative of …

Relationships Among Mineralogy, Geochemistry, And Oil And Gas Production In The Tuscaloosa Marine Shale, Hayley Roxana Beitel

Masters Theses

"The Tuscaloosa Marine Shale (TMS) is an unconventional shale reservoir located in southeast Louisiana and southwest Mississippi. Limited mineralogical and geochemical data for the TMS have been published. The data that do exist indicate that the formation is heterogeneous. Consequently, previous investigators and oil and gas companies have not managed to effectively link mineralogical and chemical changes to oil and gas production in the TMS. These linkages are critical to establish for future exploration efforts. In this study, we attempt to establish these relationships by gathering all existing mineralogical and chemical data in the TMS, including newly acquired data from …

Crustal And Upper Mantle Structure Beneath The Southeastern United States From Joint Inversion Of Rayleigh Wave Dispersion And Receiver Functions, Qiuyue Yang

Doctoral Dissertations

"In spite of numerous geophysical investigations have been conducted in southeastern United States, the structure and evolution of the crust and lithospheric mantle remain controversial due the thick sedimentary covers atop the crust of the coastal plains there. In this study, we use data from 186 broadband seismic stations belonging to the USArray Transportable Array to construct a 3-D shear wave velocity model for the southeastern United States for the top 180 km by a joint inversion of Rayleigh wave phase velocity dispersion and receiver functions. Our results show a clear spatial correspondence with major surficial geological features. A prominent …

Spatiotemporal Variations Of Upper Crustal Anisotropy Along The San Jacinto Fault Zone In Southern California And The Fairview Region In Central Oklahoma, Enyuan Jiang

Doctoral Dissertations

"To discern spatial and explore the possible existence of temporal variations of upper crustal anisotropy along an ~15 km section of the San Jacinto Fault Zone (SJFZ) in California, and in the Fairview, Oklahoma, region, we conduct systematic shear wave splitting (SWS) investigations using local S-wave data recorded by seismic stations. Strong spatial variations in crustal anisotropy are revealed by 1694 and 405 pairs of splitting parameters (including the fast polarization orientation and the splitting time), respectively. For both areas, for raypaths traveling through the fault zones, the fast orientations are parallel to the faults and may be attributed to …

Receiver Function Imaging Of The 410 And 660 Km Discontinuities And Seismic Azimuthal Anisotropy Revealed By Shear Wave Splitting Beneath The Australian Continent, Kailun Ba

Doctoral Dissertations

"The Australian continent is composed the of Precambrian cratons in the west and Phanerozolc orogens in the east. Despite numerous seismological studies, controversies remain regarding the structure, evolution, and dynamics of the crust and mantle beneath Australia. In this study, we used two techniques, receiver functions and shear wave splitting analyses, to investigate the topography of the mantle transition zone (MTZ) discontinuities and mantle seismic azimuthal anisotropy, respectively. We utilized P-to-S receiver functions to map the 410 and 660 km discontinuities bordering the MTZ. The discontinuity depths obtained show a systematic apparent uplifting for both discontinuities in central and western …

Spatial Variations Of Teleseismic P-Wave Attenuation And Scattering Beneath The Southeastern United States And The Malawi And Luangwa Rift Zones In East Africa, Ashutosh Shrivastava

Doctoral Dissertations

"Seismic attenuation is an important physical parameter for characterizing subsurface morphology and the thermal structure of the Earth’s crust and mantle. In this study, teleseismic P-wave amplitude spectra are used to examine the seismic attenuation beneath the southeastern United States and the Malawi and Luangwa rift zones in east African. The resulting seismic attenuation parameters (Δt*) reveal a systematic contrast between the Appalachian Mountains and the Gulf of Mexico Coastal Plain exhibiting high and low attenuation, respectively. Spatial coherency analysis of the Δt* observations suggests that the center of the low-attenuation layer is located within the uppermost mantle at about …

Mantle Flow Systems Associated With Slab Subduction And Absolute Plate Motion In Alaska Constrained By Shear Wave Splitting Analyses, Yuchen Yang

Doctoral Dissertations

"Alaska has long been recognized as a geologically complex region with a sharp contrast in tectonic activity between southern and northern Alaska. While the former is characterized by the subduction of the geometrically varying Pacific-Yakutat plate beneath the North American plate, the latter has a mostly stable cratonic setting. To investigate the mantle flow fields beneath Alaska and understand the influence of the subduction process on regional mantle dynamics, a total of 2790 pairs of well-defined teleseismic shear wave splitting (SWS) measurements recorded from 379 stations are obtained and analyzed. In addition, 247 pairs of SWS results from local earthquake …

Strain Partitioning Across The Polochic-Motagua Fault System In Guatemala: Insight From Kinematic Modeling, Qiaoqi Sun

Masters Theses

”The Polochic-Motagua Fault System in Guatemala is the on-land segment of the sinistral transform plate boundary between the North American Plate and the Caribbean Plate. Three major seismically active strike-slip faults in this fault system pose significant earthquake threats to surrounding populated cities. The assessment of seismic hazard requires a better understanding of the kinematics of the fault system. GPS monitoring indicates that seventy-five percent of the ~20 mm/yr. plate motion is accommodated by the Motagua Fault and less than twenty-five percent is accommodated by the Polochic Fault. However, the Polochic Fault documents a lateral offset of ~132 ± 5 …

An Integrated Wellbore Stability Study To Mitigate Expensive Wellbore Instability Problems While Drilling Into Zubair Shale/Sand Sequence, Southern Iraq, Ahmed Khudhair Abbas

Doctoral Dissertations

”The Zubair Formation is the most prolific reservoir in Iraq, which is comprised of sandstones interbedded with shale sequences. Due to the weak nature of the shale sequence, the instability of a wellbore is one of the most critical challenges that continuously appears during drilling across this formation. Historically, over 90% of wellbore problems in the Zubair Formation were due to wellbore instability. Problems associated with wellbore instability, such as tight hole, shale caving, stuck logging tools along with subsequent fishing, stuck pipe, and sidetracking result in increasing the non-productive time. This non-productive time has cost an enormous amount of …

The Role Of Tectonic Inheritance, Plate-Reorganization, And Magma Flare-Ups In The Evolution Of The Sevier Orogeny, J. Daniel Quick

Masters Theses

"The temporal and spatial distribution of strain associated with the Sevier Orogeny in western North America is significantly different in the southern end of the belt, at the latitude of Las Vegas, than further to the north at the latitude of Salt Lake City. Until this study, reasons for these differences were speculative as a lack of thrust kinematic data in the intervening region hindered along strike correlation across the belt. A crystallization age of 100.18 ± 14 0.04 Ma was determined for zircons extracted from a recently recognized ash fall tuff near the base of the synorogenic Iron Springs …

Predictive Geohazard Mapping Using Lidar And Satellite Imagery In Missouri And Oklahoma, Usa, Olufeyisayo B. Ilesanmi

Doctoral Dissertations

”Light Detection and Ranging (LiDAR) and satellite imagery have become the most utilized remote sensing technologies for compiling inventories of surficial geologic conditions. Point cloud data obtained from multi-spectral remote sensing methods provide a detailed characterization of the surface features, in particular, the detailed surface manifestations of underlying geologic structures. When combined, point clouds eliminate bias from visual inconsistencies and/or statistical values. This research explores the competence of point clouds derived from LiDAR and Unmanned Aerial Systems (UAS) as a predictive tool in evaluating various geohazards. It combines these data sets with other remote sensing techniques to evaluate the sensitivity …

Geophysical Characteristics Of Nickel And Copper Deposits In Wadi Al Khadra Prospect, Southwestern Of Saudi Arabia, Abdulrahman Ahmed Aljabbab

Doctoral Dissertations

“Three geophysical datasets (self-potential, magnetics, and time - domain electromagnetics) were acquired at Wadi Al Khadra Ni-Cu prospect in southwest Saudi Arabia, and were processed and interpreted for the Saudi Geological Survey. The primary objectives were to map the distribution of metallic mineralization, map structures, verify the integration of the geophysical interpretations and its signatures in conjunction with boreholes information, distinguish the similarities and differences in the integrated interpretation of geophysical data, and design optimal processing and interpretation data parameters. The self-potential tool was used to map the variation in natural surface potential differences to map lateral variations in the …

Aquatic Plants And Their Application To Successful Floating Treatment Wetlands, Katherine May Mazanec

Masters Theses

“This research aims to mitigate eutrophication of freshwater habitats affected by urban stormwater runoff. Two highly impacted urban ponds near the Missouri S&T campus in Rolla were the focus of this research on the application of floating treatment wetlands (FTWs). An FTW consists of a man-made floating mat that is planted with emergent or floating macrophytes. The plants grow on the mat and their roots extend into the water column below the mat. Plant tissues, especially roots in direct contact with the water, take up nutrients, act as biofilm growth sites, and may facilitate precipitation of nutrients. With urbanization, ponds …

Mineral Compositions Of Meteorite Samples Alha 77005, Nwa 7397, Nwa 5480, And Ausson: Implications For Geodynamic Processes On Their Parent Bodies And Meteorite Reclassification, Kaylin Agnata Tunnell

Masters Theses

“This study investigates the major, minor, and trace element compositions of minerals from a series of meteorites which represent different stages of planetary evolution including two sample from Mars (ALHA 77005 and NWA 7397), one sample from Vesta (NWA 5480), and one ordinary chondrite (Ausson). The goal of this study is to investigate if petrogenetic tracers commonly employed to understand terrestrial samples can also be applied to extraterrestrial samples. The data presented here show that mineral trace element data allow for novel insight into the magmatic history of meteorite samples. For example, V/Sc and Fe/Mn ratios in olivine provide insight …