Physical Sciences and Mathematics Commons^™

Silver Nanoparticle Transport Through Soil: Illuminating The Governing Pore-Scale Processes, Ian L. Molnar

Electronic Thesis and Dissertation Repository

Engineered nanoparticles are widely used and will eventually be released to the subsurface environment and contaminate groundwater resources. However, the transport of engineered nanoparticles through soil is currently not well understood and cannot be modelled in any fundamental manner, placing groundwater resources at risk from nanoparticle contamination. This inability to accurately simulate transport is due to a lack of experimental information on nanoparticle interactions in the pore spaces of real soils.

This thesis illuminates the pore-scale processes governing silver nanoparticle transport through soil. In addition, it examines the influence of surface chemistry and grain/pore distributions on those processes. For the …

Impacts Of Three-Dimensional Non-Uniform Groundwater Flows For Quantifying Groundwater-Surface Water Interactions Using Heat As A Tracer, Jonathan M. Reeves

Masters Theses

Heat-as-a-tracer has become a common method to quantify surface water-groundwater interactions (SW/GW). However, the method relies on a number of assumptions that are likely violated in natural systems. Numerical studies have explored the effects of violating these fundamental assumptions to various degrees, such as heterogeneous streambed properties, two-dimensional groundwater flow fields and uncertainty in thermal parameters for the 1-dimensional heat-as-a-tracer method. No work to date has addressed the impacts of non-uniform, three-dimensional groundwater flows on the use of heat-as-a-tracer to quantify SW/GW interactions. Synthetic temperature time series were generated using COMSOL Multiphysics for a three-dimensional cube designed to represent a …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Model Of Residence Time And Analysis Of Nitrogen Removal For Two Constructed Wetlands At The Franklin Demonstration Farm In Lexington, Illinois, Emma Singh Baghel

Theses and Dissertations

Pollution from nonpoint agricultural runoff has become a major problem facing our streams and rivers today. Not only are fish and aquatic life affected, but so is the quality of our drinking and recreational water resources. Studies have shown that wetlands have proven to be the most cost-effective and low maintenance method of removing nonpoint or diffused contaminate inputs. The biological processes and removal of nutrients in wetlands depend on the total surface area available for microbial activity in the soil and a certain period of water retention time. Since chemical processes take time, the measure of residence time is …

Quantifying Water Budgets To Evaluate The Hydrologic Performance Of Two Stormwater Detention Ponds In Coastal South Carolina, Samantha Corley

Electronic Theses and Dissertations

Due to their ability to reduce local flooding and protect receiving waters from intense stormwater pulses, stormwater detention ponds are commonly used stormwater management practices. Stormwater engineers construct ponds to moderate peak flow intensities and to allow residence time of the water within the pond to enhance nutrient removal prior to discharging into downstream ecosystems. Yet rarely, if ever, is the functionality of these ponds verified post-construction. This study aimed to compare hydrologic performance of two stormwater detention ponds located in coastal South Carolina to theoretical design plans by assessing a high resolution water budget. Inflow components of the water …

Characterization Of Groundwater Discharge In A Back Barrier Tidal Creek, Matthew L. Carter

Electronic Theses and Dissertations

Groundwater discharge in the coastal environment is known to be a complex process. The driving mechanisms of groundwater discharge vary on spatial and temporal scales that can significantly impact coastal water chemistry and play a role in ecological zonation. Evolving combinations of observational and modeling approaches provide a basis to quantify groundwater discharge in a spatial and temporal sense. Here we employ a combination of geochemical (naturally occurring radon isotope) and geophysical (electrical resistivity) techniques to measure groundwater-surface water interactions along a back-barrier tidal creek. In addition to field measurements, a unique non-steady state radon mass balance equation was developed …

Identifying A Mechanism For An Infiltration Threshold From The Sunflower River, Ms To The Underlying Alluvial Aquifer, Austin Cole Patton

Electronic Theses and Dissertations

Long-term groundwater level and stream stage measurements at a USGS coupled groundwater stream-gaging station located on the Sunflower River in Sunflower, MS show an apparent stage-threshold for infiltration to the underlying alluvial aquifer. This site is located near the center of a large regional groundwater cone of depression in the Mississippi River Valley alluvial aquifer. The USGS well (termed well 3 in this study) was thought to be completed in the regional shallow aquifer, though often recording anomalously high water levels relative to other wells in the region. The purpose of this research was to identify the responsible mechanism for …

Using Modflow To Predict Impacts Of Groundwater Pumpage To Instream Flow: Upper Kittitas County, Washington, Zoe O. Futornick

All Master's Theses

Surface waters in the Yakima River Basin in central Washington are considered over allocated. Since 1960, new water demands have been met through groundwater withdrawals, with most groundwater users holding a later priority date than senior and junior surface water users. As a result of the discussions surrounding this issue, the Upper Kittitas Groundwater Rule has been in effect since 2010. Pumping from new domestic (i.e., permit-exempt or “exempt”) groundwater wells in Upper Kittitas County is not allowed unless mitigation is used to offset the groundwater use. The United States Geological Survey (USGS) has already created a basin-wide model for …

The Effect Of Spatial Patterns Of Soil Hydraulic Conductivity And Depth On Local And Hillslope Scale Shallow Water Table Dynamics, Casey E. Ryan

Graduate Student Theses, Dissertations, & Professional Papers

Much research in forested headwater catchments has focused on the role of topography for organizing subsurface flow and the hydrologic connectivity of upland flow paths to stream networks. However, little work has been conducted to evaluate how localized and hillslope scale patterns of hydraulic conductivity and soil depth contribute to spatial patterns of water table duration, magnitude, and connectivity. I monitored shallow groundwater dynamics in wells distributed across a 1st order hillslope in the Lubrecht Experimental Forest, Montana. Additionally, I collected in-situ measurements of soil saturated hydraulic conductivity and soil depth at 10m intervals across the study hillslope and compared …