Physical Sciences and Mathematics Commons^™

Liberation Of Acidity And Arsenic From Schwertmannite: Effect Of Fulvic Acid, Chamindra Vithana, Leigh Sullivan, Edward Burton, Richard Bush

Chamindra Vithana

Schwertmannite is one of the major components that produces acidity in acid mine drainage (AMD) and acid sulfate soils (ASS) and is also known to be an effective scavenger of Arsenic (As) in such environments. Fulvic acid (FA) is an active component of natural organic matter (NOM) and is known to interact strongly with both schwertmannite and As. Two main environmental hazards related to schwertmannite are acidity liberation and potential re-mobilization of adsorbed or co-precipitated As upon hydrolysis. This study focused on understanding the behaviour of As-substituted schwertmannite with regard to the potential of acidity liberation, the effect of FA …

Assessment And Behaviour Of Secondary Iron(Iii) Minerals In Acid Sulphate Soil Materials, Chamindra Vithana

Chamindra Vithana

This study examined two aspects of acidity generating secondary Fe(III) minerals (i.e. schwertmannite and jarosite) in acid sulfate soils (ASS) environments: i) accurate identification and quantification, and ii) improving our understanding of their behaviour in ASS.The study showed that current assessment methods have a number of limitations and are not reliable for accurate estimation of both minerals in ASS environments. The study also showed that in natural environments, these minerals can behave in a manner different to current conceptual understanding. The broad implication of this study was identification of the need for development of improved management techniques for ASS.

Arsenic Mobilization In An Alluvial Aquifer Of The Terai Region, Nepal, Jasmine Diwakar, Scott Johnston, Edward Burton, Suresh Das Shrestha

Associate Professor Edward D Burton

Study Region

A shallow (<50 m) alluvial aquifer in the Terai region of Nepal.

Study Focus

We examine the hydrogeochemical characteristics of a shallow alluvial aquifer system in the Terai region (Nawalparasi district) to identify possible mechanisms and controls on geogenic As mobilization in groundwater. Groundwater and river water samples from a topo-gradient flow-path and floodplain of a minor river draining the Siwalik forehills were analyzed for physico-chemical parameters.

New Hydrological Insights for the Region

The aquifer is characterized by Ca-HCO₃ type water and is multi-contaminated, with the WHO guideline values exceeded for As, Mn and F in 80%, 70% and 40% of cases respectively. The middle portion …

Liberation Of Acidity And Arsenic From Schwertmannite: Effect Of Fulvic Acid, Chamindra Vithana, Leigh Sullivan, Edward Burton, Richard Bush

Associate Professor Edward D Burton

Schwertmannite is one of the major components that produces acidity in acid mine drainage (AMD) and acid sulfate soils (ASS) and is also known to be an effective scavenger of Arsenic (As) in such environments. Fulvic acid (FA) is an active component of natural organic matter (NOM) and is known to interact strongly with both schwertmannite and As. Two main environmental hazards related to schwertmannite are acidity liberation and potential re-mobilization of adsorbed or co-precipitated As upon hydrolysis. This study focused on understanding the behaviour of As-substituted schwertmannite with regard to the potential of acidity liberation, the effect of FA …

Arsenic Mobilization And Iron Transformations During Sulfidization Of As(V)-Bearing Jarosite, Scott Johnston, Edward Burton, Annabelle Keene, Britta Planer-Friedrich, Andreas Voegelin, Mark Blackford, Greg Lumpkin

Associate Professor Edward D Burton

Jarosite (KFe3(SO4) 2(OH)6) is an important host-phase for As in acid mine drainage (AMD) environments and coastal acid sulfate soils (CASS). In AMD and CASS wetlands, jarosite may encounter S(−II) produced by sulfate reducing bacteria. Here, we examine abiotic sulfidization of As(V)-bearing K-jarosite at pH 4.0, 5.0, 6.5 and 8.0. We quantify the mobilization and speciation of As and identify corresponding Fe mineral transformations. Sulfide-promoted dissolution of jarosite caused release of co-precipitated As and the majority of mobilized As was re-partitioned to a readily exchangeable surface complex (AsEx). In general, maximum As mobilization occurred in the highly sulfidized end-members of …