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Synthesis And Characterization Of Thermoelectric Nanomaterials, Kamal Kadel Mar 2014

Synthesis And Characterization Of Thermoelectric Nanomaterials, Kamal Kadel

FIU Electronic Theses and Dissertations

As existing energy sources have been depleting at a fast pace, thermoelectric (TE) materials have received much attention in recent years because of their role in clean energy generation and conversion. Thermoelectric materials hold promise in terrestrial applications such as waste heat recovery. Bismuth selenide (Bi2Se3), lead telluride (PbTe), skutterudites CoSb3, and Bi-Sb alloys are among the widely investigated thermoelectric materials.

Synthesis of above mentioned thermoelectric materials in nanostructured form and their characterization were investigated. Highly crystalline Bi2Se3, undoped and indium (In) doped PbTe, unfilled and ytterbium (Yb) filled CoSb …


Synthesis And Electron Emission Properties Of Aligned Carbon Nanotube Arrays, Suman Neupane Feb 2014

Synthesis And Electron Emission Properties Of Aligned Carbon Nanotube Arrays, Suman Neupane

FIU Electronic Theses and Dissertations

Carbon nanotubes (CNTs) have become one of the most interesting allotropes of carbon due to their intriguing mechanical, electrical, thermal and optical properties. The synthesis and electron emission properties of CNT arrays have been investigated in this work. Vertically aligned CNTs of different densities were synthesized on copper substrate with catalyst dots patterned by nanosphere lithography. The CNTs synthesized with catalyst dots patterned by spheres of 500 nm diameter exhibited the best electron emission properties with the lowest turn-on/threshold electric fields and the highest field enhancement factor. Furthermore, CNTs were treated with NH3 plasma for various durations and the …