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Condensed Matter Physics

Arts & Sciences Electronic Theses and Dissertations

2020

Nucleation

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Full-Text Articles in Physical Sciences and Mathematics

Studies Of Maximum Supercooling And Stirring In Levitated Liquid Metallic Alloys, Mark Edward Sellers May 2020

Studies Of Maximum Supercooling And Stirring In Levitated Liquid Metallic Alloys, Mark Edward Sellers

Arts & Sciences Electronic Theses and Dissertations

Nucleation—or the formation of some cluster in a medium undergoing a phase transition—is usually the initial step in a phase transition. However, this process is still not fully understood, as outstanding questions related to the role of structure, local order, and diffusion remain unanswered. Systematic supercooling studies on metallic liquids performed using electrostatic and electromagnetic (ESL and EML, respectively) will be presented and discussed within the context of several nucleation theories, such as the Classical Nucleation Theory, Diffuse Interface Theory, and Coupled-Flux theory. To study the role of diffusion on nucleation, studies on the International Space Station using the on-board …


Thermophysical Properties And Phase Transformations In Metallic Liquids And Silicate Glasses, Daniel Christian Van Hoesen May 2020

Thermophysical Properties And Phase Transformations In Metallic Liquids And Silicate Glasses, Daniel Christian Van Hoesen

Arts & Sciences Electronic Theses and Dissertations

The first quantitative measurements of the electrical resistivity in binary metallic liquids, used to probe local order in the liquid, are reported in this dissertation. The electrical resistivity is very sensitive to short and medium range ordering because the electron mean free path is approximately the same length scale as the atomic spacing. Particular attention is given to the resistivity value at a crossover temperature that, based on molecular dynamics (MD) simulations, is the onset of cooperative motion in liquid alloys. Experimental evidence for the crossover is found in measurements of the shear viscosity, a dynamical property. An indication of …