Physical Sciences and Mathematics Commons^™

Ligand-Promoted Dissolution Of Uranyl Phosphate Across Scales, Brennan Ferguson

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The formation of uranyl phosphate precipitate is a remediation strategy because the low solubility of uranyl phosphate minerals, like chernikovite, limits the mobility of uranium in contaminated soils. However, organic ligands can complex with aqueous metal cations to form more soluble species. For example, citrate is a commonly occurring organic ligand produced by plants and microbes that increases the solubility of uranium and therefore the dissolution of uranyl phosphate minerals in the uranyl phosphate-citrate system. This effect is an important control on the mobility of uranium in organic-rich, and near-surface vegetated environments. Nevertheless, key aspects of the citrate-uranyl phosphate system …

Mysteerio: Multi-Regional Environmentally Extended Input-Output Model For United States, Yash Srivastava

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This research work titled My State Environmentally Extended Regional Input-Output (MYSTEERIO) is based on the concept of multi-regional environmentally extended input-output (MREEIO), which is a combination of lifecycle thinking and economics principles. Numerous studies have highlighted the advantages of using this methodology to determine the environmental impacts associated with economic activities for a region. However, no prior attempt has been made to conduct a state-level analysis for the US. This research work thus tries to estimate the impacts embodied due to the consumption of goods and services at the state level by using the MREEIO principles. Extensive coverage of the …

Geology-Based Shear-Wave Velocity Model Of Reference Site Conditions In South Carolina For Seismic Site Response Analysis, Camilius Amevorku

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Assessing earthquake hazard in the State of South Carolina is important because it is one of the most seismically active regions of the eastern United States and has experienced earthquakes of damaging levels in the historical past. Examples of these damaging seismic events are the 1886 Charleston earthquake (M 6.7 to 7.5) and the 1913 Union County earthquake (M 4.5 to 5.5).

Small-strain shear-wave velocity (V_S) is an important parameter in performing site response analysis. The deep nature of the top of reference firm rock (i.e., V_S ≥ 760 m/s or B-C boundary) due to …

Application Of A 14c-Assay To Assess Methanotrophic Biodegradation Of Tce In Low Ph Groundwater, Evan Groome

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Current biological strategies for remediating trichloroethylene (TCE) in low pH aquifers (i.e., pH14C-TCE assay was developed to determine pseudo first-order rate constants for the degradation of TCE in microcosms containing soil and groundwater from the Boeing Michigan Aeronautical Research Center (BOMARC) superfund site, where the pH ranges from 4.1 to 4.9. The ¹⁴C-TCE assay was also adapted to calculate soil-normalized rate constants for data from this site, as well as data that Szwast²¹ collected from the Beltsville Agricultural Research Center (BARC). In addition to natural attenuation, biostimulation through amendments of methane and nutrients were also assessed. This treatment …

Characterization Of Water Flow And Solute Transport Driven By Preferential Flow In Soil Vadose Zone, Abdullah Al Mamun

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The vadose zone acts as a buffer zone between the ground surface and the aquifers underneath and controls the transmission of infiltrating water and contaminants, for example, pesticides and chemical spills. Therefore, understanding the flow and transport processes that dominate the vadose zone is important. Macropores are ubiquitous and particularly found in abundance in the vadose zone. These macropores facilitate preferential flow, through which water travels rapidly deep into the soil, bypassing most of the porous matrix. Preferential flow and transport have environmental significance as their processes impact hydrology, ecology, agriculture, subsurface contamination, and waste management sectors. Thus, the overall …

Floating Treatment Wetlands For Brackish Waters: Plant Selection And Nutrient Uptake Potential., Andrea Landaverde

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Brackish water bodies in coastal regions provide critical ecosystem services that support human and environmental health. Anthropogenic activities such as agricultural and industrial activities, construction, urban settlements, and tourism contribute to increased inputs of nitrogen (N) and phosphorus (P) in brackish coastal ecosystems. Excess nutrients can lead to impaired water quality and affect marine organisms. Floating treatment wetlands (FTWs) are a vegetated-base technology used to remove contaminants from water column, that has been mainly studied and applied in freshwater systems. Application of FTWs in brackish systems requires further investigation, as high salinity in brackish waters could result in toxicity to …

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

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Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

Wetland Uranium Transport Via Iron-Organic Matter Flocs And Hyporheic Exchange, Connor J. Parker

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Uranium (U) released from the M-Area at the Department of Energy Savannah River Site into Tims Branch, a seasonal wetland and braided stream system, is estimated to be 43,500 kg between 1965 and 1984. The motivation for this work is the uranium’s persistence in the wetland for decades, where it is estimated that 80% of the U currently remains in the Tims Branch wetland. U has begun to incorporate into wetland iron (Fe) and carbon cycles, associating with local Fe mineralogy and deposits of rich wetland organic matter (OM). The objective of this work is to characterize the chemical phases …