Physical Sciences and Mathematics Commons^™

Bioremediation Of Petroleum Hydrocarbons In Coastal Sediments, Charbel Abou Khalil

Dissertations

The biodegradation of dispersed crude oil in the ocean is relatively rapid (a half-life of a few weeks). However, it is often much slower on shorelines, usually attributed to low moisture content, nutrient limitation, and higher oil concentrations in beaches than in dispersed plumes. Another factor may be the increased salinity of the upper intertidal and supratidal zones since these parts of the beach are potentially subject to prolonged evaporation and only intermittent inundation. Therefore, two laboratory experiments are conducted to investigate whether such an increase in porewater salinity results in additional inhibitory effects on oil biodegradation in seashores.

In …

Planning Methodology For Alternative Intersection Design And Selection, Liran Chen

Dissertations

The recent publication of the 6th Edition of the Highway Capacity Manual included a chapter on Ramp Terminals and Alternative Intersections that introduces various alternative intersection designs and assesses the performance of Median U-turn, Restricted crossing U-turn and Displaced left-turn intersections. Missing from the literature is an alternative intersection selection tool for identifying whether an alternative intersection would be successful under local conditions. With limited information of organized alternative intersection research, most planners must rely heavily on their personal judgement while selecting the most suitable intersection designs. As appealing as alternative intersections are, there is no comprehensive methodology for planners …

A Self-Learning Intersection Control System For Connected And Automated Vehicles, Ardeshir Mirbakhsh

Dissertations

This study proposes a Decentralized Sparse Coordination Learning System (DSCLS) based on Deep Reinforcement Learning (DRL) to control intersections under the Connected and Automated Vehicles (CAVs) environment. In this approach, roadway sections are divided into small areas; vehicles try to reserve their desired area ahead of time, based on having a common desired area with other CAVs; the vehicles would be in an independent or coordinated state. Individual CAVs are set accountable for decision-making at each step in both coordinated and independent states. In the training process, CAVs learn to minimize the overall delay at the intersection. Due to the …

Reactive Iron Mineral Coatings In Redox Transition Zones Of A Site With Historical Contamination: Abiotic Attenuation, Xin Yin

Dissertations

Reactive iron mineral coatings are found throughout reduction-oxidation (redox) transition zones and play a significant role in contaminant transformation processes. In this study, an 18.3-meter core is collected, subsampled, and preserved under anoxic conditions to maintain its original redox state. Screening analyses are conducted at sampling increments of 5.08 cm in depth for the following: elemental concentrations with X-ray fluorescence (XRF), sediment pH, sediment oxidation-reduction potential (ORP), total volatile organic carbon (TVOC) in the sample headspace, and abundant bacteria (16S rRNA sequencing). Using the Fe and S gradients correlated with microbial data, five RTZs are delineated. To characterize iron mineral …

Shale Softening Based On Pore Network And Laboratory Investigations, Di Zhang

Dissertations

This dissertation consists of two major parts: Firstly, experimental investigation of four major shale softening mechanisms and quantifications of structural parameters. Secondly, numerical simulations of nano-scale flow behaviors using the previous experiments determined parameters based on modified pore network modeling.

Hydraulic fracturing is widely applied to economical gas production from shale reservoirs. Still, the gradual swelling of the clay micro/nano-pores due to retained fluid from hydraulic fracturing causes a gradual reduction of gas production. Four different gas-bearing shale samples are investigated to quantify the expected shale swelling due to hydraulic fracturing. These shale samples are subject to heated deionized (DI) …

Analysis Of Container Throughput: Demand Forecast And Seaport Competitiveness Assessment, Hussain Talat Sulaimani

Dissertations

Seaports play a crucial role in the container industry, where they act as important nodes in the transport chain to facilitate international trade. In a competitive market, port capacity plays a significant role in defining its competitive position to attract demand and avoid congestion. Failing to provide suitable capacity results in the loss of market share. Therefore, port decision-makers face the challenge of maintaining and developing suitable port facilities to provide efficient services to port users. One of the aspects that decision-makers consider in the planning and development process is analyzing container demand. The analysis of container demand can be …

Safe Yield Comparisons For The 1960’S And 2000’S Drought In The Passaic River Basin, Stephanie R. Santos

Dissertations

The Passaic River Basin is a complex system of rivers, tributaries, reservoirs, and some of the largest water purveyors in the State of New Jersey. Located in the northeastern part of the State, it drains approximately 800 square miles of water that is used for distribution to the five major purveyors: North Jersey District Water Supply Commission, Passaic Valley Water Commission, Jersey City, Newark, and New Jersey American Water. These purveyors operate under a safe yield, which is defined by the New Jersey Department of Environmental Protection (NJDEP) as the amount of water that should be continuously available should the …

Optimizing Work Zone Schedules Considering Traffic Diversion With Artificial Bee Colony Algorithm, Celina Semaan

Dissertations

Highway maintenance activities often decrease roadway capacity and intrude traffic movements. The need to finish the project on time and under a specific budget while minimizing the traffic congestion and complying with the emission standards requires an appropriate work zone schedule optimization. The objective of this research is to improve the efficiency of work zone activities and minimize the total project cost including maintenance, user, and emission cost.

While previous studies investigated the work zone optimization problem, they did not consider the implementation of emission standards nor applied a green diversion strategy. This dissertation analyzes the optimization of work zone …

A Deep Machine Learning Approach For Predicting Freeway Work Zone Delay Using Big Data, Abdullah Shabarek

Dissertations

The introduction of deep learning and big data analytics may significantly elevate the performance of traffic speed prediction. Work zones become one of the most critical factors causing congestion impact, which reduces the mobility as well as traffic safety. A comprehensive literature review on existing work zone delay prediction models (i.e., parametric, simulation and non-parametric models) is conducted in this research. The research shows the limitations of each model. Moreover, most previous modeling approaches did not consider user delay for connected freeways when predicting traffic speed under work zone conditions. This research proposes Deep Artificial Neural Network (Deep ANN) and …

Characterizing Reactive Iron Mineral Coatings And Their Roles In Natural Attenuation At A Site With Historical Contamination, Han Hua

Dissertations

Reactive iron mineral coatings in redox transition zones play an important role in contaminant attenuation. These mineral coatings include poorly crystalline to crystalline iron sulfides, carbonates, and oxyhydroxides, and are a signature of the biogeochemical processes occurring. To better understand these processes, reactive iron mineral coatings are characterized in an 18-m Anaerobic Core collected from a contaminated industrial site. This study targets redox transition zones uncovered in the core. A suite of complementary analyses is applied to distinguish the surface coating mineralogy using X-ray Diffraction, X-ray fluorescence, and field-emission scanning electron microscopy (FESEM) with energy dispersive X-ray analyzer (EDX). In …

Compound Flooding In Coastal Areas Emanating From Inland And Offshore Events, Hamed Behzad Koochaksaraii

Dissertations

The vulnerability of urban populations to natural hazards and climate change is a major theme in many reports on coastal cities with flooding ranking highly among the climate change concerns. Flooding could occur as a result of runoff for inland rainfall that accumulates at the mouth of the estuary to the sea or it could occur due to a storm surge emanating from the ocean. The techniques for modeling the flooding from these events are very different, as they were developed in different scientific fields: hydrology and hydraulic engineering for inland rainfall versus coastal oceanography and coastal engineering for offshore …

Stress-State And Injection-Rate Dependent Damage Processes During The Hydraulic Fracturing Of Granite, Gayani Sasendrika Gunarathna

Dissertations

Hydraulic fracturing is a well-stimulation technique that is employed in field applications, such as enhanced geothermal systems (EGS) and shale oil/gas extraction. This research experimentally investigates the effect of the state of stress and injection rate on the hydraulic fracturing processes. In addition, a displacement discontinuity method (DDM) code, FROCK, is used to model the crack initiation and propagation in a granite specimen under hydraulic fracturing conditions. In order to conduct the experimental work, a test setup capable of applying a triaxial state of stress and water pressure inside pre-fabricated flaws cut in prismatic granite specimens is developed. Additionally, the …

Numerical And Analytical Methods To Predict Behavior Of Reinforced Ductile Concrete Composites, Mandeep Pokhrel

Dissertations

Structural components constructed with ductile concrete composites, such as high-performance fiber-reinforced cementitious composites (HPFRCC), are known to perform exceptionally well under extreme mechanical and environmental loading conditions compared to traditional concrete. HPFRCC flexural components exhibit enhanced performance in terms of displacement ductility, energy dissipation capacity, and damage tolerance capacity. However, recent research suggests that the flexural behavior of reinforced HPFRCCs in terms of crack progression, reinforcement plasticity, and failure mechanism is significantly different than conventional reinforced concrete. Specifically, the failure mode of flexural members is found to be predominantly through the fracture of longitudinal reinforcement rather than compression crushing of …

Effects Of Electro-Osmotic Consolidation Of Clays And Its Improvement Using Ion Exchange Membranes, Lucas Martin

Dissertations

Electro-osmosis is an established method of expediting consolidation of soft, saturated clayey soils compared to commonly used methods, such as preloading with wick drains. In electro-osmotic consolidation a direct current (DC) is applied via inserted electrodes. This causes hydrated ions in the interstitial fluid to migrate to oppositely charged electrodes. Because the clay particles have a negative surface charge, the majority of ions in the interstitial fluid are positively charged. Therefore, the net flow will be towards the negatively charged electrode (cathode), where the water can be removed and thus consolidation is achieved. Certain problems, such as pH changes in …

Fouling And Aging In Membrane Filtration : Hybrid Afm-Based Characterization, Modelling And Reactive Membrane Design, Wanyi Fu

Dissertations

Membrane filtration has been extensively used in water and wastewater treatment, desalination, dairy making, and biomass/water separation. However, membrane fouling, aging and insufficient removal efficiency for dissolved organic matters remain major challenges for wider industrial applications. In order to tackle these challenges, this doctoral dissertation investigates mechanisms of membrane fouling and development of antifouling membrane filtration technologies. Specifically, four major research areas are explored: (i) nanoscale physicochemical characterization of the chemically modified polymeric membranes; (ii) quantitative modelling between membrane properties and membrane fouling and defouling kinetics; (iii) development of quantitative structure-activity relationships for membranes that undergo thermal and chemical aging …

Methods To Improve The Remediation Of Polycyclic Aromatic Hydrocarbons (Pahs) In Aerobic And Anaerobic Environments, Brian Wartell

Dissertations

Oil spills occur regularly in terrestrial environments and crude oil can contain many compounds that are highly resistant to degradation. Among these compounds are high levels of polycyclic aromatic hydrocarbons (PAHs) which are not only toxic but can also be carcinogenic and/or mutagenic. The first chapter of this dissertation includes an extensive review chapter on the variables affecting the anaerobic degradation of hydrocarbons, with a particular focus on PAHs. Electron acceptors, electron donors, temperature, salinity, pH all play key roles in determining the possibility effective of effective degradation occurring. Thus, by addressing solutions, such as biostimulation, improving environmental variables for …