Physical Sciences and Mathematics Commons^™

Development Of Lower Rio Grande River Water Quality Transportation Numerical Model For Bi-National River Management, Jose O. Gonzalez

Theses and Dissertations

Traditionally, water quality modelling has focused on modelling individual water bodies. However, water quality management problems must be analyzed at the larger scale to include influences from various water bodies that are interconnected. This paper provides a study on the hydrologic and quality transportation calculation by developing a hydrodynamic (unsteady state) channel routing model using a water-balanced approach. A one dimension Lagrangian river model was developed and applied to the 210 plus miles for the lower Rio Grande River Basin from the Falcon Dam to the head water of Brownsville that pours onto the Gulf of Mexico. This model can …

Development Of A Multiband Remote Sensing System For Determination Of Unsaturated Soil Properties, Cyrus D. Garner

Graduate Theses and Dissertations

A multiband system including active microwave sensing and visible-near infrared reflectance spectroscopy was developed to measure unsaturated soil properties in both field and laboratory environments. Remote measurements of soil volumetric water content (θv), soil water matric potential (ψ), and soil index properties (liquid limit [LL], plastic limit [PL], and clay fraction [CF]) were conducted. Field-based measurement of θv was conducted using a ground-based radar system and field measurements within 10 percentage points of measurements acquired with traditional sampling techniques were obtained. Laboratory-based, visible and near infrared spectroscopy was found to be capable of obtaining empirical, soil specific regression functions (partial …

Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham

Graduate Theses and Dissertations

The formation of N-nitrosodimethylamine (NDMA) in drinking water systems is a concern because of its potential carcinogenicity and occurrence at toxicologically relevant levels. The postulated mechanism for NDMA formation involves a substitution between dichloramine and amine-based precursors to form an unsymmetrical dimethylhydrazine (UDMH), which is then oxidized by ground-state molecular oxygen to form NDMA. However, this latter reaction is spin forbidden, thus likely occurs at a slow rate. It is hypothesized that the reaction between monochloramine and hydroxylamine (a nitrification product) may form an intermediate, which is involved in the NDMA formation pathway. This intermediate may also be generated from …

Policy Design Tool For Managing Indoor Residential Water Demand In Water-Scarce Regions, Mujahed M. Thneibat

Open Access Dissertations

In view of population growth; climate change; and economic evolution, water resources in numerous parts of the world have reached their natural capacities. Consequently, the ability of many countries to grow; meet the basic needs of inhabitants; and protect the environment will be endangered like never before unless water resources are smartly handled and managed. ^ In the past few decades, many developed and developing countries have suffered from water scarcity, and more are certain to follow. The water security dilemma is much more challenging in developing countries. Water utilities have had to follow regulatory plans to manage demand on …

Asbestos Cement Pipe Condition Assessment And Remaining Service Life Prediction, Abiy Melles Ghirmay

Graduate Theses and Dissertations

This research details a condition assessment of asbestos cement (AC) pipe within in the Bella Vista Village Property Owners Association water distribution system. Bella Vista Village contains appropriately 300 miles of AC pipe with nominal diameters from 6-14 inch. The goal of the research is to determine the current condition of AC pipe within the system and predict future performance of the pipes. AC pipe samples were obtained from 23 locations disturbed across the distribution system with nominal pipe diameters of 6-8 inch. Estimates of current level of degradation were obtained using phenolphthalein staining and hardness measurements of each sample. …

Role Of River Bathymetry In Hydraulic Modeling Of River Channels, Sayan Dey

Open Access Theses

Accurate geometric representation of the river channel is required for accurate hydraulic modeling of rivers. These are generally obtained through remote sensing techniques such as Light Detection and Ranging (LIDAR). However, these techniques lack the ability to model the submerged channel bed effectively and need to be complemented with surveyed bathymetric data for complete representation of the channel bathymetry, which can be time and cost prohibitive. An alternative to address this issue is to develop conceptual models that can estimate bathymetry.

This study aims to evaluate the potential of a conceptual model, the River Channel Morphology Model (RCMM) which estimates …

Evaluating A Measure-Calculate Method For Determining Sediment Oxygen Demand In Lakes, Adrian Beirise

Graduate Theses and Dissertations

A steady-state mass diffusion model used with simple measurable and calculable inputs for determining sediment oxygen demand (SOD) is compared to an intact core incubation (ICI) SOD method using samples from three lakes. The mass diffusion model coupled with inputs is known as the measure-calculate method (M-C) and is a potential alternative to existing methods for measuring SOD which are more complex, time-consuming, and costly. The M-C method requires inputs for volumetric sediment oxygen uptake (Ṅsed), sediment density and porosity, and water properties. Ṅsed was determined by suspending sediment in oxygen-saturated water with a DO probe and determining the steady …

Trend Analysis Of Water Quality In Northwest Arkansas Streams Reflects Changes In The Watershed, Zachary Paul Simpson

Graduate Theses and Dissertations

Watershed export of nutrients, sediments, and chemicals impacts receiving waters. Changes within the watershed (e.g., anthropogenic or climatic) can alter the transport of constituents in streams. Stream monitoring is crucial for understanding these effects. This study developed a potential improvement to flow-adjusting constituent concentrations in streams, an important step of analyzing monitoring data in lotic systems for trends. The method incorporates a K-fold cross-validation procedure to optimize a model explaining the relationship between the concentration and streamflow, thus providing a valuable tool to researchers in water quality. Additionally, two case studies were conducted on watersheds located in northwest Arkansas using …

The Role Of Organic Matter In The Fate And Transport Of Antibiotic Resistance, Metals, And Nutrients In The Karst Of Northwest Arkansas, Victor Lee Roland Ii

Graduate Theses and Dissertations

Organic matter (OM) in the environment acts as a nutrient, but may also act as a transport vector for harmful chemical compounds and bacteria. Acetate is a labile form of OM produced during fermentation in anaerobic lagoons used to store animal fecal-waste from concentrated animal feeding operations (CAFOs). Dry and liquid fertilizers from CAFOs pose a threat to groundwater by introducing excessive amounts of nutrients (e.g. OM, nitrate and ammonia), metals, and antibiotic compounds. In the epikarst of Northern Arkansas in the Buffalo River watershed additional input of labile dissolved organic carbon (DOC) from liquid CAFO waste-fertilizers was hypothesized to …

Electrodeionization Versus Electrodialysis: A Clean-Up Of Produced Water In Hydraulic Fracturing, Brigitte Marie Rodgers

Graduate Theses and Dissertations

Electrodeionization (EDI) is a widely studied process ranging from applications in wastewater clean-up in the food and beverage industry to purifying organic compounds. To date, there are no apparent studies on applying this technology to produced wastewater recovered from hydraulic fracking sites. Water consumption within hydraulic fracturing sites can reach in the upwards of millions of gallons per site, so a need for a water recycling process becomes necessary within areas where water requirements are scarce. Implementation of an EDI module that is capable of handling high salt solutions from produced wastewater in subsequent fracturing practices will decrease overall water …

Field Observations And Computer Modeling Of Tornado-Terrain Interaction And Its Effects On Tornado Damage And Path, Nawfal Shihab Ahmed

Graduate Theses and Dissertations

Tornado forces on structures have been a research focus for the past decades, and some comparisons have been made to distinguish between straight boundary layer (SBL) wind and tornado wind forces on specific structures. However, very little attention has been paid to terrain effects on tornado damage and path. Available damage investigation data for four tornado locations (Joplin-2011, Tuscaloosa-2011, Parish-2011 and Mayflower-2014) is utilized to explore terrain effects on tornado damage and path. Google Earth, site visits and aerial images are employed to study the influence of terrain on an extent of damage and path variation. Additionally, a three dimensional …

Impact Of Extreme Summer Temperatures On Bridge Structures, Ryan Hagedorn

Graduate Theses and Dissertations

Climate change and its effect on weather in the United States is a well-documented phenomenon. In particular, extreme heat waves have become more intense, more frequent, and longer lasting, especially in the southern United States. As with much of America’s transportation infrastructure, prestressed concrete bridge girders experience the effects of these heat waves. Uneven heating of optimized bridge girder sections results in large non-linear temperature gradients. In this study, temperature was monitored in three different AASHTO I-girders to determine the vertical and transverse temperature gradients in a pre-deck placement condition. It was determined that the current design standard, which uses …

Simulation Of Conservation Practice Effects On Water Quality Under Current And Future Climate Scenarios, Carlington W. Wallace

Open Access Dissertations

Analysis of the effects of implementing different conservation practices, as well as increased levels of conservation practices under existing and projected future climate, will determine if current conservation practice recommendations will be sufficient to maintain soil and water resources. The Soil and Water Assessment Tool (SWAT) was used to study four watersheds of different sizes (CCW = 680 km2, F34 = 183 km2, AXL = 42 km 2 and ALG = 20 km2) located in Northeastern Indiana. The overarching goal of this study was to evaluate the effect of various agricultural practices on runoff and agricultural chemical losses under current …

Development And Evaluation Of A Watershed-Scale Hybrid Hydrologic Model, Younghyun Cho

Open Access Dissertations

A watershed-scale hybrid hydrologic model (Distributed-Clark), which is a lumped conceptual and distributed feature model, was developed to predict spatially distributed short- and long-term rainfall runoff generation and routing using relatively simple methodologies and state-of-the-art spatial data in a GIS environment. In Distributed-Clark, spatially distributed excess rainfall estimated with the SCS curve number method and a GIS-based set of separated unit hydrographs (spatially distributed unit hydrograph) are utilized to calculate a direct runoff flow hydrograph, and time-varied SCS CN values and conditional unit hydrograph approach for different runoff depth-based flow convolution are also used to compute long-term rainfall-runoff flow hydrographs. …

An Empirical Water Quality And Best Management Practice Prioritization Model For Select Arkansas Watersheds, James Mccarty

Graduate Theses and Dissertations

The purpose of this study was to prioritize subwatersheds using water quality data and watershed characteristics. Water quality data was provided through studies by the Arkansas Natural Resources Commission, Beaver Water District, Arkansas Water Resources Center, and publicly available USGS gage data. A total of 114 sites across five HUC-8 watersheds were analyzed, including 12 USGS gages. Watershed characteristic data was retrieved from USGS and Arkansas GeoStore geodatabase repositories. A significant linear relationship between baseflow and stormflow nutrient concentrations was established allowing for the use of baseflow concentrations in the prioritization methodology. Pearson correlation, linear regression, classification and regression tree, …

High Voltage Rear Electric Drivetrain Design For A Parallelthrough-The-Road Plug-In Hybrid Electric Vehicle, Adam Garrett Fogarty

Open Access Theses

Purdue University was selected as one of 15 universities to participate in a three year Advanced Vehicle Technology Competition (AVTC) called EcoCar2: Plugging Into the Future. The vehicle built by the Purdue team was a Parallel-Through-The-Road Plug-in Hybrid Electric Vehicle (PTTR PHEV). The vehicle utilized a B20 diesel powertrain to power the front wheels, as well as a custom electric drivetrain to power the rear wheels. Using this vehicle during the final year of the competition, the team was successful in placing 4th overall as well as 2nd in the category of Well-To-Wheel (WTW) Greenhouse Gas Emissions. A stock 2013 …

Evaluation Of Collapse Indicators For Seismically Vulnerable Reinforced Concrete Buildings, Nicholas R. Skok

Open Access Theses

Older reinforced concrete buildings can be prone to column shear and compression failures during earthquakes because of inadequate transverse reinforcement. Cities in seismic areas still have large inventories of older and potentially deficient buildings. To analyze every building and estimate its vulnerability in detail is costly. A simple method to rank quickly older buildings according to their seismic vulnerability is needed to help engineers prioritize the use of resources for rehabilitating the most vulnerable buildings.

Four indicators of building damage or collapse were evaluated using numerical analysis and prior data from building surveys: column index (Hassan & Sozen, 1997), R …

Systematic Analysis Of Drainage Events In Free Draining And Managed Subsurface Drainage Systems, Guy Bou Lahdou

Open Access Theses

Understanding the hydrologic controls that regulate outflow from free and managed subsurface drainage systems during drainage events can offer improved insight on the overall functioning and effectiveness of the systems so that they can be better managed or retrofitted to increase their environmental benefits. This study used drainage, precipitation, water table, and soil moisture data from a monitoring site located in east central Indiana to investigate the event hydrology of 22 drainage events in free and managed subsurface drainage systems. Relationships between event drainage volume, drain flow hydrograph metrics, column soil moisture, water table depth, and precipitation characteristics were explored …

Floodplain Mapping Using Soil Survey Geographic (Ssurgo) Database, Nikhil Sangwan

Open Access Theses

Floods are the most damaging of all natural disasters, adversely affecting millions of lives and causing financial losses worth billions of dollars every year across the globe. Flood inundation maps play a key role in assessment and mitigation of the potential flood hazards. However, there are several communities in the United States for which the flood risk maps have not been published yet, as the current flood inundation mapping methods are typically very expensive and time consuming. The objective of this study is to develop and examine an economical alternative approach to floodplain mapping using widely available soil survey data. …

Retrofiting Lid Practices Into Existing Neighborhoods: Is It Worth It?, Timothy Wright

Open Access Theses

Low impact development (LID) practices are gaining popularity as a way to manage stormwater close to the source. This reduces infrastructure requirements and helps to maintain hydrologic processes close to predevelopment conditions. Studies have shown LID practices to be effective in reducing runoff and improving water quality. However, little has been done to aid decision makers in selecting the most effective practices for their needs and budgets.

To this end, the L-THIA LID model has been applied. Using readily available data sources, multiple scenarios can quickly be examined, and then analyzed to determine the cost of implementation and the approximate …

Effect Of Multivalent Ions On The Swelling And Mechanical Behavior Of Superabsorbent Polymers (Saps) For Mitigation Of Mortar Autogenous Shrinkage, Qian Zhu

Open Access Theses

The chemical and physical structure-property relationships of model superabsorbent polymer (SAP) hydrogels were characterized with respect to swelling behavior and mechanical properties in different ionic solutions (Na+ , Ca2+ , and Al3+ ). The model hydrogels were composed of poly(sodium acrylate-acrylamide) (PANa-PAM) copolymer with varying concentrations of PANa (0, 17, 33, 67, and 83 wt.%) and covalent crosslinking densities of 1, 1.5, and 2 wt.%. By synthesizing the hydrogels in-house, systems with independently tunable amounts of covalent crosslinking and anionic functional groups were created, allowing for the relative effects of covalent and ionic crosslinking on the properties of the hydrogels …

Effectiveness Of Air Sealing Measures And Other Energy Retrofit Measures In Lafayette Energy Improvement Program, Jia Ye

Open Access Theses

From September 2011 to March 2013, the City of Lafayette, IN implemented Lafayette Improvement Program. The goal of this project was to "increase energy efficiency of existing homes through retrofitting, thereby lowering the costs of home ownership within the Vinton and Glen Acres Neighborhood Target Area (The City of Lafayette, 2011)." Energy audit companies carried out before blower door test and after blower door test to identify air tightness of subjects. This paper finds out there was an improvement in air tightness in the population of 85 houses and the degree of improvement was between 16.85% and 17.85%.

Change point …

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Assessing The Impact Of Chlorine Residual On Trihalomethane And Haloacetonitrile Formation Under Chlorination And Chloramination Disinfection Regimes, Thien Duc Do

Graduate Theses and Dissertations

A disinfection byproduct (DBP) formation potential (FP) test can be used to indirectly measure the concentration of DBP precursors in natural waters, permitting assessment of various DBP-related treatment processes and control strategies. While these tests require a 7-day chlorine residual (CR) between 3-5 mg L^-1 as Cl², it is not well known if this recommended residual corresponds to the true DBPFP (i.e., the maximum concentrations) for trihalomethanes (THMs) and haloacetonitriles (HANs). In this study, THMs and HANs were quantified as a function of CR under three common disinfection regimes: (1) free chlorine at pH 7.0 (FC7), (2) …

Evaluation Of Broiler Litter Heat Production During Windrowing & Nitrogen Based Gas Emission Mitigation Using Biofilter, Min Lei

Graduate Theses and Dissertations

Ammonia emission from animal feeding operations (AFOs) has negative effects on environment and animals' health. Thus measuring and mitigating ammonia emission from AFOs is important for environmental protection. In chapter I, different ammonia measurements were discussed and a mitigation technology- biofilter was represented.

In-house windrowing of built-up litter has been used by broiler producers to reduce pathogen loads and rejuvenate litter for the next flock. When litter is piled up for an extended period during downtime, heat generated by the litter pile can become a substantial heat source due to the metabolism of microorganisms. In chapter II, heat production rates …

Variability In The Hydraulic Conductivity Of A Test Pad Liner System Using Different Testing Techniques, Matthew Jonathan Nanak

Graduate Theses and Dissertations

Historic methods (the time lag approach, the velocity approach, and the Z-t approach), utilized to reduce two stage borehole test data, were evaluated. Two of the historic methods provided viable results and were used for this research project. Additionally, these two methods are recommended for reducing two stage borehole test data in the future.

Flexible wall permeameter and soil index laboratory testing were conducted on the soil used to construct three environmentally controlled compacted clay liners (test pads) to develop a zone of acceptance (placement window). Using the results from the laboratory testing, two acceptance criterions were evaluated, while one …

Simulating Land Use Land Cover Change Using Data Mining And Machine Learning Algorithms, Amin Tayyebi

Open Access Dissertations

The objectives of this dissertation are to: (1) review the breadth and depth of land use land cover (LUCC) issues that are being addressed by the land change science community by discussing how an existing model, Purdue's Land Transformation Model (LTM), has been used to better understand these very important issues; (2) summarize the current state-of-the-art in LUCC modeling in an attempt to provide a context for the advances in LUCC modeling presented here; (3) use a variety of statistical, data mining and machine learning algorithms to model single LUCC transitions in diverse regions of the world (e.g. United States …

An Evaluation Of Spatial Variability Of Water Stress Index Across The United States: Implications Of Supply And Demand In The East Vs The West, Jennifer Ann Roath

Open Access Theses

In order to support both human and environmental needs, high quality fresh water must be available when and where it is required. As a metric for indicating unsustainable water usage, WSI is only useful when the values reflect accurate interactions between supply and demand; however, the complexity of temporal and spatial variability of available fresh water complicates the analysis of water stress.

The overall goal of this project was to investigate the spatial variability of water stress across the United States and the appropriate spatial scale for management decisions. To accomplish this, a national dataset describing spatial distribution and breakdown …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …

Effects Of Testing Time On Anaerobic Toxicity Assessment, Omolola Atinuke Akintomide

Graduate Theses and Dissertations

Anaerobic digestion has been widely used for wastewater treatment for decades. Several Anaerobic Toxicity tests have been developed to screen wastewater for toxicity and assess the treatability of such toxicants. However, past research and reviews on Biochemical Methane Potential (BMP) test and Anaerobic Toxicity Assay (ATA) were considered in this study.

The experimental tests included ammonium-nitrogen and sodium chloride toxicity tests with varied concentration and solid retention time. These tests were designed to demonstrate the impact of ammonia- nitrogen and sodium chloride on the biological degradation process. The anaerobic test set-up includes bench-scale test reactors and respirometers used for measuring …