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Nanomole Silver Detection In Chloride-Free Phosphate Buffer Using Platinum And Gold Micro- And Nanoelectrodes, Prabhakar Sidambaram, John Colleran

Articles

The electrochemical determination of ultra-low concentrations of silver requires reliable, reproducible measurements using sensitive analytical techniques. To date, the electrochemical determination of silver in biological buffers and pH neutral media has not been successful in terms of reproducibility. In this work, we report on the determination of ultra-low concentrations of silver in chloride-free phosphate buffer solution (PB, pH 7.4). Detection was conducted at gold and platinum micro and nanoelectrodes using anodic stripping voltammetry (ASV). The micro and nanoelectrodes were fabricated using a Sutter P-2000 laser puller, with physical and electrochemical characterization revealing flat disk-shaped working surfaces of 10–15 μm (microelectrode) …