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Full-Text Articles in Physical Sciences and Mathematics

Exposure Of Candyland Red Tomatoes (¬Solanum Lycopersicum L.) To Various Metal Oxide Nanomaterials: Full Life Cycle And Assessment Of Fruit Quality, Jesus Manuel Cantu Aug 2022

Exposure Of Candyland Red Tomatoes (¬Solanum Lycopersicum L.) To Various Metal Oxide Nanomaterials: Full Life Cycle And Assessment Of Fruit Quality, Jesus Manuel Cantu

Open Access Theses & Dissertations

The use of nanotechnology in agriculture has attained high interest to enhance crop production due to their unique properties. Moreover, metal oxide nanomaterials can potentially supplement nutrients, enhance plant growth, and crop production. When investigating fruits' nutritional quality, carbohydrates and phytonutrients (bioactive compounds) play important roles. Therefore, it is important to understand how nanomaterials will affect the quality of tomato fruits. In this dissertation, various metal oxides were synthesized and applied to Candyland Red tomato seedlings to assess the plant growth and tomato production. In the first investigation, Candyland Red tomatoes (Solanum lycopersicum) were exposed to synthesized pristine CuO and …


Isolation And Characterization Of Extracellular Vesicles From Various Biological Matrices Using Capillary-Channeled Polymer (C-Cp) Fiber Solid-Phase Extraction Spin-Down Tips, Kaylan Jackson Aug 2022

Isolation And Characterization Of Extracellular Vesicles From Various Biological Matrices Using Capillary-Channeled Polymer (C-Cp) Fiber Solid-Phase Extraction Spin-Down Tips, Kaylan Jackson

All Dissertations

A number of recent works have emphasized the need to isolate nanometer-scale analytes, like extracellular vesicles (EVs), from various biologically-relevant fluids. Exosomes are a subset of small EVs that range from 30-200 nm in diameter that serve as biomolecular snapshots of their cell of origin containing mother cell-specific DNA, miRNA, mRNA, and proteins. As critical components of intercellular communication, exosomes and other EVs play significant roles in many physiological and pathological processes. Diverse populations of these vesicles can be collected from biofluids, including blood, saliva, and urine, from cell culture conditioned media and primary cells, and even from plant …


The Dissolution And Recovery Of Critical Materials (Li2co3 And Uf6) From Ionic Liquid, Cassara Higgins May 2022

The Dissolution And Recovery Of Critical Materials (Li2co3 And Uf6) From Ionic Liquid, Cassara Higgins

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lithium and uranium are critical materials in both the energy industry and for national security. Lithium is necessary for the next generation of batteries and 6Li is valuable for the production of tritium necessary for both fusion energy and to maintain our nuclear stockpiles. Uranium is a fuel source or precursor fuel source for commercially operating nuclear fission power. The monitoring of uranium hexafluoride (UF6) enrichment at foreign facilities is important for the monitoring of nuclear safeguards and enforcement of non-proliferation treaties. Recovery methods for lithium at the end of life of batteries are necessary to ensure abundance of the …


Compatible Blends Of N-Type Polymer Semiconductors: Impact On The Morphology And Mechanics Of Flexible Optoelectronics, Zachary C. Ahmad May 2022

Compatible Blends Of N-Type Polymer Semiconductors: Impact On The Morphology And Mechanics Of Flexible Optoelectronics, Zachary C. Ahmad

Honors Theses

Conjugated polymers offer the potential for the development of robust, low-cost electronics, but achieving high mechanical deformability and high charge transport simultaneously in polymer semiconductors remains a significant challenge. In this work, blends of conjugated polymers were investigated to elucidate the influence of compatible conjugated blends on polymer morphology, mechanics, and electrical properties (using a partially conjugated polymer as the soft matrix and a fully conjugated polymer as the electrically active component). This work achieves a fundamental understanding of blend morphology for these similar components by establishing the framework for how they deform with strain. Grazing-incidence wide-angle X-ray scattering (GIWAXS) …


Synthesis, Characterization And Activity Of Palladium Catalysts On The Dual Support Of Cerium And Aluminum Oxides, Jihyeon Park Apr 2022

Synthesis, Characterization And Activity Of Palladium Catalysts On The Dual Support Of Cerium And Aluminum Oxides, Jihyeon Park

Theses and Dissertations

The effects of sequence of impregnation (Pd on cerium oxides -alumina and cerium oxides on Pd-alumina) and calcination temperature (500 ℃ and 850 ℃) on the catalytic oxidation of methane under lean conditions were investigated. The catalysts were prepared by a combination of impregnation, slurry and vortexing methods. The catalysts had 4.7 wt.% Pd and 10.7 wt.% Ce based on inductively coupled plasma optical emission spectrometry (ICP-OES) analysis. The catalysts were characterized by pulse chemisorption, temperature programmed reduction (TPD), scanning transmission electron microscopy (STEM), and X-ray photoelectron spectroscopy (XPS). The activity of the catalysts for methane combustion was measured in …


Infrared Investigation Of Lithium Ion Electrolytes: Characterization Of Structure And Dynamics Via Linear And Nonlinear Spectroscopy, Jeramie Christopher Rushing Feb 2022

Infrared Investigation Of Lithium Ion Electrolytes: Characterization Of Structure And Dynamics Via Linear And Nonlinear Spectroscopy, Jeramie Christopher Rushing

LSU Doctoral Dissertations

Lithium ion batteries are widely employed in energy storage, but the connection between the molecular interactions in their electrolytes and the macroscopic properties remains elusive. Across three vastly different electrolytes, speciation and dynamics were studied via linear and nonlinear infrared spectroscopy to shed light on this relationship. The impact of mixed solvation on ionic speciation was studied from the perspective of the anion, which revealed a significant energetic favorability for the formation of contact ion pairs in linear carbonate solvents over cyclic carbonates. Infrared spectroscopy and density functional theory calculations described a complete inversion of the speciation due to solvent …


Synthesis And Advanced Characterization Of Energy Materials, Erik Sarnello Jan 2022

Synthesis And Advanced Characterization Of Energy Materials, Erik Sarnello

Graduate Research Theses & Dissertations

Catalysts are used in an extremely broad range of systems including everything from biological systems to industrial processes. An ideal catalyst offers robust stability and high activity. This work focuses on the synthesis and characterization of materials that show promise in the field of catalysis. Advanced synchrotron characterization techniques and unique experimental design are highlighted to provide foundation work that will provide the necessary information to aid in designing and fabricating catalytic materials. Supported metal nanoparticle (SMN) catalysts are enormously crucial for many catalytic applications. However, catalyst deactivation, caused by sintering and coke formation, is a ubiquitous problem that significantly …


Characterization Of Nanoparticles Using Inductively-Coupled Plasma Mass Spectrometry, Jabez D. Campbell Jan 2022

Characterization Of Nanoparticles Using Inductively-Coupled Plasma Mass Spectrometry, Jabez D. Campbell

MSU Graduate Theses

Nanomaterials are a relatively new class of materials that have many applications which span a wide host of fields from medical products to consumer products. The possible compositions and forms of nanomaterials are just as varied as the applications. Therefore, a versatile characterization method is needed for researchers and regulators alike to ensure nanomaterials are properly used. Single Particle Inductively Coupled Plasma Mass Spectrometry (SP-ICP-MS) is a functional method that could fill the characterization need in the nanomaterial research field. Using data from both SP-ICP-MS tests and data from literature established characterization methods, the viability of making SP-ICP-MS the standard …