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Full-Text Articles in Physical Sciences and Mathematics

Effects Of Nitrate On Arsenic Mobilization During Aquifer Storage And Recovery, Hania Hawasli Oct 2021

Effects Of Nitrate On Arsenic Mobilization During Aquifer Storage And Recovery, Hania Hawasli

USF Tampa Graduate Theses and Dissertations

Aquifer storage and recovery technology is used to sustain water resources and to prevent saltwater intrusion. The injected water can come from various resources, including treated wastewater. In pilot ASR studies in the Tampa Bay region, researchers found high As concentrations in the recovered water from the oxidation of the arsenopyrite that is embedded in the aquifers. The presence of dissolved O2 in the injected water is a major factor in the arsenopyrite oxidation during ASR, however the effects of NO3- on the arsenopyrite has not been studied yet. This is an important knowledge gap because injected water may contain …


Removal Of Arsenic (Iii) And Arsenic (V) From Aqueous Solution Via Solanum Lycopersicum Phytoremediation And Essential Nutrient Analysis, Grecia W. Garcia Salazar May 2021

Removal Of Arsenic (Iii) And Arsenic (V) From Aqueous Solution Via Solanum Lycopersicum Phytoremediation And Essential Nutrient Analysis, Grecia W. Garcia Salazar

Theses and Dissertations

ICP-OES was used to investigate the uptake of arsenic (V) and arsenic (III) from aqueous solution using tomato seedlings. The effect of arsenic on essential nutrient uptake by tomato was analyzed. The experiment was performed at three levels of arsenic: 1ppm, 2 ppm and 5 ppm [added as sodium arsenate (Na3AsO4) and arsenic trioxide (As2O3)], in nutrient solution. Plants remained in solution for two weeks. Arsenic accumulation depended on arsenic concentration in solution, when exposed to higher arsenic concentrations the plant uptake increased. The highest arsenic accumulation was found in roots, followed by stems and leaves in that order. Essential …


Artisanal Mining Impacts In Urbanized Semi-Arid Environments: Lessons From Historic Arsenic Mining Near San Diego, California, James A. Wright Jan 2021

Artisanal Mining Impacts In Urbanized Semi-Arid Environments: Lessons From Historic Arsenic Mining Near San Diego, California, James A. Wright

Theses

Anomalously elevated arsenic concentrations occur at an abandoned artisanal mine site in an open space recreational park in urban San Diego County, California. Although mining at the site ceased 100 years ago little to no remediation efforts took place leaving shafts, adits, waste piles and derelict infrastructure accessible by inquisitive hikers and adventurers frequenting Black Mountain Open Space Park. This study evaluates the geochemical mechanisms of As transport downgradient from the mine and examines the contribution of both climate and urbanization on the restriction of As mobility. Sediment As concentrations reach 2,320 mg/kg (483 times background crustal concentrations; n=73) along …