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Full-Text Articles in Physical Sciences and Mathematics
Polyaniline And Its Derivatives For Environmental Analysis., Atogho Jude Abia
Polyaniline And Its Derivatives For Environmental Analysis., Atogho Jude Abia
Electronic Theses and Dissertations
Electrooxidation has been used to deposit thin film polyaniline as well as its derivative - thin film poly (ortho-phenylenediamine) (POPD) and poly (meta-phenylenediamine) (PMPD) on carbon electrodes, which are subsequently used to monitor the environmental heavy metal ions (Hg2+, Pb2+ ,Cd2+) through a rather unusual "blocking" of anodic stripping for these metals. Using Hg2+ as a model, its cyclic voltammogram for a modified glassy carbon electrode with the resultant polymer shows an enhanced cathodic peak that increases linearly with the analyte ion concentration. POPD also exhibits unique selective detection for organic species. Acetaminophen and …
Gas Chromatography On Self Assembled Single Walled Carbon Nanotubes, Mahesh Kumar Karwa
Gas Chromatography On Self Assembled Single Walled Carbon Nanotubes, Mahesh Kumar Karwa
Dissertations
Carbon nanotubes (CNTs) are nano-sized carbon-based sorbents, which have high surface area, large aspect ratio, can be self-assembled and are known to be stable at high temperatures. It is therefore conceivable that separation techniques, such as, gas chromatography (GC) can benefit from their unique properties and nano-scale interactions. Self-assembly, in-contrast to packing these materials in a tube, prevents them from agglomeration and thus facilitates in retaining their nano-characteristics. In this research, novel substrates, such as, steel tubings, on a scaled-up level have been explored for the self-assembly process of CNTs, for applications such as gas chromatography, where the CNTs served …