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Coordination Chemistry Of Bidentate Difluorophosphines, Darrell Lynn Gallup
Coordination Chemistry Of Bidentate Difluorophosphines, Darrell Lynn Gallup
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
The reactions of 1, 2–bis(difluorophosphino)cyclohexane, PF2C6H10PF2, with hexacarbonyls of Cr(O), Mo(O), and W(O) have been extensively investigated. The hexacarbonyls react, either under photolytic or thermolytic conditions, to produce carbon monoxide and oily mixtures of products of the general formulations, [M(CO)4(PF2C6H10PF2C)]x, where x varies apparently from 1 – 4. The higher values of x, corresponding to species involving bridging ligands, are more common to the photolysis rather than the thermolysis reactions. Photolysis reactions of Mo(Co)6 with increasing amounts of the …