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An Investigation Of Coulometric Methods Of Analysis Of 1,1-Dimethylhydrazine, David M. Creighton
An Investigation Of Coulometric Methods Of Analysis Of 1,1-Dimethylhydrazine, David M. Creighton
Theses and Dissertations
The oxidation of 1,1-dimethylhydrazine by bromine has been studied using a coulometric method of bromine generation, and a dual intermediate system of bromide and cupric ions in solution. The system allowed over-generation of bromine and back-titration by cupric ion. The results of the investigation showed that the mechanism of oxidation is not fixed, but is a function of the concentration of bromine in the solution at any time. Additional studies have been recommended, whereby the mechanisms of the reactions may be determined.