Physical Sciences and Mathematics Commons^™

The Chelation Of Cu(Ii) With 1, 3-Bis(Tris(Hydroxymethyl)Methylamino)-2-Propanol And 1, 3-Bis (2-Hydroxyethylamino)-2-Propanol, David Andrew Jackson Jr.

Master's Theses

The chelating agent 1, 3-bis(2-hydroxyethylamino)-2-propanol dihydro­chloride was prepared and preliminary examinations of the Cu(ll) and Fe(lll) complexes were carried out spectrophotometrically. This dihydrochloride as well as 1, 3 bis(tris(hydroxymethyl)methylamino)-2-propanol dihydrochloride. were converted from the chloride salts to their corresponding ammonium bases. The conversion was carried out by passing an aqueous solution of each chloride salt through an ion exchange column containing Amberlite XE-78 resin.

Solutions of these bases were standardized for use in potentiometric titration&. Each ammonium base was titrated with standard perchloric acid at 20°C, 30°C, and 40°C. The dissociation constants. were calculated using these data. Aqueous solutions of …