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Chemistry

Theses

Soil pollution

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I. Removal Of Chromium From A Highly Contaminated Soil/Slag Matrix By Soil Washing At Low Ph, Ii. Removal Of Chromium From Impregnated Clay Matrices By Soil Washing At Low Ph, Erez Gotlieb Jan 1992

I. Removal Of Chromium From A Highly Contaminated Soil/Slag Matrix By Soil Washing At Low Ph, Ii. Removal Of Chromium From Impregnated Clay Matrices By Soil Washing At Low Ph, Erez Gotlieb

Theses

Section I. Chromium is a major soil contaminant of industrial sites in New Jersey, as well as in many of the Superfund sites throughout the United States. Removal of chromium by soil/slag washing with low pH sulfuric acid solutions is described. The extraction parameters are acid concentration, contact time, temperature, solvent/soil ratio, and acid type. The effect of two-stage extraction is discussed.

Soil/slag washing with sulfuric acid concentrations of 2% weight:volume (units are g/ml. This concentration is approximately equal to 0.4 N) at 75:1 v:w solvent/soil ratios yielded chromium extraction efficiencies of 95%, but 50% of the soil matrix was …