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Full-Text Articles in Physical Sciences and Mathematics
Design And Characterization Of Plasmonic Nanoprobes And Interparticle Interactions For Surface Enhanced Raman Scattering And Biomolecular Detection, Zakiya Skeete
Graduate Dissertations and Theses
Functional nanoparticles serve as an intriguing class of probes in medical theranostics for enabling rapid, sensitive, multiplexing, and point-of-care treatment and diagnosis. One important aspect of these applications is the exploitation of the unique plasmonic properties of certain metal nanoparticles. A key challenge is the understanding of effective harnessing of the plasmonic coupling of the nanoparticles upon interacting with the targeted biomolecular species. This thesis work focuses on investigating the interparticle interactions of chemcially-labled and bioconjugated gold and silver based nanoparticles and their influences on the plasmonic coupling for specctroscopic detection of biomolecules. Examples of the interparticle interactions include dye-mediated …
A Thermally Stabilized Fluorescent Organic Chromophore, Brendan P. Hughes
A Thermally Stabilized Fluorescent Organic Chromophore, Brendan P. Hughes
Graduate Dissertations and Theses
A fluorescent chromophore, hereby designated as cyanine dye, has been bound to generated zinc oxide nanoparticles. It has been shown that the material not only retains the characteristic absorption peak of the native chromophore, but it also continues to fluoresce with comparable intensity. The binding occurs through a Zn – O2C bridge, which allows for vibrational relaxation as the dye heats up, yet also preserves the optical properties of the dye. This bond linkage can be observed from the comparison of FT-IR spectra of the nanoparticles and the native dye, designated by a shift in one of the …
Harnessing Solar Energy: Vapor Phase Polymerized Poly(3,4-Ethylenedioxythiophene) For Solid State Dye-Sensitized Solar Cells And The Photodegradation Of Organic Toxicants, Steven M. Boyer
Graduate Dissertations and Theses
Solar energy is the most abundant energy resource available and can be utilized for a variety of applications such as photovoltaics and promote chemical reactions. Dye-sensitized solar cells (DSSCs) are a class of photovoltaic cells that have been well studied for their low cost and environmentally friendly materials. Previous research focused on developing more efficient liquid phase solar cells, but little work has gone into solid state DSSCs. Moving towards the solid state would improve the lifetime of the cells, preventing leaking of electrolyte and corrosion of the electrode while potentially being a more scalable process for mass production, improving …
Fabrication Of Electrospun Tio2/Polymer Composite Nanofibers For Photocatalysis And Degradation Of Toxins, Danielle L. Mccarthy
Fabrication Of Electrospun Tio2/Polymer Composite Nanofibers For Photocatalysis And Degradation Of Toxins, Danielle L. Mccarthy
Graduate Dissertations and Theses
Our society has made significant advancements in technology as it continues to grow in size which in turn has led to an accumulating amount of toxic threats. Some types of harmful pollution our society is currently facing include industrial waste such as organic dyes, pharmaceutical pollution and chemical warfare agents (CWAs). To date the nerve agent, O-ethyl S-[2-(diisopropylamino)ethyl] methylphosphonothioate), also known as VX, is the world’s most lethal chemical substance. Some of these deadly nerve agents have been employed in various conflict and terrorist attacks. Currently available CWA degradation techniques include incineration and water hydrolysis followed by biotreatment …
Peroxyoxalate Chemiluminescence And Capillary Electrophoresis : New Methods For Bioanalytical Chemistry, Nian Wu
Graduate Dissertations and Theses
The general research objectives lie in the development of new approaches to improve chemical analysis in the area of bioanalytical chemistry. More specifically this thesis is focused on the development and application of new methodologies and instrumentation involving two potentially powerful techniques: 1) Chemiluminescence-a spectroscopic technique in which the generation of fluorescence from the electronically excited state of the molecule is provided by a chemical reaction and 2) Capillary electrophoresis-a separation technique in which small ions as well as large biomolecules can be separated with high efficiency within a narrow capillary under the influence of high voltage.
Synthesis And Chemistry Of Thione-Iron Carbonyl Complexes, Albert Shil-Kwan Chan
Synthesis And Chemistry Of Thione-Iron Carbonyl Complexes, Albert Shil-Kwan Chan
Graduate Dissertations and Theses
The first examples of sulfur-donor ligand ortho-metallated complexes were obtained in good to excellent yields by reaction of various thiobenzophenones and a thiobenzoate with diiron enneacarbonyl in benzene at room temperature. The known trinuclear complex S2Fe3(CO)9 was a by-product of these reactions, and complexes of the type (Ar2C)S2Fe2(CO)6 were formed in several instances. The structures of these complexes were established on the basis of microanalytical and spectral data as well as by reductive cleavage experiments. Oxidative or photolytic cleavage of the ortho-metallated complexes provides a convenient …