Physical Sciences and Mathematics Commons^™

Crude Oil Characterization Using Gas Chromatography, Ion Mobility Spectrometry And Mass Spectrometry, Clement A. Olanrewaju

FIU Electronic Theses and Dissertations

The characterization of crude oils at the compositional level remains challenging due to their high chemical complexity and isomeric diversity. The present work expands the analytical separation space of chemical components in crude oils by coupling gas chromatography (GC), trapped ion mobility spectrometry (TIMS), and mass spectrometry (GC-TIMS-MS and TIMS-FT-ICR MS) for the effective separation and identification of isomeric compounds. The coupling of GC and TIMS-MS platform enhanced the peak capacity and showed complementary isomeric separation. The combination of GC-TIMS-MS and GC-EI-MS technique provided a comprehensive characterization of PAHs and similar compounds from crude oils on the basis of retention …

Simplifying Sample Preparation Using Fabric Phase Sorptive Extraction: Analysis Of Trace Targeted Pollutant Residues In Environmental, Biological And Food Samples, Rodolfo Mesa

FIU Electronic Theses and Dissertations

Sample preparation is an essential component of analytical methods in chemistry. It is not only necessary but also presents an opportunity to increase the effectiveness of the method significantly. There are various commercially available technologies for sample preparation, including numerous variations of LLE, SPE, and SPME. However, these technologies all present significant deficiencies, including the inability to extract directly from complex samples such as whole milk. Instrumental analysis has been improved greatly in the last two decades but still is not applicable to complex samples without sample preparation.

This work presents the theory of FPSE, including the synthesis of sol-gel …

Trapped Ion Mobility Spectrometry Coupled To Fourier Transform Ion Cyclotron Resonance Mass Spectrometry For The Analysis Of Complex Mixtures., Paolo Benigni

FIU Electronic Theses and Dissertations

Analytical Characterization of complex mixtures, such as crude oil, environmental samples, and biological mixtures, is challenging because of the large diversity of molecular components. Mass spectrometry based techniques are among the most powerful tools for the separation of molecules based on their molecular composition, and the coupling of ion mobility spectrometry has enabled the separation and structural elucidation using the tridimensional structure of the molecule. The present work expands the ability of analytical chemists by furthering the development of IMS-MS instrumentation by coupling Trapped Ion Mobility Spectrometry to Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (TIMS-FT-ICR MS). The TIMS-FT-ICR MS …

Physical And Chemical Characterization Of Crude Oil-Water Mixtures: Understanding The Effects Of Interfacial Process To Chemical Bioavailability, Kathia A. Sandoval

FIU Electronic Theses and Dissertations

This work detailed the physical and chemical characterization of oil water mixtures prepared using fresh and weathered Macondo related oils under different conditions of mixing energy/time and in the presence/absence of chemical dispersants. The results indicated that WAFs produced consistent, droplet free solutions for both source and weathered oils with concentration ranges that represented the soluble components of the oil used. Chemically enhanced WAFs prepared with the source oil generated a large amount of micron-size droplets; however the viscosity of the weathered oils were a limiting factor for the preparation of CEWAFs with weathered oils. Droplet size distributions were influenced …