Physical Sciences and Mathematics Commons^™

Electronic Spectroscopy And Dissociation Dynamics Of Gasphase Transition Metal Containing Cations And Dications, Kanchana Manori Perera

Doctoral Dissertations 1896 - February 2014

Studies of gas-phase ionic clusters have become an integral component in understanding microsolvation and catalysis by transition metal cations. Further interest in this field is due to the possibility of bridging the gap between the condensed and gas phases by developing our understanding of clusters and the possibility that small clusters can have unique chemical and catalytic properties. Most gas phase studies have focused on singly charged ions. Electrospray allows for the production of multiply charged ions solvated by a few solvent molecules. Understanding smaller reactive species such as metal centered clusters with well-defined, gas phase conditions also allows for …