Physical Sciences and Mathematics Commons^™

Crystal Growth And Surface Modification Of Pyrite For Use As A Photovoltaic Material, Eric Rustad Young

Dissertations and Theses

Pyrite (FeS₂) has recently attracted significant interest as a photovoltaic material due to its promising optical properties, high photon to electron conversion yield, and low-cost raw materials. However, hopes have been tempered by recent discoveries that suggest the presence of hard to remove bulk sulfur defects. This research was focused on engineering and implementing the crystallization of pyrite from a sulfur rich solution to counteract the material's natural tendency to form bulk sulfur defects. Homoeptiaxial layers and single-crystal samples have been grown from tellurium sulfur melts with an Fe:S ratio of 1:4 using both natural and synthetic substrates. …

The Effects Of Phosphonic Acids In Dye-Sensitized Solar Cells, Keith Edward James

Dissertations and Theses

Novel methods for the construction of dye-sensitized solar cells (DSSCs) were developed. A thin dense underlayer of TiO₂ was applied on fluorine-doped tin oxide (FTO) glass using as a precursor Tyzor AA-105. Subsequently a mesoporous film of P-25 TiO₂ was applied by spreading a suspension uniformly over the surface of the underlayer and allowing the plate to slowly dry while resting on a level surface. After sintering at 500° C slides were treated with TCPP as a sensitizing dye and assembled into DSSCs. A novel method was used to seal the cells; strips of Parafilm® were used as …

The Synthesis And Characterization Of A Porphyrin Oligomer As A Potential Antenna For Light Harvesting Solar Cells, Tristan Timothy Jenkins

Dissertations and Theses

Mankind's attempts to harvest the sun have resulted in photocells with about 15% overall energy conversion efficiency. The best of these cells consist of a light-sensitive dye attached to a semiconductor. Absorbed light energy is transferred to the semiconductor via the delivery of an excited electron from the dye. Dye electrons are replenished with a redox solution, coupling the dye to the counter electrode.

This research was the beginning of an exploration into some potential improvements in the cell. First of all, the redox solution is a corrosive liquid, and leaks present a problem. A porphyrin oligomer with a TCPP …

Syntheses And Characterizations Of Unsymmetrical Porphyrins As Photosensitizers For A Solid-State Solar Cell, Yinping Zhao

Dissertations and Theses

Solar light is the most important source of regenerative energy and represents mankind's only inexhaustible energy source. One of today's most promising tools to make use of solar energy is its direct conversion into electrical energy in a photovoltaic cell. The practical use of these solar cells depends on the price of the devices and therefore of the obtained energy. The conventional silicon cells, although efficient, are expensive for common consumer applications. The Grätzel cell is a photovoltaic system for harvesting the sun's energy that operates at about 10-15% overall efficiency, like a conventional solar cell, but does it at …

Synthesis And Characterization Of A Porphyrin Dyad, Dale A. Braden

Dissertations and Theses

The sun is a bountiful source of energy for our planet. .With the advent of photovoltaic cells, man has begun harnessing the sun's radiant energy, turning it into a form more directly useful: electricity. Commercially available solar cells currently operate at about 13% efficiency, sufficiently high to make them a viable source of electrical energy. It is of great interest, however, to improve their conversion efficiency, and to lower the cost of production so as to make them more economical, and thereby reduce our dependence upon traditional "dirty" sources of energy such as coal and oil. It has been found …