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Full-Text Articles in Physical Sciences and Mathematics
Solid State Nmr Characterization Of Conductive Polyanilines, Yanina Anatolievna Goddard
Solid State Nmr Characterization Of Conductive Polyanilines, Yanina Anatolievna Goddard
Dissertations, Theses, and Masters Projects
Different forms of ring deuterated polyaniline with different conductivity have been characterized by solid state deuteron nuclear magnetic resonance.;Quadrupole echo (QE) spectra of all forms of polyaniline consist of a superposition of lineshapes for nearly rigid aromatic rings and a small fraction of rings which undergo fast 180?? flips. The intensity of the fast flipping component is temperature dependent and different for conductive emeraldine salt (ES) and non-conductive emeraldine base (EB). This is a manifestation of the different structure and morphology of these polymers.;Simultaneous measurements of QE lineshapes and the relaxation time anisotropies allowed an accurate description of motion in …
Synthesis And Characterization Of Polyimide Residuum, Friable Balloons, Microspheres And Foams, Erik Saul Weiser
Synthesis And Characterization Of Polyimide Residuum, Friable Balloons, Microspheres And Foams, Erik Saul Weiser
Dissertations, Theses, and Masters Projects
In order to meet requirements of future NASA systems for advanced polymeric cellular materials, research was undertaken to develop the next generation of polyimide foams which could be utilized as a reusable structural insulation on future Reusable Launch Vehicle (RLV) Programs. This research activity focused on developing polyimide foam and foam structures which were made using monomeric solutions or salt solutions formed from the reaction of a dianhydride and diamine dissolved in a mixture of foaming agents and alkyl alcohols. This process produced a precursor solid residuum which could then be manufactured into foams, friable balloons and microspheres. Polyimide foams …
Binding Studies On Molecularly Imprinted Polymers, Lucy Yue Hu
Binding Studies On Molecularly Imprinted Polymers, Lucy Yue Hu
Dissertations, Theses, and Masters Projects
Molecular imprinting is a rapidly developing technique for preparation of polymeric materials that are capable of molecular recognition for selective separation and chemical identification. to prepare molecularly imprinted polymers (MIPs), a functional monomer and a crosslinker are polymerized in the presence of a template molecule. Then the template is extracted leaving sites which are complementary in both shape and chemical functionality to those of the template. This resin then becomes capable of selectively absorbing the template species. Because of MIPs' stability, predesigned selectivity, and easy preparation, they have been used for separation, sensor, drug development and directed synthesis.;In this study, …