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Chemistry

Dissertations, Theses, and Masters Projects

Theses/Dissertations

2012

Articles 1 - 6 of 6

Full-Text Articles in Physical Sciences and Mathematics

Dark Matter In The Heavens And At Colliders: Models And Constraints, Reinard Primulando Jan 2012

Dark Matter In The Heavens And At Colliders: Models And Constraints, Reinard Primulando

Dissertations, Theses, and Masters Projects

In this dissertation, we investigate various aspects of dark matter detection and model building. Motivated by the cosmic ray positron excess observed by PAMELA, we construct models of decaying dark matter to explain the excess. Specifically we present an explicit, TeV-scale model of decaying dark matter in which the approximate stability of the dark matter candidate is a consequence of a global symmetry that is broken only by instanton-induced operators generated by a non-Abelian dark gauge group. Alternatively, the decaying operator can arise as a Planck suppressed correction in a model with an Abelian discrete symmetry and vector-like states at …


Thermochemistry Of Amino Acids And Constrained Diamines, Erica Jane Tullo Jan 2012

Thermochemistry Of Amino Acids And Constrained Diamines, Erica Jane Tullo

Dissertations, Theses, and Masters Projects

The gas-phase proton affinities of several highly basic amino acids and diamines were determined using the extended kinetic method in an ESI-quadrupole ion trap instrument. The non-protein amino acid L-canavanine is structurally related to L-arginine with an oxygen substituted for the terminal methylene group of L-arginine and is highly toxic to humans. The proton affinity of L-arginine, a protein amino acid, was determined to be 1036 kJ mol -1, whereas the proton affinity of L-canavanine was determined to be 1005 kJ mol-1. Thus, substitution of an oxyguanidino group for the guanidine group in L-arginine results in a large decrease in …


Fluorescence Quenching Of Ppv-So And Bodipy-Naphthalene Systems, Brooklynd Dawn Saar Jan 2012

Fluorescence Quenching Of Ppv-So And Bodipy-Naphthalene Systems, Brooklynd Dawn Saar

Dissertations, Theses, and Masters Projects

No abstract provided.


Luminescent Nitrogen And Sulfure Adducts Of Cui Disubstituted Piperazine Complexes, Jason P. Safko Jan 2012

Luminescent Nitrogen And Sulfure Adducts Of Cui Disubstituted Piperazine Complexes, Jason P. Safko

Dissertations, Theses, and Masters Projects

No abstract provided.


Effects Of Nucleophile Strength On Selectivity In Bibr3 Catalyzed Cyclic Ether Construction, Ajara A. Rahman Jan 2012

Effects Of Nucleophile Strength On Selectivity In Bibr3 Catalyzed Cyclic Ether Construction, Ajara A. Rahman

Dissertations, Theses, and Masters Projects

No abstract provided.


The Role Of Small Carboxylic Acids During Poly(Amide) 11 Hydrolysis, John-Andrew Samuel Hocker Jan 2012

The Role Of Small Carboxylic Acids During Poly(Amide) 11 Hydrolysis, John-Andrew Samuel Hocker

Dissertations, Theses, and Masters Projects

No abstract provided.