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Full-Text Articles in Physical Sciences and Mathematics
Activation Of Tri(2-Furyl)Phosphine At A Dirhenium Centre: Formation Of Phosphido-Bridged Dirhenium Complexes, Shishir Ghosh, Mansura Khatun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, Dennis W. Bennett, Graeme Hogarth, Ebbe Nordlander, Shariff E. Kabir
Activation Of Tri(2-Furyl)Phosphine At A Dirhenium Centre: Formation Of Phosphido-Bridged Dirhenium Complexes, Shishir Ghosh, Mansura Khatun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, Dennis W. Bennett, Graeme Hogarth, Ebbe Nordlander, Shariff E. Kabir
Chemistry Faculty Research and Publications
Reaction of tri(2-furyl)phosphine (PFu3) with [Re2(CO)10−n(NCMe)n] (n = 1, 2) at 40 °C gave the substituted complexes [Re2(CO)10−n(PFu3)n] (1 and 2), the phosphines occupying axial position in all cases. Heating [Re2(CO)10] and PFu3 in refluxing xylene also gives 1 and 2 together with four phosphido-bridged complexes; [Re2(CO)8−n(PFu3)n(μ-PFu2)(μ-H)] (n = 0, 1, 2) (3–5) and [Re2(CO)6 …
Investigations Of 2-Thiazoline-2-Thiol As A Ligand: Synthesis And X-Ray Structures Of [Mn2(Co)7(Μ-Ns2C3H4)2] And [Mn(Co)3(Pph3)(Κ2-Ns2C3H4)], Shishir Ghosh, Faruque Ahmed, Rafique Al-Mamun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, Dennis W. Bennett, Shariff E. Kabir
Investigations Of 2-Thiazoline-2-Thiol As A Ligand: Synthesis And X-Ray Structures Of [Mn2(Co)7(Μ-Ns2C3H4)2] And [Mn(Co)3(Pph3)(Κ2-Ns2C3H4)], Shishir Ghosh, Faruque Ahmed, Rafique Al-Mamun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, Dennis W. Bennett, Shariff E. Kabir
Chemistry Faculty Research and Publications
Treatment of Mn2(CO)10 with 2-thiazoline-2-thiol in the presence of Me3NO at room temperature afforded the dimanganese complexes [Mn2(CO)7(μ-NS2C3H4)2] (1) and [Mn2(CO)6(μ-NS2C3H4)2] (2) in 51 and 34% yields, respectively. Compound 1 was quantitatively converted into 2 when reacted with one equiv of Me3NO. Reaction of 1 with triphenylphosphine at room temperature furnished the mononuclear complex [Mn(CO)3(PPh3)(κ 2 …