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Full-Text Articles in Physical Sciences and Mathematics
Variation Of Anions In Layered Double Hydroxides: Effects On Dispersion And Fire Properties, Linjiang Wang, Shengpei Shu, Dan Chen, Charles A. Wilkie
Variation Of Anions In Layered Double Hydroxides: Effects On Dispersion And Fire Properties, Linjiang Wang, Shengpei Shu, Dan Chen, Charles A. Wilkie
Chemistry Faculty Research and Publications
Layered double hydroxides (LDHs) are interesting materials for nanocomposite formation because one can vary the identity of the metals, the anions and the stoichiometry to see the effect of these on the ability of the nano-material to disperse in a polymer and to see what effect dispersion has on the properties of the polymer. In this study, the anions 2-ethylhexyl sulfate (SEHS), bis(2-ethylhexyl) phosphate (HDEHP) and dodecyl benzenesulfonate (SDBS) have been utilized as the charge balancing anions to synthesize organo-LDHs. Nanocomposites of poly(methyl methacrylate) (PMMA) and polystyrene (PS) with organo-LDHs were prepared both by melt blending and bulk polymerization. X-ray …