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Decarbonylation Reaction Of [Os3(Co)10(Μ-H)(Μ-Sn2C4H5)]: X-Ray Structures Of The Two Isomers Of [Os3(Co)9(Μ-H)(Μ3-Η2-Sn2C4H5)], Shishir Ghosh, Shariff E. Kabir, Mansura Khatun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, Dennis W. Bennett
Decarbonylation Reaction Of [Os3(Co)10(Μ-H)(Μ-Sn2C4H5)]: X-Ray Structures Of The Two Isomers Of [Os3(Co)9(Μ-H)(Μ3-Η2-Sn2C4H5)], Shishir Ghosh, Shariff E. Kabir, Mansura Khatun, Daniel T. Haworth, Sergey V. Lindeman, Tasneem Siddiquee, Dennis W. Bennett
Chemistry Faculty Research and Publications
The thermal reaction of [Os3(CO)10(μ-H)(μ-SN2C4H5)] (1) at 110 °C afforded the new compound [Os3(CO)9(μ-H)(μ 3-η 2-SN2C4H5)] (2) in 84% yield. Compound 2 exists as two isomers, which differ in the disposition of the bridging hydride ligand. Both of the isomers of 2 have been characterized by a combination of elemental analysis, infrared and 1H NMR spectroscopic data together with single crystal X-ray crystallography. The isomers …