Physical Sciences and Mathematics Commons^™

Toward The Synthesis Of Functionalized Poly (Ether Ether Ketone): Monitoring The Meta-Fluorine Displacement In 3,5,4’-Trifluorobenzophenone, Giovanni Covarrubias

Browse all Theses and Dissertations

The synthesis of functionalized, linear poly (ether ether ketone), tailored to be semi-crystalline and soluble in a variety of organic-solvents was explored. Nucleophilic aromatic substitution was a chemical reaction method used to condense 3,5,4’-trifluorobenzophenone (TFK) with four different phenols at its para-positioned carbon-fluorine site: 4-methoxyphenol, 3-aminophenol, 4-bromophenol, and m-cresol. Further poly-condensation of functionalized TFK occurred at the meta-positioned carbon-fluorine sites with 4,4’-Bis[4-hydroxyphenoxy] benzophenone (Big A2) and 4,4’-difluorobenzophenone at molar equivalents of 1 to 0.5, respectively. The reaction afforded products that became insoluble in solvents needed for nuclear magnetic resonance spectroscopic (e.g. DMSO-d6) analysis. The lack of desirable compounds compelled the …