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Chemistry

Browse all Theses and Dissertations

Theses/Dissertations

2021

Chemistry

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Full-Text Articles in Physical Sciences and Mathematics

The Formation Of Prenucleation Clusters For Calcium Fluoride, Taylor M. Muterspaw Jan 2021

The Formation Of Prenucleation Clusters For Calcium Fluoride, Taylor M. Muterspaw

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There have been limited studies on the analysis of the nucleation and precipitation behind calcium fluoride. Earlier studies support a nucleation mechanism in agreement to classical nucleation theory (CNT) in which a surface nucleation mechanism is required for calcium fluoride. This experiment devised using the ISE method to calcium fluoride to find evidence of a nucleation mechanism like that of calcium carbonate (prenucleation cluster pathway). The potential and pH were recorded versus time and the potential data was converted to nCa2+ data of free calcium ions. It was determined that there was evidence of a similar nucleation mechanism for calcium …


Investigation Into The Source Of Contamination Of Surface Waters Flowing Through The Wright State University Woods, Nnadozie Kennedy Okeke Jan 2021

Investigation Into The Source Of Contamination Of Surface Waters Flowing Through The Wright State University Woods, Nnadozie Kennedy Okeke

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This investigative research was carried out with the purpose of determining the source of contaminants present in the surface waters flowing through the Wright State University woods. Five sample sites going from upstream to downstream namely; Inflow to Nutter Center Pond (INNCP), Nutter Center Pond (NCP), Outfall 21 (OTF 21), Burley, and Outfall 15 (OTF 15), were sampled over a time period spanning from June 2020 to January 2021. Samples collected were analyzed for Escherichia coli (E. coli) using 3M™ Petrifilm™ E. coli/Coliform Count (EC) plates, select anions (Phosphate PO43-, Nitrate NO3-, Sulfate SO42-, Fluoride F- and Chloride Cl-) using …


Cytoviva Hyperspectral Imaging For Comparing The Uptake And Transformation Of Agnps And Ag+ In Mitochondria, Kristina Steingass Jan 2021

Cytoviva Hyperspectral Imaging For Comparing The Uptake And Transformation Of Agnps And Ag+ In Mitochondria, Kristina Steingass

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Nanomaterials have attracted significant attention in the last decade, with applications in everyday products. Amongst all known nanomaterials in use, silver is the leading metal, present in 531 different types of products, owing to their unique optical, electrical, antimicrobial, and thermal properties. Though silver nanoparticles (AgNPs) come in contact regularly with the general population, there is little known about their toxicity mechanism due to limited techniques for thorough analysis. CytoViva Hyperspectral Imaging (HSI) shows potential for filling these gaps. In this study, borohydride-capped AgNPs with an approximate diameter of 10 nm were synthesized using the modified Creighton method and characterized …


Benzotriazole And Tolytriazole Analysis In Select Surface Waters Near Wilmington Air Park, Lee A. Raska Jan 2021

Benzotriazole And Tolytriazole Analysis In Select Surface Waters Near Wilmington Air Park, Lee A. Raska

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Previous investigations into the presence of benzotriazole (BTZ) and corresponding analogs done in early 2019 found elevated levels near the Wilmington Air Park in Wilmington, Ohio. The analogs detected were 4-methyl-1H-benzotriazole and 5-methyl-1H-benzotriazole: known together as tolytriazole (TTZ). BTZ and TTZ are emerging environmental contaminants of concern that are often found in aircraft de-icing solutions, anti-icing solutions and detergents. The Wilmington Air Park has two facilities used to pre-treat runoff water before its subsequent release into surrounding streams. Three sites were chosen: Lytle Creek, Indian Run, and Cowan Creek. For the 2019 and 2019/2020 investigative projects, Cowan Creek was designated …