Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Chemistry

Articles

2013

Photocatalysis

Articles 1 - 4 of 4

Full-Text Articles in Physical Sciences and Mathematics

A Simple Inexpensive Method For The Rapid Testing Of The Photocatalytic Activity Of Self Cleaning Surfaces, Andrew Mills, James Hepburn, David Hazafy, Christopher O'Rourke, Josef Krysa, Michal Baudys, Martin Zlamal, Hana Bartkova, Claire Hill, Kim Winn, Morten Simonsen, Erik Sogaard, Suresh Pillai, Nigel Leyland, Rachel Fagan, Frank Neumann, Christina Lampe, Tobias Graumann Nov 2013

A Simple Inexpensive Method For The Rapid Testing Of The Photocatalytic Activity Of Self Cleaning Surfaces, Andrew Mills, James Hepburn, David Hazafy, Christopher O'Rourke, Josef Krysa, Michal Baudys, Martin Zlamal, Hana Bartkova, Claire Hill, Kim Winn, Morten Simonsen, Erik Sogaard, Suresh Pillai, Nigel Leyland, Rachel Fagan, Frank Neumann, Christina Lampe, Tobias Graumann

Articles

A rapid semi-quantitative, inexpensive method,using a simple digital scanner and an indicator ink, suitable for use in the laboratory, or in the field, for assessing the photocatalytic activity of commerical photocatalytic self-cleaning materials such as glass, is described. The repeatability of the current method is found to be hight and better than many of the previously reported ISO photocatalyst tests.


Novel Microwave Assisted Synthesis Of Zns Nanomaterials, Suresh Pillai, Michael Seery, Damian Synnott, John Colreavy, Stephen Hinder Jan 2013

Novel Microwave Assisted Synthesis Of Zns Nanomaterials, Suresh Pillai, Michael Seery, Damian Synnott, John Colreavy, Stephen Hinder

Articles

A novel ambient pressure microwave-assisted technique is developed in which silver and indium modified ZnS is synthesised. The as prepared ZnS is characterised by X-ray diffraction, UV-Vis spectroscopy, X-ray photoelectron spectroscopy and luminescence spectroscopy. This procedure produced crystalline materials with particle sizes below 10 nm. The synthesis technique leads to defects in the crystal which induce mid energy levels in the band gap and lead to indoor light photocatalytic activity. Increasing the amount of silver causes a phase transition from cubic blende to hexagonal phase ZnS. In a comparative study, when the ZnS cubic blende is heated in a conventional …


A Highly Efficient Tio2-Xcx Nano-Heterojunction Photocatalyst For Visible-Light Induced Antibacterial Applications, Vinodkumar Etacheri, Michael Seery, Stephen Hinder, Georg Michlits, Suresh Pillai Jan 2013

A Highly Efficient Tio2-Xcx Nano-Heterojunction Photocatalyst For Visible-Light Induced Antibacterial Applications, Vinodkumar Etacheri, Michael Seery, Stephen Hinder, Georg Michlits, Suresh Pillai

Articles

Visible-light-induced antibacterial activity of carbon-doped anatase-brookite titania nano-heterojunction photocatalysts are reported for the first time. These heterostructures were prepared using a novel low temperature (100 °C) non-hydrothermal low power microwave (300 W) assisted method. Formation of interband C 2p states was found to be responsible for the band gap narrowing of the carbon doped heterojunctions. The most active photocatalyst obtained after 60 minutes of microwave irradiation exhibits a 2-fold higher visible-light induced photocatalytic activity in contrast to the standard commercial photocatalyst Evonik-Degussa P-25. Staphylococcus aureus inactivation rate constant for carbon-doped nano-heterojunctions and the standard photocatalyst was 0.0023 and -0.0081 min …


Uv And Visible Light Activated Tio2 Photocatalysis Of 6-Hydroxymethyluracil, A Model Compound For The Potent Cyanotoxin Cylindrospermopsin, Cen Zhao, Miquel Pelaez, Dionysios Dionysiou, Suresh Pillai, John Byrne, Kevin O'Shea Jan 2013

Uv And Visible Light Activated Tio2 Photocatalysis Of 6-Hydroxymethyluracil, A Model Compound For The Potent Cyanotoxin Cylindrospermopsin, Cen Zhao, Miquel Pelaez, Dionysios Dionysiou, Suresh Pillai, John Byrne, Kevin O'Shea

Articles

TiO2 photocatalyses of 6-hydroxymethyl uracil (6-HOMU) a model compound for the potent cyanotoxin, cylindrospermopsin (CYN), were carried out employing visible and UV irradiation using different non-metal doped TiO2 materials, nitrogen and fluorine-TiO2 (NF-TiO2), phosphorus and fluorine-TiO2 (PF-TiO2) and sulfur-TiO2 (S-TiO2). The model compound was readily degraded under UV TiO2 photocatalysis with pseudo-first-order rate constants (k) of 2.1, 1.0, and 0.44 h−1 for NF-TiO2, PF-TiO2 and S-TiO2, respectively. Under visible light activated (VLA), NF-TiO2 was the most active photocatalyst, PF-TiO …