Physical Sciences and Mathematics Commons^™

(E)-6,6′-(Diazene-1,2-Di­Yl)Bis­(1,10-Phenanthrolin-5-Ol) Tri­Chloro­Methane Disolvate: A Superconjugated Ligand, Muhib Ahmed, Michael Devereux, Vickie Mckee, Malachy Mccann, A. Denise Rooney

Articles

Phenanthroline ligands are important metal-binding mol­ecules which have been extensively researched for applications in both material science and medicinal chemistry. Azo­benzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as mol­ecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C24H14N6O2·2CHCl3.