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Chemistry

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

2016

Diffusion Monte Carlo

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Computational Studies Of Microscopic Superfluidity In 4he Clusters, Angeline R. Wairegi May 2016

Computational Studies Of Microscopic Superfluidity In 4he Clusters, Angeline R. Wairegi

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The onset of microscopic superfluidity has been reported in ultracold droplets of bosons (4He atoms or para-H2 molecules) containing a variety of molecular dopants. The physics of these droplets involve both Bose-Einstein condensation (BEC) and superfluidity. The two phenomena, while closely related, are not exactly the same. Superfluidity is fundamentally a microscopic effect and thermodynamic limit is necessary; it is still remarkable, though, that the signature of superfluidity has been reported in doped droplets consisting of as few as 4 4He atoms. The studies presented here adopt a molecular vantage point to investigate the quantum mechanics …