Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Physical Sciences and Mathematics
Carbon Monoxide On Demand: Light-Induced Co Release Of Flavonols, Stacey N. Anderson
Carbon Monoxide On Demand: Light-Induced Co Release Of Flavonols, Stacey N. Anderson
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Carbon monoxide (CO) is an extremely useful molecule with applications in industrial manufacturing, synthetic procedures as a C1 building block, and as a potential pharmaceutical to produce anti-inflammatory effects and vasodilation. However, the toxicity associated with CO has prevented its full utilization. In order to safely handle CO, compounds and molecules have been developed that act as storage materials for the gas. Ideal storage platforms only release CO upon stimulation via a trigger. Light activation is the most desirable trigger as it can be regulated in terms of the intensity and the wavelength of light used. The majority of light-induced …
Oxidative Aliphatic Carbon-Carbon Bond Cleavage Reactions, Caleb J. Allpress
Oxidative Aliphatic Carbon-Carbon Bond Cleavage Reactions, Caleb J. Allpress
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
The work presented in this dissertation has focused on the activation and cleavage of chemical bonds between two carbon atoms. The selective oxidative activation of carbon-carbon bonds is important due to potential applications in the utilization of biomass for fuel production, applications in wastewater treatment and bioremediation, and in developing new reactions for organic synthesis of fine chemicals including pharmaceuticals. Ideally these reactions would be carried out with high atom economy at low temperatures and pressures, and using earth-abundant elements as reagents and catalysts. With these points in mind, nature provides an ideal model framework, carrying out its chemistry at …