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Chemistry

Wright State University

Theses/Dissertations

2006

Chemistry

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Water Solubility Characteristics Of Hydrophobically Modified Polyethyleneimines, Jennifer N. Williams Aug 2006

Water Solubility Characteristics Of Hydrophobically Modified Polyethyleneimines, Jennifer N. Williams

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Commercially available polyethyleneimines varying in molecular weights and viscosities were synthetically modified in order to increase their hydrophobicity when dissolved in water. Used as additives for inkjet industry inks, these polymers have been designed to promote interaction between formulated inks and paper, while increasing the water-fastness of these water-soluble inks once they are dried on bond paper. Waterfastness, the ability of an ink to maintain print integrity once it becomes wet, as well as optical density, solubility, pH, molecular weight, polydispersity and viscosity are amongst the characteristics analyzed. The modifications of these polyethyleneimines (PEis) with alkyl bromides and alkyl epoxides …