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Bidentate Ferrocenyl-Dithiol Reagents For Nanocluster Surface Functionalization, Yiyi Liu

Electronic Thesis and Dissertation Repository

Previous work using monodentate ferrocenyl-chalcogen reagents for nanocluster surface functionalization has indicated an effective way to involve ferrocene moieties onto the surface of these frameworks. However, the abilities of the large polynuclear nanocluster with ferrocene rich surface to form crystalline materials suitable for single crystal X-ray analysis proved to be limited. New bidentate ferrocenyl-chalcogen reagents have been synthesized and characterized in order to probe their ability in this case.

The preparation of new bidentate ferrocenyl chalcogen reagents 1,1’-fc(C{O}OCH₂CH₂SH)₂ (fc = ferrocenyl) and 1,1’-fc(C{O}NHCH₂CH₂SH)₂ are presented. Furthermore, the preparation of silylated …