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Full-Text Articles in Physical Sciences and Mathematics

Caffeine And Acetaminophen Concentration And Other Water Quality Parameters Along The Middle To Lower Bear River, Autumn Slade May 2017

Caffeine And Acetaminophen Concentration And Other Water Quality Parameters Along The Middle To Lower Bear River, Autumn Slade

Undergraduate Honors Capstone Projects

Various water quality parameters were measured at seven sites along the Middle to Lower Bear River and compared across the sites, to past data and to set standards in Utah and Idaho. Much of the data was comparable to past data with most state standards being met. However, nitrate was above indicator level for half of the sites, and turbidity is a problem at the last two sites. Also, chloride and unionized ammonia are at high levels by the last site. Overall, the river tended to decrease in water quality as it moved downstream, with dams like at Cutler Reservoir …


The Effect Of Pure Infrared Light On The Growth Of Rhodospirrilum Rubrum, Jordan Lee Wilkes May 2016

The Effect Of Pure Infrared Light On The Growth Of Rhodospirrilum Rubrum, Jordan Lee Wilkes

Undergraduate Honors Capstone Projects

Scientists who study aquatic ecosystems quickly notice a diversity of pathways that different microbes and organisms can use to metabolize nutrients found in common ponds or pools. Competition for vital resources, such as light and inorganic minerals, allow only certain organisms to grow in certain niches within these ecosystems. Rhodospirillum rubrum is a gram negative, photosynthetic bacteria that competes for light within aquatic ecosystems in order to survive. R. rubrum is believed to specifically absorb light for photosynthesis at wavelengths in the range of infrared light. It was found that R. rubrum indeed can grow in "dark", anaerobic environments by …


Diffusion Monte Carlo Studies Of Quantum Solvation: Finding Nodal Functions Of Wavefunctions Using A Genetic Algorithm, Christina Hansen Howell May 2010

Diffusion Monte Carlo Studies Of Quantum Solvation: Finding Nodal Functions Of Wavefunctions Using A Genetic Algorithm, Christina Hansen Howell

Undergraduate Honors Capstone Projects

Solvation is important in many chemical reactions since most reactions occur in solution. Recently, progress has been made using helium-4 nanodroplets as the solvent at temperatures close to absolute zero. Because helium-4 is a superfluid it solvates dissolved molecules much differently that does a conventional solvent. This opens up the possibility of performing new types of chemistry in the superfluid environment. However, the nature of the interaction of the dissolved species with the solvent remains poorly understood. The basic question to be answered in this project is: how does the quantum solvent perturb the rotational dynamics of the solute particles? …


Oxidative Damage Caused By Iron Loading Into Ferritin, Talina Christensen Watts May 2006

Oxidative Damage Caused By Iron Loading Into Ferritin, Talina Christensen Watts

Undergraduate Honors Capstone Projects

Ferritin is the iron storage protein found in humans, animals, plants, fungi and bacteria. We are interested in how iron is loaded and stored in mammalian ferritin. Ferrous iron must be oxidized to ferric iron in order to be stored in ferritin. It is generally believed that ferritin does the loading itself, dependant upon a "ferroxidase activity." Oxidation of iron can result in the production of the hydroxyl radical which can cause oxidative damage to surrounding proteins and other biomolecules. An indicator of oxidative damage to proteins is the formation of carbonyl groups. Using only the H subunit of human …


Genetic Analysis Of Acetone Carboxylase In Azotobacter Vinelandii, Jessica Gardner May 2004

Genetic Analysis Of Acetone Carboxylase In Azotobacter Vinelandii, Jessica Gardner

Undergraduate Honors Capstone Projects

Acetone carboxylase, an inducible multimeric enzyme found in several bacteria, catalyzes the carboxylation of acetone to produce acetoacetate. This is an important reaction for the bacteria because, upon addition of coenzyme A, the acetoacetate can be converted to acetyl-CoA, a common metabolic intermediate. Azotobacter vinelandii, one of the bacteria that produces acetone carboxylase, has two different genes encoding this enzyme. We knocked out the first of these by disrupting it with a kanamycin cassette to help us understand the function of the second gene. Knocking out the gene will also make possible the use of site-directed mutagenesis to further study …


Determination Of Intracellular Glutathione Concentration Using Monobromobimane, Ryan R. Owens May 1998

Determination Of Intracellular Glutathione Concentration Using Monobromobimane, Ryan R. Owens

Undergraduate Honors Capstone Projects

Asbestos is a general term for a group of fibrous silicates. Diseases such as asbestosis, bronchogenic carcinoma, and mesothelioma have been linked to asbestos exposure (1,2). The 1 two classes of asbestos, serpentine and amphibole, are distinguished by differences in structure and chemical composition (3). The amphibole crocidolite contains 27% iron while the serpentine chrysotile contains only 2-3% iron. The higher iron content of crocidolite is proposed to be a contributing factor for a much higher incidence of cancer with crocidolite exposure compared with chrysotile exposure ( 4). Iron mobilized intracellularly from asbestos fibers may participate in the formation of …


Plant-Availability Fractionation Of Nickel For Bioremediation, Jason Henrie May 1998

Plant-Availability Fractionation Of Nickel For Bioremediation, Jason Henrie

Undergraduate Honors Capstone Projects

The bioremediation of contaminated soils or the biomining of waste tillings has been explored through the use of hyperaccumulating plants such as S. polygaloides which is a nickel hyperaccumulator. However, it is important to discover which soils are well-suited for this type of process by determining the plant-availability of the nickel. By extracting the nickel sequentially with increasing severity it is possible to determine the chemical distribution, or fractionation, of nickel in a soil. One fraction is already suspected to be plant-available and correlates very well with the results of a previous plant-availability study. A calcareous Millville silt loam which …


Thermal Decomposition Of Cp*Re(Co)(No)No2, Kale Allen Swainston May 1998

Thermal Decomposition Of Cp*Re(Co)(No)No2, Kale Allen Swainston

Undergraduate Honors Capstone Projects

The focus of this work is to examine the thermal reactivity of the Cp*Re(CO)(NO)NO2 complex. Upon heating with a flame, the orange crystals decompose very rapidly, with a darkening of color and gas production. To investigate this reaction, the decomposition was carefully controlled by heating with N2 gas, and in heated solution. The products obtained from the heated solution were purified using column chromatography, yielding two new interesting compounds, believed to be Cp*ReNO dimers with bridging oxygens.


Site-Directed Mutagenesis Of The Nitrogenase Fe-Protein From Azotobacter Vinelandii, Talmage L. Shill May 1998

Site-Directed Mutagenesis Of The Nitrogenase Fe-Protein From Azotobacter Vinelandii, Talmage L. Shill

Undergraduate Honors Capstone Projects

Nitrogen fixation is the chemical reaction of dinitrogen (N2) being reduced to ammonia (NH3). This reaction occurs naturally by nitrogen fixing microorganisms which contain the enzyme nitrogenase. The overall reaction is written below.


Synthesis And Protection Of Nitrogen Containing Heterocycles, Timothy I. Elwell May 1997

Synthesis And Protection Of Nitrogen Containing Heterocycles, Timothy I. Elwell

Undergraduate Honors Capstone Projects

The pyrrolo[2,3-d] pyrimidine ring systems are present in a variety of antibacterial/anticancer compounds. A scarcity of natural sources has made necessary the need for researchers to find more efficient methodologies to synthesize such compounds.1 The Edstrom research group is currently exploring new routes to these compounds, varying the protecting groups and the precursors used to make them.


Iron-Dithiothreitol Dependent Production Of 8-Hydroxy-2'-Deoxyguanosine In Dna, David Allan Cook May 1995

Iron-Dithiothreitol Dependent Production Of 8-Hydroxy-2'-Deoxyguanosine In Dna, David Allan Cook

Undergraduate Honors Capstone Projects

Oxidative damage to DNA in a metal-thiol system was studied. Calf thymus DNA was incubated in an iron(IIl)-dithiothreitol system prepared in various buffers. Damage was measured by monitoring the production of 8-hydroxy-2'-deoxyguanosine. DNA oxidation was proportional to the concentration of dithiothreitol (DTT) in HEPES and tris(hydroxymethyl)aminomethane (Tris) buffers while it was only roughly related to DTT concentration in sodium chloride. Incubation in potassium phosphate buffer produced no damage. The results indicate that hydroxyl radicals may be generated by the iron-OTT system in HEPES, Tris, and sodium chloride, while in the phosphate buffer an iron phosphate complex may be formed which …


Investigation Of New Methods For The Synthesis Of Pyrrolidines And The Generation Of Novel Heterocumulenes, Travis R. Taylor Oct 1994

Investigation Of New Methods For The Synthesis Of Pyrrolidines And The Generation Of Novel Heterocumulenes, Travis R. Taylor

Undergraduate Honors Capstone Projects

The following paper is a summary of the research completed from March to August of 1990. This research project proceeded through the guidance of Dr. Eric Edstrom incorporating a senior thesis in conjunction with the Honors Program.


Oxidation Of Thin Silver Films By Ozone And Atomic Oxygen, Lawrence R. Thorne Jan 1973

Oxidation Of Thin Silver Films By Ozone And Atomic Oxygen, Lawrence R. Thorne

Undergraduate Honors Capstone Projects

Recently, thin silver film detectors have been used to determine atomic oxygen profiles in the 70-100 km region of the upper atmosphere. The detectors' sensitivity to atomic oxygen is the result of the formation of silver oxide(s) which cause their electrical resistance to increase. A common procedure to calibrate and to make these detectors more sensitive is to cycle them through a series of three or more oxidations and reductions. This paper indicates that this cycling makes silver films more sensitive to ozone, causing them to be usable only at heights greater than 38 km. Also reported herein are experimentally …