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Physical Sciences and Mathematics Commons

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Chemistry

University of Texas Rio Grande Valley

Theses/Dissertations

2011

Pure sciences

Articles 1 - 3 of 3

Full-Text Articles in Physical Sciences and Mathematics

Creation Of Post Ap Chemistry Class, Julian Medrano Aug 2011

Creation Of Post Ap Chemistry Class, Julian Medrano

Theses and Dissertations - UTB/UTPA

The creation of a Post AP Chemistry Class to be taught at the high school level for grade 12 students is discussed. The class is to be taught under the supervision of the University of Texas Pan American professors and taught by an MS Chemistry teacher, in order to better transition students into upper level chemistry courses beyond Chemistry 1401 and 1402.


Biocompatibility Of Electrospun Polymer Nanofibers (Epns) With Nih 3t3 Cell Line And Interaction Of Quercetin With Different Flavonoids: Induction Of Phase Ii Enzymes In Vitro Cancer Cell Lines, Brenda S. Benavides May 2011

Biocompatibility Of Electrospun Polymer Nanofibers (Epns) With Nih 3t3 Cell Line And Interaction Of Quercetin With Different Flavonoids: Induction Of Phase Ii Enzymes In Vitro Cancer Cell Lines, Brenda S. Benavides

Theses and Dissertations - UTB/UTPA

Part I: In this study Electrospun nanofibers, Elasthane™ 55D, Elasthane™ 75D, Biospan®, Hydrothane™ and Lycra® were evaluated for their biocompatibility to be artificial tissue substitutes using NIH-3T3 fibroblast cells. A colorimetric based MTT dye reduction assay demonstrated that EPNs did not stop cell growth in vitro. Additionally, fluorescence confocal microscope images verified that cell adhesion occurred in the nanofibers, and cell growth on the EPNs over two weeks period was confirmed by DNA quantification.

Part II: This section of the thesis is focused on evaluation of chemopreventive properties of various phytochemicals by induction of Phase II enzymes. The interaction of …


Synthesis And Characterization Of 4,4-Prime-Distyrylbiphenyl And Its Applications In Organic Field Effect Transistors, Nestor A. Santos Jr. May 2011

Synthesis And Characterization Of 4,4-Prime-Distyrylbiphenyl And Its Applications In Organic Field Effect Transistors, Nestor A. Santos Jr.

Theses and Dissertations - UTB/UTPA

4,4’-distyrylbiphenyl (DSBP), an ambipolar small molecule with electroluminescent properties, was synthesized following two synthetic protocols. Accordingly, biphenyl was bromomethylated using a mixture of paraformaldehyde and hydrogen bromide in 20% to 60% isolated yields. Bromomethylated biphenyl was then reacted with triphenyl phosphine, or with triethyl phosphate to yield the corresponding triphenyl phosphonium bromide or triethyl phosphonate, respectively. DSBP was synthesized by reaction of the triphenyl phosphonium bromide or triethyl phosphonate with freshly distilled benzaldehyde according to the Wittig, or Horner-Wadsworth-Emmons protocols. DSBP from the Wittig reaction resulted in a mixture of cis-trans isomers, while the product from the Horner-Wadsworth-Emmons reaction yielded …