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Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Chemistry

University of South Carolina

Theses/Dissertations

2021

Nanomaterials

Articles 1 - 2 of 2

Full-Text Articles in Physical Sciences and Mathematics

Investigations On The Surface Chemistry Of Colloidal Quantum Dots Towards Fluorescent Biological Probes, John Hardin Dunlap Oct 2021

Investigations On The Surface Chemistry Of Colloidal Quantum Dots Towards Fluorescent Biological Probes, John Hardin Dunlap

Theses and Dissertations

Colloidal semiconductor quantum dots (QDs) have garnered significant interest as promising materials for biological applications due to their improved photostability and narrow, tunable photoluminescence properties compared to organic fluorophores. To facilitate their utility as fluorescent bioimaging probes, QDs must undergo post-synthetic modifications to exchange their native hydrophobic ligands from synthesis with hydrophilic ones that enable colloidal dispersions in aqueous environments. Many examples exist that demonstrate surface modifications for water-soluble QDs and their efficacy in biological systems, however, there is a need to develop a more thorough understanding of how hydrophilic ligands coordinate to QD surfaces in order to develop more …


Plasmonic Metallic And Semiconductor Nanomaterials, Mengqi Sun Jul 2021

Plasmonic Metallic And Semiconductor Nanomaterials, Mengqi Sun

Theses and Dissertations

The earliest account of localized surface plasmon resonance (LSPR) has to date back to the ancient age of Rome in 400 A.D. The famous glass of Lycurgus cup told the story of unique light-and-matter interaction at the nanoscale that confines the electromagnetic field resonance at its surface and therefore allows LSPR feature to noticeably arise. The conventional metallic LSPR nanomaterials, like Au and Ag nanoparticles attract constant attentions due to their synthetic simplicity, chemical robustness, and visible spectral response. Its ability to generate sensitive dielectric sensing of the surroundings, strong electromagnetic field and active charge carriers upon optical excitation triggered …