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Full-Text Articles in Physical Sciences and Mathematics
A Comparison Of Gc-Fid And Ptr-Ms Toluene Measurements In Ambient Air Under Conditions Of Enhanced Monoterpene Loading, Jesse L. Ambrose, K. Haase, R. S. Russo, Y. Zhou, M. L. White, E. K. Frinak, C. Jordan, Howard R. Mayne, Robert W. Talbot, B. C. Sive
A Comparison Of Gc-Fid And Ptr-Ms Toluene Measurements In Ambient Air Under Conditions Of Enhanced Monoterpene Loading, Jesse L. Ambrose, K. Haase, R. S. Russo, Y. Zhou, M. L. White, E. K. Frinak, C. Jordan, Howard R. Mayne, Robert W. Talbot, B. C. Sive
Chemistry
Toluene was measured using both a gas chromatographic system (GC), with a flame ionization detector (FID), and a proton transfer reaction-mass spectrometer (PTR-MS) at the AIRMAP atmospheric monitoring station Thompson Farm (THF) in rural Durham, NH during the summer of 2004. Simultaneous measurements of monoterpenes, including alpha- and beta-pinene, camphene, Delta(3)-carene, and d-limonene, by GC-FID demonstrated large enhancements in monoterpene mixing ratios relative to toluene, with median and maximum enhancement ratios of similar to 2 and similar to 30, respectively. A detailed comparison between the GC-FID and PTR-MS toluene measurements was conducted to test the specificity of PTR-MS for atmospheric …
2,3-Bis(Bromomethyl)-1,4-Diphenylbenzene, Jonathan B. Briggs, Mikael D. Jazdzyk, Glen P. Miller
2,3-Bis(Bromomethyl)-1,4-Diphenylbenzene, Jonathan B. Briggs, Mikael D. Jazdzyk, Glen P. Miller
Chemistry
In the title compound, C(20)H(16)Br(2), the terminal phenyl groups are twisted away from the central ring by approximately 55 and -125 degrees (average of four dihedral angles each), respectively. The crystal structure is stabilized by a combination of interMolecular and intraMolecular interactions including interMolecular pi-pi stacking interactions [C atoms of closest contact = 3.423 ( 5) angstrom].