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Physical Sciences and Mathematics Commons

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Chemistry

University of Missouri, St. Louis

Theses/Dissertations

2016

Analytical chemistry

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Full-Text Articles in Physical Sciences and Mathematics

Study Of Vaporization Enthalpies And Vapor Pressures Of Potential Environmental Pollutants By Correlation-Gas Chromatography, Chase Patrick Gobble Aug 2016

Study Of Vaporization Enthalpies And Vapor Pressures Of Potential Environmental Pollutants By Correlation-Gas Chromatography, Chase Patrick Gobble

Dissertations

The focus of this dissertation is on the measurement and analysis of thermodynamic data, including vaporization, fusion, and sublimation enthalpies and vapor pressures of dialkyl phthalates, as well as aliphatic and aromatic primary and tertiary amines by correlation gas chromatography (CGC). These compounds are important industrial and pharmaceutical substances whose prolonged use and sometimes misuse with regards to their disposal has created an environmental concern. Thermodynamic properties, such as vaporization enthalpy and vapor pressure provide crucial information to numerous industries and fields of study that include the chemical and petrochemical industry, chemical engineering and environmental science. Dialkyl phthalates are essential …