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Full-Text Articles in Physical Sciences and Mathematics
Synthesis And Evaluation Of Polymer Supported Homogenous Oxidation Catalysts, Raymond J. Riley
Synthesis And Evaluation Of Polymer Supported Homogenous Oxidation Catalysts, Raymond J. Riley
Retrospective Theses and Dissertations
Polystyrene bis(salicylaldehyde)-propylene-1,3-diiminato Cobalt (II) [salen] and Polystyrene bis(2,4-pentanedione)-propylene-1,3-diiminato Cobalt (II) [BAE] were prepared stepwise from chloromethylated polystyrene. In addition, a new preparation of a Schiff base was attempted resulting in Polystyrene bis(salicylaldehyde)-isobutylene-1,3-diiminoato Cobalt (II) being produced. Optimum reaction conditions were determined with regard tot ime, temperature, reaction ratios and solvent for each step for the reaction. The ability of the above named Cobalt (II) Schiff bases to oxidize 3-methyl indole to give the corresponding o-formylaminoacetophenone was also studied. One polymer-bound Schiff base cobalt catalyst (co-salen) demonstrated a very small amount of catalytic activity resulting in a minimum amount of o-formylaminoacetophenone …
Reactions Of (3-(Dimethylamino)-2-Azaprop-2-En-1-Ylidene) Dimethylammonium Chloride (Gold's Reagent) With Carboxylic Acid Derivatives And Grignard Reagents, Dale E. Polk
Retrospective Theses and Dissertations
An azavinamidium salt, [3-(Dimethylamino)-2-azaprop-2-en-l-ylidene] dimethylammonium chloride was reacted with primary amides, esters containing an ╬▒-methylene group and Grignard reagents. The reaction of this azavinamidium salt with amides and esters produced respectively, acyl amidines and enamino esters. Both of these products were produced in high yields by using relatively mild conditions. Reaction of the salt with Grignard reagents resulted in a novel synthesis of aldehydes. This aldehyde synthesis was shown to be of general utility and to proceed in high yields.