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Chemistry

University at Albany, State University of New York

Theses/Dissertations

2021

Raman Spectroscopy

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Full-Text Articles in Physical Sciences and Mathematics

Comparison Of Raman Spectra Of Smokeless Powders For Cartridge Differentiation, Nathan Bartlett May 2021

Comparison Of Raman Spectra Of Smokeless Powders For Cartridge Differentiation, Nathan Bartlett

Chemistry

As crimes involving firearms continue to be prevalent, forensic methods processing firearms evidence must keep pace with the changes in said evidence. Scanning Electron Microscopy with Energy Dispersive Spectroscopy, or SEM-EDS, is a method that targets the inorganic portions of gunshot residue (GSR) evidence, namely lead, barium, and antimony, to characterize a cartridge used at a crime scene, and was the most often used analysis method for characterizing ammunition cartridges. The rise of lead-free ammunition has made it so that SEM-EDS alone is not sufficient for the characterization of inorganic gunshot residue (IGSR), and studies have shifted towards being able …


The Detection And Identification Of Blood On Interfering Substrates Using Raman Spectroscopy And Hamand For Forensic Purposes, Jalissa M. Thomas Jan 2021

The Detection And Identification Of Blood On Interfering Substrates Using Raman Spectroscopy And Hamand For Forensic Purposes, Jalissa M. Thomas

Legacy Theses & Dissertations (2009 - 2024)

Body fluids, such as blood and semen, can provide invaluable information to a criminal investigation. As such, it is imperative that body fluid evidence is properly detected and identified. Our laboratory has developed a methodology to universally detect and identify body fluids using Raman spectroscopy and chemometrics. This methodology was developed under ideal conditions, which are rare in the field. Body fluid evidence can be found on substrates that produce a large Raman signal that can hinder detection of body fluid traces, which produce a weak signal. This project proposes the use of a statistical program called HAMAND (Hypothetical Addition …


Utilizing Raman Spectroscopy To Determine The Time Since Deposition Of Heated Bloodstains, Alexis Pearl Barber Jan 2021

Utilizing Raman Spectroscopy To Determine The Time Since Deposition Of Heated Bloodstains, Alexis Pearl Barber

Legacy Theses & Dissertations (2009 - 2024)

The development of novel forensic methods is a rapidly growing area within analytical chemistry. Analytical chemistry is well suited for forensic analyses as a plethora of information can be ascertained from utilizing a wide variety of techniques. At the scene of violent crimes, bloodstain evidence is one of the most frequently found and valuable types of evidence. This is because blood is a complex biological fluid which can provide crucial information during a forensic investigation including DNA evidence. The most informative form of analysis is DNA profiling, which potentially allows for the identification of an individual. However, there is more …