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Full-Text Articles in Physical Sciences and Mathematics
Hierarchical Modelling Of Raman Spectroscopic Data Demonstrates The Potential For Manufacturer And Caliber Differentiation Of Smokeless Powders, Nathan Russell Bartlett
Hierarchical Modelling Of Raman Spectroscopic Data Demonstrates The Potential For Manufacturer And Caliber Differentiation Of Smokeless Powders, Nathan Russell Bartlett
Legacy Theses & Dissertations (2009 - 2024)
With the rise of gun-based crime and the advent of lead-free ammunition reducing the effectiveness of previously used methods, the analysis of smokeless powders to better understand organic gunshot residues is now more important than ever. One method that has shown potential is Raman spectroscopy, a relatively quick, nondestructive, and non-contact analysis method. To investigate whether Raman spectroscopy could be used to characterize individual powders, samples of smokeless powders from three manufacturers, Remington, Federal, and Winchester, each with two 9mm caliber and two .38 caliber ammo types, were dissolved, and their Raman spectra were collected. A hierarchical modelling system was …
A Project To Dye For : Differentiation Of Dyed And Non-Dyed Human Hairs Using Atr Ft-Ir Spectroscopy, Joseph John Greco
A Project To Dye For : Differentiation Of Dyed And Non-Dyed Human Hairs Using Atr Ft-Ir Spectroscopy, Joseph John Greco
Legacy Theses & Dissertations (2009 - 2024)
IR spectroscopy is widely utilized for forensic purposes due to the chemical fingerprint the method provides. ATR FT-IR spectroscopy is particularly advantageous because it allows for spectra to be collected quickly, accurately, and perhaps most importantly for forensics, non-destructively. Human hair is commonly collected at a crime scene, and further analyzed using DNA analysis and microscopy. However, these techniques have limitations. In the past ATR FT-IR spectroscopy has shown promise in the analysis of human hair for forensic purposes. In this study, the differentiation of undyed hair versus dyed hair classes of varying colors based on their IR spectra were …
Further Development Of Raman Spectroscopy For Body Fluid Investigation : Forensic Identification, Limit Of Detection, And Donor Characterization, Claire K. Muro
Further Development Of Raman Spectroscopy For Body Fluid Investigation : Forensic Identification, Limit Of Detection, And Donor Characterization, Claire K. Muro
Legacy Theses & Dissertations (2009 - 2024)
The challenges to forensic body fluid analysis have placed limitations on the type of information that investigators can acquire and how that information can be collected. In recent years, Raman spectroscopy has proven itself useful for characterizing body fluids. In 2008, a large-scale investigation was undertaken to explore the use of Raman spectroscopy as a means of identifying body fluids. This work resulted in multidimensional Raman spectroscopic signatures for the five main body fluids: semen, peripheral blood, saliva, vaginal fluid, and sweat. These studies were incredibly successful and created the foundation for years of continued research. Accordingly, the studies included …
Vibrational Spectroscopic Analysis Of Gunshot Residue : A Novel Approach For Detection And Characterization, Justin J. Bueno
Vibrational Spectroscopic Analysis Of Gunshot Residue : A Novel Approach For Detection And Characterization, Justin J. Bueno
Legacy Theses & Dissertations (2009 - 2024)
Due to the increasing prevalence of firearm related crimes, there is a need for an all-encompassing analytical technique which can rapidly detect and analyze trace crime scene firearm evidence. There are several forms of ballistics and trace evidence associated with firearm offenses. Historically, the most neglected piece of evidence has ironically been the most prevalent. Each firearm discharge produces a so called gunshot residue (GSR) sample, expelling dust and particles numbering from hundreds to thousands throughout the shooting environment. The detection of GSR at a crime scene or on a suspect is critical for determining what actually happened during a …
Raman Spectroscopic Analysis Of Body Fluids : Species Differentiation And The Effect Of Substrate Interference And Laser Power, Gregory Keith Mclaughlin
Raman Spectroscopic Analysis Of Body Fluids : Species Differentiation And The Effect Of Substrate Interference And Laser Power, Gregory Keith Mclaughlin
Legacy Theses & Dissertations (2009 - 2024)
Several recent discoveries demonstrate that Raman spectroscopy has a unique capability to characterize body fluid traces in a forensic capacity. This approach has thus garnered interest in the forensic community since 2008, when a proof of concept experiment established that blood, semen, vaginal fluid, sweat and saliva are easily differentiable through their Raman spectra. Several possible methods of identification have been described in the literature, one approach uses chemometrical models, and another applies recently formulated multidimensional Raman signatures. The analytical sampling method and the identification procedure provide several desirable traits for the field of forensic science. In particular, Raman spectroscopy …
Structural Interactions And Dynamics Of Disease Related Proteins By Using Nmr Spectroscopy, Shadakshara Swamy Puttamadappa
Structural Interactions And Dynamics Of Disease Related Proteins By Using Nmr Spectroscopy, Shadakshara Swamy Puttamadappa
Legacy Theses & Dissertations (2009 - 2024)
Nuclear Magnetic Resonance (NMR) is a powerful spectroscopic technique to study the structure, molecular interactions, and dynamics of proteins. Modern NMR instrumentation, advancements in experimental techniques and revolutionary developments in recombinant DNA technology have made NMR a versatile and very convenient tool for biomolecule characterization.
Elucidating The Structure Of Protein Aggregates By Raman Spectroscopy, Ludmila A. Popova
Elucidating The Structure Of Protein Aggregates By Raman Spectroscopy, Ludmila A. Popova
Legacy Theses & Dissertations (2009 - 2024)
The structures and properties of amyloid fibrils are of considerable interest due to their associations with numerous neurodegenerative diseases such as Alzheimer's disease, Parkinson's disease and transmissible spongiform encephalopaties (prion diseases). Understanding fibrillogenesis at a molecular level requires detailed structural characterization of amyloid fibrils. However amyloid fibrils are difficult objects to study due to their non-crystalline and insoluble nature. These properties make the application of classical tools of structural biology, such as X-Ray crystallography and solution Nuclear Magnetic Resonance spectroscopy, impractical for structural characterization of protein fibrils.